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1. Iron-Catalyzed Synthesis of (E)-β-Vinylsilanes via a Regio- and Stereoselective Hydrosilylation from Terminal Alkynes.

Author

Zhi-Kai Liu, Guo-Liang Zhang, Ding-Chang Li, Ying Yang, Li Chen, and Zhuang-Ping Zhan

Subjects
*HYDROSILYLATION, *HYDROGENATION, *CHEMICAL reactions
Abstract

A concise strategy for the synthesis of vinylsilanes from an iron-catalyzed regio- and stereoselective hydrosilylation of terminal alkynes has been developed. The catalyst and reagents are commercially available and easy to handle, providing a simple and practical method for iron-catalyzed anti-Markovnikov hydrosilylation with a good functional group tolerance. [ABSTRACT FROM AUTHOR]

Published
2019
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