1. Mechanism of enhancement of superconducting properties in a Ba1-xKxFe2As2 superconductor by Pb addition.
- Author
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Xianping Zhang, Chao Yao, ChunleiWang, Zhaoshun Gao, Dongliang Wang, Chengduo Wang, He Lin, Yanpeng Qi, Lei Wang, and Yanwei Ma
- Subjects
SUPERCONDUCTORS ,REACTION mechanisms (Chemistry) ,COMPARATIVE studies ,BARIUM compounds ,LEAD ,POLYCRYSTALS ,DISPERSION (Chemistry) - Abstract
A comparative study of the addition of Pb to polycrystalline Ba
0.6 K0.4 Fe2 As2 has revealed that the Pb should be added after the Ba0.6 K0.4 Fe2 As2 phase has formed. The uniformly dispersed Pb can ameliorate the Ba0.6 K0.4 Fe2 As2 grain linkages. In contrast, pre-added Pb in the raw powder congregates to form large particles and has hardly any positive effect on the Jc enhancement. To conglutinate at the grain surface and avoid contamination of the Ba0.6 K0.4 Fe2 As2 , the material added should have a low melting point and inertia to the superconducting phase. This model also enables us to predict desirable dopants for enhancing superconducting properties of Ba0.6 K0.4 Fe2 As2 . [ABSTRACT FROM AUTHOR]- Published
- 2012
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