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1. Chiral phosphine-catalyzed regio- and enantioselective allylic amination of Morita–Baylis–Hillman acetates

Author

Ma, Guang-Ning, Cao, Shu-Hua, and Shi, Min

Subjects
*AMINATION, *CHIRALITY, *ACETATES, *SUBSTITUTION reactions, *ENANTIOSELECTIVE catalysis, *PHOSPHINE, *LIGANDS (Chemistry)
Abstract

Abstract: Enantioselective allylic substitution of Morita–Baylis–Hillman (MBH) acetates with phthalimide was realized in the presence of a novel l-proline-derived chiral trifunctional phosphine amide ligand to give the corresponding allylic amination adducts in good yields (70–95%) and in modest to good enantioselectivities (34–78% ee’s). [Copyright &y& Elsevier]

Published
2009
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