Search

Microstructure evolution, static coarsening mechanism and coarsening kinetics of a pre-deformed Ti 2 AlNb-based alloy during aging at 945 °C and 970 °C were investigated in this study. The corresponding microstructures were characterized by scanning electron microscopy and transmission electron microscopy. The results show that the pre-deformed alloy exhibited different morphologies aged at 945 °C and 970 °C. When the alloy was aged at 970 °C, the coarsening mechanism of the O precipitates was mainly controlled by the Ostwald ripening mechanism at first aging stage; after that, it was controlled by the boundary splitting mechanism and termination migration mechanism. Due to the difference in interface energy between the terminals and the long-axis direction of the O lath, diffusion process of solute atoms leads to the coarsening and fragmenting of O lath. The dimension of the O precipitates in the studied alloy continued to grow with the prolonged time during aging at 945 °C or 970 °C while the coarsening rate decreased. The static coarsening kinetic of the studied alloy was established in term of the modified Lifshitz-Slyozov-Wagner (LSW) theory. Static coarsening behavior of the pre-deformed alloy was mainly controlled by bulk diffusion at 945 °C and interfacial diffusion at 970 °C, respectively. • The thickness of O precipitates increased with aging temperature and time. • The microstructure consisted of lamellar O at 945 °C and changed from spherical to lath with aging time at 970 °C-aging. • Static coarsening behavior was controlled by Ostwald ripening, boundary splitting and termination migration mechanism. • Coarsening kinetics of the studied alloy can be established according to modified LSW theory. [ABSTRACT FROM AUTHOR]

Cyclic oxidation behavior of a polycrystalline Ni 3 Al-based superalloy under as-cast and solution treated conditions was investigated in detail. SEM equipped with energy dispersive X-ray spectrometer and high-resolution transmission electron microscopy was used for microstructure observation and mechanism analysis. Results showed that oxidation process occurred along eutectic area (γ-γ′) and dual phase area (γ+γ′)interfaces firstly for as-cast alloy and oxide scales along (γ-γ′)/(γ+γ′) interfaces spalled gradually with oxidation process proceeding. As for the solution treated alloy, though oxidation process also occurred along (γ-γ′)/(γ+γ′) interfaces, no obvious spalling of oxide scales was observed under the present conditions. Due to the precipitation of Hf-containing carbides which can increase the adhesion of scales and its segregation to Al 2 O 3 grain boundaries during cyclic oxidation to hinder outward migration of Al, leading to slower growth rate of scales. During the long-time (8–200 h) cyclic oxidation process of the solution treated alloy, O atoms continuously diffused towards the matrix along the pores in scales, resulting in thickening of Al 2 O 3 layer. Moreover, thickening of Al 2 O 3 layer also hindered the outward diffusion of Ni and a small amount of NiO was observed on surface of specimen after long-term cyclic oxidation, meaning the improvement of oxidation resistance. • The oxidation behavior occurs on the interface area firstly. • Hf-containing carbides increase the adhesion force of scale. • Solution elements and thermal expansion affect the oxidation behavior. [ABSTRACT FROM AUTHOR]