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Composting municipal food waste is a key strategy for beneficially reusing methane-producing waste that would otherwise occupy landfill space. However, land-applied compost can cycle per- and polyfluoroalkyl substances (PFAS) back into the food supply and the environment. We partnered with a pilot-scale windrow composting facility to investigate the sources and fate of 40 PFAS in food waste compost. A comparison of feedstock materials yielded concentrations of ∑PFAS under 1 ng g -1 in mulch and food waste and at 1380 ng g -1 in leachate from used compostable food contact materials. Concentrations of targeted ∑PFAS increased with compost maturity along the windrow (1.85-23.1 ng g -1 ) and in mature stockpiles of increasing curing age (12.6-84.3 ng g -1 ). Among 15 PFAS quantified in compost, short-chain perfluorocarboxylic acids (PFCAs) - C5 and C6 PFCAs in particular - led the increasing trend, suggesting biotransformation of precursor PFAS into these terminal PFAS through aerobic decomposition. Several precursor PFAS were also measured, including fluorotelomer carboxylic acids (FTCAs) and polyfluorinated phosphate diesters (PAPs). However, since most targeted analytical methods and proposed regulations prioritize terminal PFAS, testing fully matured compost would provide the most relevant snapshot of PFAS that could be land applied. In addition, removing co-disposed food contact materials from the FW feedstock onsite yielded only a 37 % reduction of PFAS loads in subsequent compost, likely due to PFAS leaching during co-disposal. Source-separation of food contact materials is currently the best management practice for meaningful reduction of PFAS in food waste composts intended for land application., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: John A. Bowden reports financial support was provided by US Environmental Protection Agency. John A. Bowden reports financial support was provided by Hinkley Center for Solid and Hazardous Waste Management. Timothy G. Townsend reports financial support was provided by US Environmental Protection Agency. Timothy G. Townsend reports financial support was provided by Hinkley Center for Solid and Hazardous Waste Management. Co-author Stephan Barron is the owner and operator of the composting facility from which samples for this study were collected. We felt that it was important to include Stephan as a co-author because he had to facilitate our access to sample collection and provide information about his composting process, which was then incorporated into the manuscript. Stephan was not involved in any way in sample processing, data analysis and interpretation, or manuscript writing. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

This study investigated the behavior of per- and polyfluoroalkyl substances (PFAS) in multiple pilot-scale vertical flow constructed wetlands (VFCW) treating landfill leachate. Eight pilot-scale VFCW columns planted with Typha latifolia or Scirpus Californicus were fed untreated municipal solid waste (MSW) landfill leachate that was diluted with potable water at a 1:10 ratio (1 part leachate to 10 parts total) at a fixed daily hydraulic loading rate of 0.525 m d -1 . Ninety-two PFAS were examined and 18 PFAS were detected at quantifiable concentrations (7 precursor species and 11 terminal species). The average concentration of Σ 92 PFAS in the influent was 3,100 ng L -1 , which corresponded with minimal reduction in the effluents from the four VFCW (decreases ranged from 1% to 12% on average for Σ 18 PFAS); however, precursors 6:3 FTCA, 7:3 FTCA, N-MeFOSAA, and N-EtFOSAA concentrations decreased significantly in the VFCW effluents, and significant decreases in the concentrations of these PFAA-precursors were concurrent with a significant increase in concentrations of five PFAAs (PFBA, PFNA, PFBS, PFOS, and PFOSI). This trend indicates that from a regulatory perspective, standalone VFCWs are likely to produce an apparent PFAS increase, which may also be true for many other leachate treatment processes incorporating aerobic biological treatment. Additional treatment to address PFAS should be integrated prior to the use of any system, including VFCWs, for the treatment of constituents of concern in MSW landfill leachate., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Construction and demolition (C&D) wood can be recycled as mulch for landscaping or cogeneration. Limitations to such recycling are dependent on metals concentrations in mulch (As, Cu, and Cr) from the inclusion of waterborne-preservative treated wood. The objective of this study was to evaluate the amount of waterborne-preservative treated wood (by wood volume and by mass of metal) that enters the C&D wood waste stream in the U.S. by utilizing a mass balance approach. A model was developed using wood treatment industry production statistics, estimated leaching rates of metal-based preservatives, and typical service lives of wood products. Outputs of the model indicate that the volumes of waterborne preservative treated wood disposed of may exceed 16 million m 3 per year by 2030. The peak yearly metal mass disposed of corresponded to 18,400 metric tons for arsenic and 24,500 tons of chromium in 2013. Given the current trends in production, the mass of copper disposed of will increase to 20,900 tons by 2030. In order to meet regulatory guidelines regarding metals in recycled C&D wood, waterborne-preservative treated wood must be separated and removed. This separation mitigates environmental contamination from wood preservatives such as chromated copper arsenate (CCA)., (Copyright © 2019 Elsevier Ltd. All rights reserved.)