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Water scarcity has become a global issue that has forced many communities to seek alternative water resources. The majority of water on the earth's surface comes from the sea. Seawater has the potential to mitigate water stress after proper treatment. In Hong Kong, seawater has been used directly for toilet flushing for more than 50 years and the seawater toilet flushing (SWTF) system serves 80% of the residents. However, its environmental feasibility remains unknown. This study is a pioneer evaluating the environmental performances of the SWTF system by comparing SWTF with other alternative water resources including desalinated seawater, desalinated wastewater effluent, centralized wastewater reclamation and on-site greywater reclamation systems, while the conventional long-distance imported water scenario is set as the baseline for comparison. This evaluation is first conducted in the Southern District and North New Territory in Hong Kong, demonstrating SWTF is significantly more environmentally-friendly than other alternative water resources, which is the only alternative water resource application approach with environmental impacts comparable with the conventional long-distance imported water scenario. On the contrary, other alternative water resources application approaches would result in additional environmental impacts. Seaside distances and effective population density are two major geographical impact factors effecting the environmental impacts of different water systems in these two districts. The benefits obtained from SWTF in fourteen cities in South China are further investigated. It is confirmed that SWTF can significantly relieve water stress with the lowest environmental impacts comparing with other alternative options in these cities if alternative water resources must be applied for domestic usage. However, the assessment from different aspects should be further conducted to compare these alternative water resources. Image 1 • Environmental impacts of seawater toilet flushing are evaluated for the first time. • Human toxicity effects drop 30–55% with coal in total fuel reducing from 20 to 10%. • Seaside distances and population density are two major impact factors. • Replacing iron pipe material with PE can further reduce 80% of environmental impacts. • SWTF is feasible to be applied in South China to save water and reduce CO 2 emission. [ABSTRACT FROM AUTHOR]

Greywater recycling and rainwater harvesting have the potential to increase the resilience of water management and reduce the need for investment in conventional water supply schemes. However, their water-savings would partly depend on the location and built-form of urban development and hence its household sizes and rainwater per dwelling. We have therefore tested how spatial planning options would affect the future viability of alternative water supply in the Greater South East of England. Our integrated modelling framework, for the first time, forecasts the future densities and variability of built-form to provide inputs to the modelling of alternative water supply. We show that using projections of the existing housing stock would have been unsound, and that using standard dwelling types and household sizes would have substantially overestimated the water-savings, by not fully representing how the variability in dwelling dimensions and household-sizes would affect the cost effectiveness of these systems. We compare the spatial planning trend over a 30 year period with either compaction at higher densities within existing urban boundaries, or market-led more dispersed development. We show how the viability of alternative water supply would differ between these three spatial planning options. The water-savings of rainwater harvesting would vary greatly at a regional scale depending on residential densities and rainfall. Greywater recycling would be less affected by spatial planning but would have a finer balance between system costs and water-savings and its feasibility would vary locally depending on household sizes and water efficiency. The sensitivity of the water savings to differences in rainfall and water prices would vary with residential density. The findings suggest that forecasts of residential densities, rainfall and the water price could be used in conjunction with more detailed local studies to indicate how spatial planning would affect the future water saving potential of alternative water supply. Image 1 The original contributions of this paper to the literature include: • Novel regional-scale method of modelling greywater recycling & rainwater harvesting. • Using standard dwelling types and occupancies would overestimate the water savings. • Spatial planning would have a bigger effect on the water savings of RWH than on GWR. • RWH would be enhanced by dispersed development and communal-GWR by urban compaction. • Sensitivity of water savings to price and rainfall varies with residential density. [ABSTRACT FROM AUTHOR]

