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1. Formation of novel spirochlorin and allylidenechlorin by the reaction of bromovinylporphyrin with tetracyanoethylene

Author

Suzuki Mikio and Shigeo Kai

Subjects
chemistry.chemical_compound, Chemistry, Stereochemistry, Organic Chemistry, Drug Discovery, Chlorin, Absorption (chemistry), Tetracyanoethylene, Photochemistry, Biochemistry, Adduct
Abstract

Treatment of bromovinylheptaethylporphyrin 1 with tetracyanoethylene leads to the formation of spirochlorin 2 and allylidenechlorin 3via the initially formed Diels-Alder adduct. The former product 2 is a new class of chlorin and the latter 3 exhibits unusual long-wavelength absorption in the red region of the spectrum.

Published
1996

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