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Adsorption and redox reactions between organic matter and natural reactive surfaces have a significant impact on pollutant sequestration and transformation, and on the effectivity of water and soil remediation practices. Herein, the interactions between an organic phenolic acid, gallic acid (GA), and clay coated with iron oxides (FeOx-MMT), were explored. Adsorption and desorption experiments revealed that GA has a higher affinity for FeOx-MMT than for native clay. The adsorption to FeOx-MMT was irreversible and only slightly affected by salinity, suggesting strong inner-sphere complexation. The GA-FeOx-MMT complex was characterized using cyclic-voltammetry, UV–Vis spectroscopy, FTIR, and XPS measurements. The results showed oxidation and transformation of GA on the surface and a considerable reduction of the surface iron. The resulting GA-FeOx-MMT complex had increased catalytic properties, enhancing hydrogen peroxide decomposition, and creating significantly more radicals than FeOx-MMT and raw clay. This led to the destruction of GA on the surface of the clay-iron complex, resulting in loss of activity over time. Our findings suggest a correlation between overall GA adsorption, consequent iron reduction and oxidant decomposition. This means that in systems where such constituents are present, these types of interactions need to be taken into consideration in terms of predicting the fate of pollutants in the environment, and for properly evaluating soil and water chemical treatment processes.

Atrazine removal from water by two polycations pre-adsorbed on montmorillonite was studied. Batch experiments demonstrated that the most suitable composite poly (4-vinylpyridine-co-styrene)-montmorillonite (PVP-co-S90%-mont.) removed 90-99% of atrazine (0.5-28 ppm) within 20-40 min at 0.367% w/w. Calculations employing Langmuir's equation could simulate and predict the kinetics and final extents of atrazine adsorption. Column filter experiments (columns 20x1.6 cm) which included 2g of the PVP-co-S90%-mont. composite mixed with excess sand removed 93-96% of atrazine (800 ppb) for the first 800 pore volumes, whereas the same amount of granular activated carbon (GAC) removed 83-75%. In the presence of dissolved organic matter (DOM; 3.7 ppm) the efficiency of the GAC filter to remove atrazine decreased significantly (68-52% removal), whereas the corresponding efficiency of the PVP-co-S90%-mont. filter was only slightly influenced by DOM. At lower atrazine concentration (7 ppb) the PVP-co-S90%-mont. filter reduced even after 3000 pore volumes the emerging atrazine concentration below 3 ppb (USEPA standard). In the case of the GAC filter the emerging atrazine concentration was between 2.4 and 5.3 microg/L even for the first 100 pore volumes. Thus, the PVP-co-S90%-mont. composite is a new efficient material for the removal of atrazine from water.