The reuse of water in a range of potable and non-potable applications is an important factor in the augmentation of water supply and in improving water security and productivity worldwide. A key hindrance to the reuse of water is the cost of compliance testing and process validation associated with ensuring that pathogen and chemicals in the feedwater are removed to a level that ensures no acute or chronic health and/or environmental effects. The critical control point (CCP) approach is well established and widely adopted by water utilities to provide an operational and risk management framework for the removal of pathogens in the treatment system. The application of a CCP approach to barriers in a treatment system for the removal of chemicals is presented. The application exemplar is to a small community wastewater treatment system that aims to produce potable quality water from a secondary treated wastewater effluent, however, the concepts presented are generic. The example used seven treatment barriers, five of which were designed and operated as CCP barriers for pathogens. The work demonstrates a method and risk management framework by which three of the seven barriers could also include a CCP approach for the removal of chemicals. Analogous to a CCP approach for pathogens, the potential is to reduce the use of chemical analysis as a routine determinant of performance criteria. The operational deployment of a CCP approach for chemicals was augmented with the development of a decision tree encompassing the classification of chemicals and the total removal credits across the treatment train in terms of the mechanistic removal of chemicals for each barrier. Validation of the approach is shown for an activated sludge, ozone and reverse osmosis barrier. Image 1 • A critical control point approach for the removal of chemicals in water recycle is presented. • The critical control point approach is detailed for three barriers. • A combined chemical log reduction value credits approach is demonstrated for a multi-barrier plant. [ABSTRACT FROM AUTHOR]

Antibiotic resistance genes (ARGs) have been regarded as an emerging pollutant in municipal wastewater treatment plant (WWTP) effluents due to their potential risk to human health and ecological safety when reused for landscape and irrigation. Conventional wastewater treatment processes generally fail to effectively reduce ARGs, especially extracellular ARGs (eARGs), which are persistent in the environment and play an important role in horizontal gene transfer via transformation. Herein, an integrated process of pre-coagulation and microfiltration was developed for removal of ARGs, especially eARGs, from wastewater effluent. Results show that the integrated process could effectively reduce the absolute abundances of total ARGs (tARGs) (>2.9 logs) and eARGs (>5.2 logs) from the effluent. The excellent performance could be mainly attributed to the capture of antibiotic resistant bacteria (ARB) and eARGs by pre-coagulation and co-rejection during subsequent microfiltration. Moreover, the integrated process exhibited a good performance on removing common pollutants (e.g., dissolved organic carbon and phosphate) from the effluent to improve water quality. Besides, the integrated process also greatly reduced membrane fouling compared with microfiltration. These findings suggest that the integrated process of pre-coagulation and microfiltration is a promising advanced wastewater treatment technology for ARGs (especially eARGs) removal from WWTP effluents to ensure water reuse security. Image 1 • Integrated pre-coagulation and microfiltration effectively reduced tARGs and eARGs. • Capture of ARB and eARGs by Fe-coagulated flocs enhanced ARGs removal. • Pre-coagulation effectively mitigated membrane fouling. [ABSTRACT FROM AUTHOR]

The intermittent nature of stormwater runoff impacts the treatment performance of biofilters, also known as stormwater biofiltration or bioretention systems and raingardens. During extended dry periods, which are common even in temperate climates, plants can perish, creating unattractive and non-functional systems that might leach pollutants during the next rainfall event. The current solution is to irrigate during long dry spells, which is costly and unsustainable as biofilters become more widespread. This paper presents the development of dual-mode biofilters, where stormwater and greywater are treated within the same system. Fifty columns, utilising eight plant species, including understory and climbing ornamentals, and designs with and without a carbon source in the submerged zone, were subjected to alternating greywater and stormwater inflows over five months. Six sampling events investigated treatment performance across these switching inflows and an extended dry period (atypical event). Good removal of total suspended solids (>83%), biochemical oxygen demand (>86%) and some heavy metals (e.g. lead >96%) were reported irrespective of design. Plant species selection was critical for the removal of nitrogen (2 to 79%) and phosphorus (12 to 75%) under dual-mode operation. However, following the extended dry period, plants with the lowest nutrient outflow concentrations also experienced some of the highest sediment and carbon concentrations, suggesting that a mixture of plant species may be beneficial for withstanding abnormal conditions. Differences between the treatment performance of designs with and without a carbon source were negligible, with potential benefits possibly negated due to the increased root mass that comes with age (systems were approximately two years old) and the release of carbon from root exudates. The results demonstrate the potential for dual-mode stormwater-greywater biofilters as an alternative to single-mode systems as they can provide effective treatment, along with greater volumes of treated water, while maintaining system performance throughout the year. Image 1 • Dual-mode stormwater-greywater biofilters can provide effective treatment. • High removal of sediment, carbon and some heavy metals irrespective of design. • Plant species selection is vital for effective removal of nitrogen and phosphorus. • No practical significance for including a carbon source in the saturated zone. • Ornamental and climbing plants can be utilised in dual-mode biofilters. [ABSTRACT FROM AUTHOR]

