1. One-pot fabrication of Mo1-xWxS2 alloy nanosheets as SERS substrates with highly Raman enhancement effect and long-term stability.
- Author
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Li, Suyang, Liang, Pei, Chen, Qiang, Sun, Biao, Shang, Ziyang, Huang, Jie, Zou, Mingqiang, Qi, Xiaohua, and Wu, Jiechen
- Subjects
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RAMAN effect , *NANOSTRUCTURED materials , *SODIUM tungstate , *GENTIAN violet , *CHARGE transfer - Abstract
[Display omitted] • New Mo1-xWxS2 two-dimensional nanosheets were prepared by the one-pot method. • Compared with MoS2, the Raman intensity of Rhodamine 6G (10−6 M) was amplified by 1.7 times with Mo1-xWxS2 nanosheets as the substrate. • With abundant edge active sites that facilitate charge transfer, Mo1-xWxS2 nanosheets could better enhance SERS signals. A new Mo 1- x W x S 2 two-dimensional nanosheets were prepared by the one-pot method. After certain Mo atoms in MoS 2 were replaced by W ones in a hydrothermal reduction procedure, Mo 1- x W x S 2 was formed on the Mo foil. Well enhanced Mo 1- x W x S 2 nanosheets were prepared when the sodium tungstate concentration got under control. Various characterizations were carried out, which indicate that Mo 1- x W x S 2 nanosheets with good crystallinity. Compared with MoS 2 , the Raman intensity of Rhodamine 6G (10−6 M) was amplified by 1.7 times with Mo 1- x W x S 2 nanosheets as the substrate. The characteristic Raman peaks could still be clearly distinguished until the concentration of Rhodamine 6G (R6G), Methylene blue (MB) and Crystal violet (CV) down to 10−8, 10−8 and 10−7 M, respectively. With abundant edge active sites that facilitate charge transfer, Mo 1- x W x S 2 nanosheets could better enhance SERS signals of target detection molecules and get a good linear relationship exists within the concentration and Raman peak strength. In addition, R6G SERS detection also shows excellent reproducibility and long-term stability of this TMDs SERS substrate. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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