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2. Palladium-Catalyzed Cross-Coupling between 7-Azaindoles and Reformatsky Reagents.

Author

Barl, Nadja M., Malakhov, Vladimir, Mathes, Christian, Lustenberger, Philipp, and Knochel, Paul

Subjects
AZAINDOLES, REFORMATSKY reaction, PALLADIUM catalysts, COUPLING reactions (Chemistry), ARYLATION, ESTER derivatives, SILYL ethers, CHEMICAL reagents
Abstract

The preparation of various 2-(7-azaindolyl)carboxylic esters by Pd-catalyzed coupling of Reformatsky reagents with TBDMS-protected 3-bromo-7-azaindoles leading to a wide range of arylated ester derivatives is reported. After removal of the protecting group, the corresponding free 2-(7-azaindolyl)carboxylic esters are obtained in satisfactory yields. [ABSTRACT FROM AUTHOR]

Published
2015
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