• Aeration-free microalgae-bacteria biofilm achieves energy-efficient greywater treatment. • Low residual linear alkylbenzene sulfonates led to low O 2 consumption but high microalgae content. • High biofilm activity led to high molecular weight and CHONS in dissolved organic nitrogen (DON). • Nitrogen was largely fixed to newly synthesized biomass during assimilation process. • High O 2 generation rate favored efficient pollutants removal and effluent DON reduction. Non-aeration microalgae-bacteria biofilm has attracted increasing interest for its application in low cost wastewater treatment. However, it is unclear the quantified biofilm characteristics dynamics and how biofilm bioactivity affects performance and nitrogen metabolisms during wastewater treatment. In this work, a push-flow microalgae-bacteria biofilm reactor (PF-MBBfR) was developed for aeration-free greywater treatment. Comparatively, organic loading at 1.27 ± 0.10 kg COD/(m3⋅d) gave the highest biofilm concentration, density, specific oxygen generation (SOGR) and consumption rates (SOCR), and pollutants removal rates. Contributed to low residual linear alkylbenzene sulfonates and bioactivity, reactor downstream showed low bacteria and protein concentrations and SOCR (12.8 mg O 2 /g TSS·h), but high microalgae, carbohydrate, biofilm density, SOGR (49.4 mg O 2 /g TSS·h) and pollutants removal rates. Dissolved organic nitrogen (DON) showed higher molecular weight, CHONS and fraction with 4 atoms of N in reactor upstream. Most of nitrogen was fixed to newly synthesized biomass during assimilation process by related functional enzymes, minor contributed to denitrification due to low N 2 emission. High nitrogen assimilation by microalgae showed high SOGR, which favored efficient multiple pollutants removal and reduced DON emission. Our findings favor the practical application of PF-MBBfR based on biofilm bioactivity, enhancing efficiency and reducing DON emission for low- energy-input wastewater treatment. [Display omitted] [ABSTRACT FROM AUTHOR]

Greywater (GW), domestic wastewater excluding the streams generated by toilets and kitchens, can serve as an alternative water source. The main options for GW reuse are toilet flushing and garden irrigation, both generating aerosols. These may transmit inhalable pathogens like Legionella and present a potential health risk. This study quantified the health risk that may arise from inhalation of Legionella- contaminated aerosols due to non-potable GW reuse. Data on Legionella concentrations in potable water and GW was collected. Then, Quantitative Microbial Risk Assessment (QMRA) was performed for two possible exposure scenarios: garden irrigation and toilet flushing. This was performed while considering Legionella seasonality. In order to determine the safety of GW reuse regarding Legionella transmission, the obtained results were compared with estimated tolerable risk levels of infection and of disease. Both limits were expressed as Disability-Adjusted Life Years index (DALY) being 10 −4 and 10 −5 , respectively. The QMRA revealed that the annual risk associated with reuse of treated and chlorinated GW for garden irrigation and toilet flushing was not significantly higher than the risk associated with using potable water for the same two purposes. In all studied scenarios, the health risk stemming from reusing treated and chlorinated GW was acceptable regarding Legionella infection. In contrast, reuse of untreated or treated but unchlorinated GW should not be practiced, as these are associated with significantly higher health risks. [ABSTRACT FROM AUTHOR]

