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1. Synthesis of novel chiral oxazoline-Schiff base ligands for the catalytic asymmetric chlorination of β-keto esters

Author

Qi, Ming-Hui, Wang, Fei-Jun, and Shi, Min

Subjects
*ASYMMETRIC synthesis, *CHIRALITY, *OXAZOLES, *SCHIFF bases, *CHLORINATION, *ESTERS, *METAL complexes, *COPPER catalysts
Abstract

Abstract: A series of novel monooxazoline-Schiff base ligands 1 has been successfully synthesized. The Cu(I)–1a complex showed excellent catalytic activities with up to 83% ee for the asymmetric α-chlorination of β-keto esters. [Copyright &y& Elsevier]

Published
2010
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