1. Metal- and Additive-Free Synthesis of α-Hydroxyamino Ketones Enabled by Organophotocatalyst.
- Author
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Yamanomoto, Ken, Matsudaira, Tadachika, and Akiyama, Takahiko
- Subjects
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KETONES , *SILICA gel , *ACYLATION , *HYDROAMINATION , *IMINES , *NORMAL-phase chromatography - Abstract
[21][24] We wish to report herein our synthetic approach toward -hydroxyamino ketones, which involves the radical acylation of nitrone with 2-acylbenzothiazolene under organophotoredox catalysis (route C). Metal- and Additive-Free Synthesis of -Hydroxyamino Ketones Enabled by Organophotocatalyst Hydroxyamino ketone, hydroxylamine, nitrone, benzothiazoline, metal-free, organophotocatalyst Keywords: hydroxyamino ketone; hydroxylamine; nitrone; benzothiazoline; organophotocatalyst; metal-free EN hydroxyamino ketone hydroxylamine nitrone benzothiazoline organophotocatalyst metal-free 1391 1394 4 07/11/23 20230725 NES 230725 Graph Nitrogen-containing compounds are prevalent in organic compounds, and a range of novel catalytic approaches have been extensively explored. [Extracted from the article]
- Published
- 2023
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