Greywater is being increasingly used as an alternative water source to reduce potable water demand and to alleviate pressure on sewerage systems. This paper presents the development of a low energy and low maintenance greywater treatment technology: a living wall system, employing ornamental plants (including vines) grown in a sand filter on a side of a building to treat shower, bath, and washing basin wastewaters. The system can, at the same time, provide critical amenity and micro-climate benefits to our cities. A large scale column study was conducted in Melbourne, Australia, to investigate the following design and operational factors of the proposed system: plant species, saturated zone design, rest period, hydraulic loading rate and pollutant inflow concentration. The results indicate that the use of ornamental species (e.g. Canna lilies , Lonicera japonica , ornamental grape vine) can contribute to pollutant removal. Vegetation selection was found to be particularly important for nutrient removal. While a wider range of tested plant species was effective for nitrogen removal (>80%), phosphorus removal was more variable (−13% to 99%) over the study period, with only a few tested plants being effective - Carex appressa and Canna lilies were the best performers. It was also found that phosphorus removal can be compromised over the longer term as a result of leaching. Excellent suspended solids and organics removal efficiencies can be generally achieved in these systems (>80% for TSS and >90% for BOD) with plants having a relatively small impact. Columns had an acceptable infiltration capacity after one year of operation. When planted with effective species (e.g. Carex appressa and Canna lilies ), it is expected that performance will not be significantly affected by longer rest periods and higher pollutant concentrations in the early years of system operation. The results of this study, thus, demonstrate that innovative and aesthetically pleasing living walls can be designed for treatment of greywater at the household scale. [ABSTRACT FROM AUTHOR]

• Coupling of electrochemical or UV disinfection with MBR or MBBR greywater treatment. • MBR required 10-times lower reactor volume than the MBBR for same greywater feed. • Using ceramic membranes in MBR decreased fouling compared to polymeric ones. • UV was less sensitive to effluent quality than EC, but provided no residual disinfectant. • A fit-for-use approach was proposed, leveraging the respective system advantages. Greywater is an attractive source for water reuse at the household or building level, particularly for non-potable applications. Two greywater treatment approaches are membrane bioreactors (MBR) and moving bed biofilm reactors (MBBR), yet, their performance has not been compared so far within their respective treatment flowsheets, including post-disinfection. Two lab-scale treatment trains were operated on synthetic greywater: a) MBR with either polymeric (chlorinated polyethylene, C-PE, 165 days) or ceramic (silicon carbide, SiC, 199 days) membranes coupled with UV disinfection; and b) single-stage (66 days) or two-stage (124 days) MBBR coupled with an electrochemical cell (EC) for in-situ disinfectant generation. Water quality was constantly monitored, and Escherichia coli log removals were assessed through spike tests. Under low-flux operation of the MBR (<8 L· m −2· h −1), the SiC membranes delayed the onset of membrane fouling and needed less frequent cleaning compared to C-PE membranes. Both treatment systems met most water quality requirements for unrestricted greywater reuse, at a 10-fold lower reactor volume for the MBR than the MBBR. However, neither the MBR nor the two-staged MBBR allowed adequate nitrogen removal, and the MBBR did not consistently meet effluent chemical oxygen demand and turbidity requirements. Both EC and UV provided non-detectable E. coli concentrations in the effluent. Although the EC provided residual disinfection, scaling and fouling decreased its energetic and disinfection performance over time, making it less efficient than UV disinfection. Several outlines to improve the performance of both treatment trains and disinfection processes are proposed, thus, allowing a fit-for-use approach that leverages the advantages of the respective treatment trains. Results from this investigation will assist in elucidating the most efficient, robust, and low-maintenance technology and configurations for small-scale greywater treatment for reuse. [Display omitted] [ABSTRACT FROM AUTHOR]

