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2. Organocatalytic Synthesis of Terminal Propargylamine Derivatives by Tandem Amination-Alkynylation.

Author

Wang, Yu, Peng, Fangzhi, Zhang, Hongbin, and Shao, Zhihui

Subjects
*AMINES, *ORGANIC compounds, *ALDEHYDES, *BINARY operations, *ALKYNES
Abstract

The first organocatalytic synthesis of terminal propargylic amines from aldehydes via tandem amination/Seyferth-�Gilbert alkynylation has been developed. The described protocol provides the formal addition products of acetylene (HC≡CH) to ali�phatic imines, which are not easily obtained directly. [ABSTRACT FROM AUTHOR]

Published
2009
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