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Claude Berge (1987) introduced the concept of k-extendable graphs, wherein any independent set of size k is inherently a constituent of a maximum independent set within a graph H = (V , E) . Graphs possessing the property of being 1-extendable are termedas Berge graphs. This introduction gave rise to the notion of well-covered graphs and well-dominated graphs. A graph is categorized as well-covered if each of its maximal independent sets is, in fact, a maximum independent set. Similarly, a graph attains the classification of well-dominated if every minimal dominating set (DS) within it is a minimum dominating set. In alignment with the concept of k-extendable graphs, the framework of (k , γ) -endowed graphs and symmetric (k , γ) -endowed graphs are established. In these graphs, each DS of size k encompasses a minimum DS of the graph. In this article, a study of γ -endowed dominating sets is initiated. Various results providing a deep insight into γ -endowed dominating sets in graphs such as those characterizing the ones possessing a unique minimum DS are proven. We also introduce and study the symmetric γ -endowed graphs and minimality of dominating sets in them. In addition, we give a solution to an open problem in the literature. which seeks to find a domination-based parameter that has a correlation coefficient of ρ > 0.9967 with the total π -electronic energy of lower benzenoid hydrocarbons. We show that the upper dominating number Γ (H) studied in this paper delivers a strong prediction potential. [ABSTRACT FROM AUTHOR]