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Abstract: Developing a robust predicting methodology on the interfacial fracture energy of dissimilar materials is urgently needed to meet the mechanical strength requirements for investigating novel materials and subsequent device structures with the bonded types of multi thin films. Thus, this paper provides an overview of useful approaches according to linear-elastic interfacial fracture mechanics, such as J-integral method, modified virtual crack closure technique (MVCCT), and analytical solutions derived from the relationship between the stress field of delaminated tip and crack tip opening displacements to compare their estimated capability of cracking energy. A popular technique for determining the interface adhesion of thin coatings is the four-point bending test (4-PBT). The testing vehicles of 4-PBT allow a more thorough validation of the foregoing predicted approaches based on finite element analysis compared with the simulated results with related experimental data. The critical energies of 18J/m2, 78.53J/m2, 52.01J/m2, and 71.02J/m2 for the bonded interfaces of SiO2/SiLK, Ta/SiLK, TaN/SiLK, and Si3N4/SiLK stacked nano-scaled thin films are precisely judged, respectively. The predicted results of the J-integral method match well with the MVCCT estimation. The results reveal that the opening fractured mode is dominant at the beginning of the crack advances along the bonded interface of Ta/SiLK, TaN/SiLK, and Si3N4/SiLK stacked films as the interfacial crack length increases. Moreover, the essential trends of dependences for the modulus ratio and thickness ratio of stacked thin films on interfacial energy release rate are logically identified and investigated. Therefore, this paper could be regarded as a design guideline of interfacial fracture behavior for stacked films utilized in the development of advanced device technologies. [Copyright &y& Elsevier]

Zr-based thin film metallic glass (TFMG), exhibiting the unique properties of good glass forming ability (GFA), corrosion resistance, and biocompatibility, can be applied in various novel fields of industries. An ultra-smooth surface is obtained with the TFMG coatings, which is beneficial to modify the work surface. Thus, TFMG can be extended to medical appliances, such as surgical blades and micro-surgery scissors. The aims of this study are to fabricate the Cu-containing Zr-based TFMG onto SUS304 plates and to investigate the surface physical properties and their antimicrobial effects. The chemical compositions of Zr–Cu–Ni–Al coatings are examined by a field emission electron probe micro-analyzer (FE-EPMA). The amorphous structures of all TFMG are characterized by the X-ray diffractometry. The surface properties are analyzed by an atomic force microscope (AFM) and a water contact angle goniometer for the 304 stainless steel substrate and Zr–Cu–Ni–Al TFMG. Liquid culture methods and plate counting methods are used to assess the antimicrobial performance of specimens. The antimicrobial rate against Escherichia coli ( E. coli ) and Staphylococcus aureus ( S. aureus ) under the Japanese Industrial Standard JIS Z2801: 2000 is over 99%. The release of copper ion from TFMG specimen is determined by the inductively coupled plasma-mass spectrometer (ICP-MS) to evaluate the antimicrobial activity of Cu-containing Zr-based TFMG. The results show that the surface of SUS 304 stainless steel substrate can be modified with deposited Zr–Cu–Ni–Al TFMG, and their improved antimicrobial efficacy against those bacteria is attributed to their amorphous rough surface, hydrophobic properties and released copper ion. The TFMG developed in this study with adequate hardness, good adhesion ability and antimicrobial efficiencies can be used as a promising candidate to improve the surface properties of the medical appliances and also to reduce the possibility of nosocomial infection. [ABSTRACT FROM AUTHOR]