• Two sets of risk-based treatment targets have been developed for onsite water sources. • Both approaches use the same modeling framework yet differ in pathogen assumptions. • Despite these differences, resulting pathogen log-reduction targets are similar. • The comparison highlights transparency and adaptability of the risk-based approach. • Future research should focus on collection of pathogen data for onsite water sources. Onsite non-potable water systems (ONWS) collect and treat local source waters for non-potable end uses such as toilet flushing and irrigation. Quantitative microbial risk assessment (QMRA) has been used to set pathogen log 10 -reduction targets (LRTs) for ONWS to achieve the risk benchmark of 10−4 infections per person per year (ppy) in a series of two efforts completed in 2017 and 2021. In this work, we compare and synthesize the ONWS LRT efforts to inform the selection of pathogen LRTs. For onsite wastewater, greywater, and stormwater, LRTs for human enteric viruses and parasitic protozoa were within 1.5-log 10 units between 2017 and 2021 efforts, despite differences in approaches used to characterize pathogens in these waters. For onsite wastewater and greywater, the 2017 effort used an epidemiology-based model to simulate pathogen concentrations contributed exclusively from onsite waste and selected Norovirus as the viral reference pathogen; the 2021 effort used municipal wastewater pathogen data and cultivable adenoviruses as the reference viral pathogen. Across source waters, the greatest differences occurred for viruses in stormwater, given the newly available municipal wastewater characterizations used for modeling sewage contributions in 2021 and the different selection of reference pathogens (Norovirus vs. adenoviruses). The roof runoff LRTs support the need for protozoa treatment, but these remain difficult to characterize due to the pathogen variability in roof runoff across space and time. The comparison highlights adaptability of the risk-based approach, allowing for updated LRTs as site specific or improved information becomes available. Future research efforts should focus on data collection of onsite water sources. [Display omitted] [ABSTRACT FROM AUTHOR]

Millions of decentralized graywater-reuse systems are operating worldwide. This water is directly accessible to household inhabitants, raising environmental and public health concerns. Graywater may contain a variety of harmful organisms, the types and numbers of which vary with source-type, storage time, and background levels of infection in the community source. In this review, we find that most studies indicate high amounts of microbial pathogens in raw graywater and therefore treatment and disinfection are recommended to lower possible health risks. Where these recommendations have been followed, epidemiological and quantitative microbial risk-assessment studies have found negligible health risks of bacterial pathogens in treated graywater. Chlorine is currently suggested as the most cost-effective disinfection agent for inactivating graywater bacterial pathogens and preventing regrowth. Various studies demonstrate that the introduction and diversity of pathogenic bacteria in the soil via irrigation can be affected by several factors, but treated graywater may not be a major contributor of bacterial contamination or antibiotic resistance. However, an accurate assessment of the infectious capabilities, exposure pathways, and resistance of specific pathogens, particularly viruses and antibiotic-resistant bacteria found in treated graywater after disinfection, as well as in the graywater piping, irrigated soils, plants, and associated aerosols is largely lacking in the literature. In addition, research shows that fecal bacterial indicators might not reliably indicate the presence or quantities of pathogens in graywater and thus, the indicator standard for graywater contamination should be revised. [ABSTRACT FROM AUTHOR]

In light of the increasing interest in development of sustainable potable reuse systems, additional research is needed to elucidate the risks of producing drinking water from new raw water sources. This article investigates the presence and potential health risks of organic micropollutants in greywater, a potential new source for potable water production introduced in this work. An extensive literature survey reveals that almost 280 organic micropollutants have been detected in greywater. A three-tiered approach is applied for the preliminary health risk assessment of these chemicals. Benchmark values are derived from established drinking water standards for compounds grouped in Tier 1, from literature toxicological data for compounds in Tier 2, and from a Threshold of Toxicological Concern approach for compounds in Tier 3. A risk quotient is estimated by comparing the maximum concentration levels reported in greywater to the benchmark values. The results show that for the majority of compounds, risk quotient values were below 0.2, which suggests they would not pose appreciable concern to human health over a lifetime exposure to potable water. Fourteen compounds were identified with risk quotients above 0.2 which may warrant further investigation if greywater is used as a source for potable reuse. The present findings are helpful in prioritizing upcoming greywater quality monitoring and defining the goals of multiple barriers treatment in future water reclamation plants for potable water production. [ABSTRACT FROM AUTHOR]

