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Start Over Author "Rocco, Pandolfo" Journal tetrahedron: asymmetry
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1. Application of Sharpless asymmetric dihydroxylation to thienyl- and benzothienyl acrylates and crotonates

Author

Lucia Chiummiento, Rocco Pandolfo, Carlo Bonini, Paolo Lupattelli, Margherita De Bonis, and Maria Funicello

Subjects
Chemistry, Peptidomimetic, organic chemicals, Organic Chemistry, Benzothiophene, Catalysis, Inorganic Chemistry, chemistry.chemical_compound, Dihydroxylation, polycyclic compounds, Thiophene, Organic chemistry, heterocyclic compounds, Crotonates, Physical and Theoretical Chemistry, Enantiomeric excess, Sharpless asymmetric dihydroxylation
Abstract

Optimized conditions for the catalytic asymmetric dihydroxylation have been applied to thiophene and benzothiophene containing acrylates and crotonates to afford the corresponding diols in good overall yields and good to excellent enantiomeric excess. The products obtained were revealed to be useful intermediates in peptidomimetic synthesis.

Published
2006
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