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Biochar as a filtering media has been attracted increasing attention for applications in urban storm-water runoff (USWR) management. Up-flow percolation tests were conducted with pine bark (PB) and biochars from PB (BCPB) for evaluating changes in dissolved organic carbon (DOC) and total dissolved nitrogen (TDN) concentrations varying with pyrolysis temperatures (i.e., 300, 450, and 700 °C) and types of USWR (i.e., roof and pathway USWR). The most suitable pyrolysis temperature for limiting DOC leaching from BCPB depends on the types of USWR. For all the adopted pyrolysis temperature, BCPB released cumulative amount of DOC up to 0.01% of the TC content in the up-flow percolation tests with pathway USWR. High-temperature (i.e., 700 °C) BCPB released lower cumulative amount of DOC (up to 0.02% of the TC content) compared to the low-temperature (

Three biodegradable materials (i.e. wood chips (WC), digested sewage sludge (DSS), and lignin (LG)) obtained as by-products of industrial processes were selected for biochar (BC) production under slow pyrolysis conditions at 450 and 700 °C. At 450 °C, the analysed trace metals (Cd, Cr, Cu, Ni, Pb, and Zn) showed the same temperature trend with concentrations which varied depending on the feedstock, increasing in BCs from WC (by as much as 191 %) and DSS (by as much as 288 %) and decreasing in BC from LG (by as much as 46 %). At 700 °C, in all the BCs, the total concentration of Ni, Pb, and Zn increased (by as much as 135, 248, 283 %, respectively) and Cr decreased (by as much as 69 %) whereas the total concentration of Cd and Cu increased or decreased depending on the feedstock. The most suitable pyrolysis temperature for reducing trace metal leachability and bioavailability (450 or 700 °C) depends on the trace metal considered. The temperature of 450 °C was effective in stabilising Cr and Ni in the analysed BCs as these trace metals were not prone to leaching or present in bioavailable forms. In all the BCs, an increase in pyrolysis temperature made trace metals such as Zn and Cu more stable in the char matrix, decreasing in the bioavailable fractions, hindering leachability of Zn, and decreasing leachability of Cu to less than 1 % of the total Cu concentration. Trace metals such as Cd and Pb did not show a clear temperature trend, increasing or decreasing in the bioavailable or leachable fractions depending on the feedstock.

The application of biochar as a sustainable material in biofilters to remove volatile compounds from the air provides a lot of advantages in relation to equipment maintenance and efficiency and ensures a zero-emission process. This work has analysed the morphology of biochar produced from birch and pine at different temperatures, its pore structure and changes depending on the type of pollutant and microorganisms used in biofiltrating media. Biochar morphology was investigated by scanning electron microscopy, while biochar pore structure was analysed by mercury intrusion porosimetry and nitrogen absorption at 77 K. Performed tests have shown that the biggest surface area of pores is in the biochar from pine that underwent thermal treatment at 750 °C. It has been determined that the pore volume of pine biochar decreases when acetone, xylene and ammonia pollutants are being removed from air during biofiltration. The biggest changes occurred in the pores with a diameter of 2–20 μm. Meanwhile, after the treatment with the studied volatile compounds, the surface area of pine biochar mesopores with a diameter smaller than 0.05 μm increased.

During an extended period from 2010–2012 ambient air quality researches, concentration of nitrogen dioxide (NO2) in the air was measured applying the passive method. In order to evaluate the spatial distribution of pollutants and the major sources, 12 sampling sites across the region were chosen. Additionally, the seasonal changes of this pollutant under different meteorological conditions (air temperature, humidity, wind speed and direction) were investigated. The long-term study showed 3.8 times higher NO2 concentrations in the Mažeikiai urban area (24.2 μg m−3) as compared to other locations in the region (6.3 μg m−3). This confirms the assumption that the main source of NO2 in this area is motor vehicle exhaust fumes. The analysis of the results obtained in different seasons showed a significant difference (p