1. Experimental and DFT Characterization of Halloysite Nanotubes Loaded with Salicylic Acid
- Author
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Davide Presti, Celia Duce, Jose Gonzalez Rivera, Alfonso Pedone, Vincenzo Ierardi, Alessio Spepi, and Maria Rosaria Tine
- Subjects
SOLUTION INTERFACE ,ADSORPTION ,Biocompatibility ,Immobilized enzyme ,Inorganic chemistry ,02 engineering and technology ,engineering.material ,010402 general chemistry ,01 natural sciences ,Halloysite ,DELIVERY ,chemistry.chemical_compound ,Adsorption ,Desorption ,Physical and Theoretical Chemistry ,Fourier transform infrared spectroscopy ,ATR-FTIR ,ELECTRONIC-PROPERTIES ,CLAY NANOTUBES ,AB-INITIO ,ALUMINUM ,RELEASE ,COMPLEXES ,Chemistry ,021001 nanoscience & nanotechnology ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,General Energy ,Chemical engineering ,engineering ,Nanocarriers ,0210 nano-technology ,Salicylic acid - Abstract
Halloysite nanotubes (HNTs) and salicylic acid (SA) are natural substances widely used in different fields. HNTs are very promising as nanocarriers because of their biocompatibility, atoxicity, anti-inflammatory properties and capacity to maintain the biological activity of immobilized enzymes. Because of its bactericidal and antiseptic properties, salicylic acid (SA) is used in pharmaceutical formulations, and as an additive for preserving foods and cosmetics. In this study, we set up a procedure for the loading of HNTs with SA for their possible application in active food packaging. Pristine HNTs were studied together with acidic etched HNTs with enlarged internal lumen, and various pH values for the loading solutions were tested in order to obtain the maximum loading. The HNTs—empty and loaded with SA—were characterized by TG-FTIR, FTIR SEM, STEM, and nitrogen adsorption/desorption isotherms measurements. We obtained a maximum loading of 10.5% (w/w), using HNTs pretreated with H2SO4 2 M at 25 °C for 48...
- Published
- 2016
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