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Start Over Author "Suzenet, Franck" Topic acrylic acid Language english Journal tetrahedron letters: international organ for the rapid publication of preliminary communications in organic chemistry

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1 results on '"Suzenet, Franck"'

1. A mild and efficient synthesis of new pentafluorosulfanyl-substituted electron-deficient alkenes and allylsilanes.

Author

Falkowska, Ewelina, Suzenet, Franck, Jubault, Philippe, Bouillon, Jean-Philippe, and Pannecoucke, Xavier

Subjects
*ALKENES, *ALLYLSILANES, *ACRYLIC acid, *ELIMINATION reactions, *COUPLING reactions (Chemistry), *CHEMICAL synthesis
Abstract

A series of pentafluorosulfanyl-substituted acrylic esters and amides have been synthesized in moderate to good yields from 3-pentafluorosulfanyl-prop-2-enol employing a chromic oxidation and subsequent coupling reaction. New pentafluorosulfanyl-substituted allylsilanes were also obtained from a SF5-Cl addition on allylsilanes followed by a β-elimination reaction. [ABSTRACT FROM AUTHOR]

Published
2014
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