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The fretting wear-resistant properties of ion-sulphuration+shot-peening and shot-peening+ion-sulphuration duplex-treated coatings on 1045 steel substrate were investigated. The results show that the fretting wear-resistance of shot-peening+ion-sulphuration coating was better than that of the ion-sulphuration+shot-peening coating. The fretting wear process of the duplex-treated coatings in the gross slip regime could be described as the sulphuration coatings playing an important lubricating role in the incubation period. Then a series of changes took place continuously and alternatively on the contact surfaces, including adhesion, material transfer, oxidation, delamination of the oxide layer and degradation. In the last stage, the trapping, pulverization and elimination of debris restrained the adhesion between the contact surfaces and led to a decrease in the friction coefficient.

The tribological properties of Si 3 N 4 and TiN thin films produced by ion beam enhanced deposition (IBED) were compared on a SRV friction and wear testing machine. The friction coefficient of all thin films shows a descending tendency with increase in load, and is lower than that of 52100 steel. All the IBED films show a much better wear resistance than 52100 steel, especially in the higher load and frequency ranges; it can reach six times that of the latter. In order to understand the reasons for their excellent properties, the microstructure, microhardness and bonding strength with the substrate were analysed by SEM, X-ray diffraction, Knoop hardness and scratching test methods separately. The results show that the TiN(1) film exhibits the best tribological properties, which are closely related with its greater hardness and bonding strength.