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X-ray spectra of galaxy clusters are dominated by the thermal emission from the hot intracluster medium. In some cases, besides the thermal component, spectral models require additional components associated, e.g., with resonant scattering and charge exchange. The latter produces mostly underluminous fine spectral features. Detection of the extra components therefore requires high spectral resolution. The upcoming X-ray missions will provide such high resolution, and will allow spectroscopic diagnostics of clusters beyond the current simple thermal modeling. A representative science case is resonant scattering, which produces spectral distortions of the emission lines from the dominant thermal component. Accounting for the resonant scattering is essential for accurate abundance and gas motion measurements of the ICM. The high resolution spectroscopy might also reveal/corroborate a number of new spectral components, including the excitation by non-thermal electrons, the deviation from ionization equilibrium, and charge exchange from surface of cold gas clouds in clusters. Apart from detecting new features, future high resolution spectroscopy will also enable a much better measurement of the thermal component. Accurate atomic database and appropriate modeling of the thermal spectrum are therefore needed for interpreting the data., published in Space Science Reviews