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1. An extremely mild 3-aza-Claisen reaction. 1. Rearrangement of simple N-allylamides

Author

Perry S. Brown, Michael A. Walters, C. S. Mcdonough, and Andrew B. Hoem

Subjects
Claisen rearrangement, Chemistry, Simple (abstract algebra), medicine.drug_class, Organic Chemistry, Drug Discovery, medicine, Organic chemistry, Carboxamide, Aliphatic compound, Biochemistry
Abstract

An extremely mild 3-aza-Claisen reaction has been developed. Readily available N-allyl amides are converted to pentenylnitriles in moderate to good yields by a transformation that occurs at room temperature under essentially neutral conditions.

Published
1991
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