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Tension remains between the observed and modeled properties of substellar objects, but objects in binary orbits, with known dynamical masses, can provide a way forward. HD 72946 B is a recently imaged brown dwarf companion to a nearby, solar-type star. We achieve ∼100 μ as relative astrometry of HD 72946 B in the K band using VLTI/GRAVITY, unprecedented for a benchmark brown dwarf. We fit an ensemble of measurements of the orbit using orbitize! and derive a strong dynamical mass constraint M _B = 69.5 ± 0.5 M _Jup assuming a strong prior on the host star mass M _A = 0.97 ± 0.01 M _⊙ from an updated stellar analysis. We fit the spectrum of the companion to a grid of self-consistent BT-Settl-CIFIST model atmospheres, and perform atmospheric retrievals using petitRADTRANS . A dynamical mass prior only marginally influences the sampled distribution of effective temperature, but has a large influence on the surface gravity and radius, as expected. The dynamical mass alone does not strongly influence retrieved pressure–temperature or cloud parameters within our current retrieval setup. Independently of the cloud prescription and prior assumptions, we find agreement within ±2 σ between the C/O of the host (0.52 ± 0.05) and brown dwarf (0.43–0.63), as expected from a molecular cloud collapse formation scenario, but our retrieved metallicities are implausibly high (0.6–0.8) in light of the excellent agreement of the data with the solar-abundance model grid. Future work on our retrieval framework will seek to resolve this tension. Additional study of low surface gravity objects is necessary to assess the influence of a dynamical mass prior on atmospheric analysis.

Direct imaging studies have mainly used low-resolution spectroscopy (R ∼ 20-100) to study the atmospheres of giant exoplanets and brown dwarf companions, but the presence of clouds has often led to degeneracies in the retrieved atmospheric abundances (e.g., carbon-to-oxygen ratio, metallicity). This precludes clear insights into the formation mechanisms of these companions. The Keck Planet Imager and Characterizer (KPIC) uses adaptive optics and single-mode fibers to transport light into NIRSPEC (R ∼ 35,000 in the K band), and aims to address these challenges with high-resolution spectroscopy. Using an atmospheric retrieval framework based on petitRADTRANS, we analyze the KPIC high-resolution spectrum (2.29-2.49 μm) and the archival low-resolution spectrum (1-2.2 μm) of the benchmark brown dwarf HD 4747 B (m = 67.2 ± 1.8 M Jup, a = 10.0 ± 0.2 au, T eff ≈ 1400 K). We find that our measured C/O and metallicity for the companion from the KPIC high-resolution spectrum agree with those of its host star within 1σ-2σ. The retrieved parameters from the K-band high-resolution spectrum are also independent of our choice of cloud model. In contrast, the retrieved parameters from the low-resolution spectrum are highly sensitive to our chosen cloud model. Finally, we detect CO, H2O, and CH4 (volume-mixing ratio of log(CH4) = −4.82 ± 0.23) in this L/T transition companion with the KPIC data. The relative molecular abundances allow us to constrain the degree of chemical disequilibrium in the atmosphere of HD 4747 B, and infer a vertical diffusion coefficient that is at the upper limit predicted from mixing length theory.

Using Keck Planet Imager and Characterizer high-resolution ( R ∼ 35,000) spectroscopy from 2.29 to 2.49 μ m, we present uniform atmospheric retrievals for eight young substellar companions with masses of ∼10–30 M _Jup , orbital separations spanning ∼50–360 au, and T _eff between ∼1500 and 2600 K. We find that all companions have solar C/O ratios and metallicities to within the 1 σ –2 σ level, with the measurements clustered around solar composition. Stars in the same stellar associations as our systems have near-solar abundances, so these results indicate that this population of companions is consistent with formation via direct gravitational collapse. Alternatively, core accretion outside the CO snowline would be compatible with our measurements, though the high mass ratios of most systems would require rapid core assembly and gas accretion in massive disks. On a population level, our findings can be contrasted with abundance measurements for directly imaged planets with m < 10 M _Jup , which show tentative atmospheric metal enrichment compared to their host stars. In addition, the atmospheric compositions of our sample of companions are distinct from those of hot Jupiters, which most likely form via core accretion. For two companions with T _eff ∼ 1700–2000 K ( κ And b and GSC 6214–210 b), our best-fit models prefer a nongray cloud model with >3 σ significance. The cloudy models yield 2 σ −3 σ lower T _eff for these companions, though the C/O and [C/H] still agree between cloudy and clear models at the 1 σ level. Finally, we constrain ^12 CO/ ^13 CO for three companions with the highest signal-to-noise ratio data (GQ Lup b, HIP 79098b, and DH Tau b) and report $v\sin i$ and radial velocities for all companions.