Abstract: Water shortage around the world enhanced the search for alternative sources. Greywater (GW) can serve as a solution for water demands especially in arid and semi-arid zones. However, issues considered which include acceptability of GW segregation as a separate water treated stream, allowing its use onsite. Consequently, it is the one of next forthcoming water resources that will be used, primarily in the growing mega-cities. It will be even more rentable when combined with the roof runoff water harvesting and condensing water from air-conditioning systems. Reuse of GW is as well beneficial in the mega-cities subject to the high expenses associated with wastewater and fresh water conveyance in the opposite direction. The main problem associated with GW reuse is the quality of the water and the targeted reuse options. At least two main options can be identified: the public sector that is ready to reuse the GW and the private sector which raises extra issues related to the reuse risks. These risk stems from the on yard use of GW, relatively close to the household location. The main focus of the Israeli guidelines for GW use is on the private and single house. The problem is less rigorous in public facilities, where the amounts are relatively large and the raw GW is relatively diluted. The two main principles adopted for reuse are: (i) greywater can be minimally treated since it differs from the black wastes, and; (ii) no contact exists with the resident around. The aggravated standards are an indication of the sensitivity issues related to the problem. [Copyright &y& Elsevier]

This study explored the effects of greywater application on the dynamics and functions of biofilms developed in bark, activated charcoal and sand filters used for removal of organic matter and nitrogen. Duplicate columns (20 cm diameter, 60 cm deep) were packed with bark, charcoal or sand with effective size 1.4 mm and uniformity coefficient 2.2, and dosed with 32 L m−2 day−1 of an artificial greywater (14 g BOD5 m−2 day−1) for 116 days. Potential respiration rate (PRR), determined in filter samples after addition of excess glucose, and bacterial diversity and composition, analysed by 454-pyrosequencing of bacterial 16S ribosomal DNA, were measured at different times and depths in the filters. The bark and charcoal filters were more efficient in removing BOD5 than the sand (98, 97% and 75%, respectively). The highest PRR in the 0–2 cm layer of the columns on day 84 was found in the bark filters, followed by the charcoal and sand filters (632 ± 66, 222 ± 34 and 56 ± 2 mg O2 L−1, respectively; n = 2). Bacterial community in the bark filters showed the highest richness. The charcoal and sand filters both developed more diverse and dynamic (changing over time and depth) bacterial communities than the bark. In addition to the greywater, the lignocelluosic composition of the bark and its lower pH probably selected for the bacterial community structure and the organic content provided additional substrate, as shown by its higher PRR and its different nitrifying bacterial genera. In the oligotrophic charcoal and sand, the composition of the greywater itself defined the bacterial community. Thus, the initially low bacterial biomass in the latter filters was enriched over time, allowing a diversified bacterial community to develop. The top layers of the bark and charcoal filters displayed a high dominance of Rhizobium, Pseudomonas and Acinetobacter, which were less evident in the 60 cm layer, whereas in the sand filters these genera were prominent at both 0–2 cm and 60 cm. The PRR, bacterial diversity and composition profiles indicated that organic matter degradation occurred mainly in the top 20 cm of the bark and charcoal filters. This means that bark and charcoal filters could be designed to be shallower than sand filters. [ABSTRACT FROM AUTHOR]

Abstract: Sustainable design and implementation of greywater reuse (GWR) has to achieve an optimum compromise between costs and potable water demand reduction. Studies show that GWR is an efficient tool for reducing potable water demand. This study presents a multi-objective optimization model for estimating the optimal distribution of different types of GWR homes in an existing municipal sewer system. Six types of GWR homes were examined. The model constrains the momentary wastewater (WW) velocity in the sewer pipes (which is responsible for solids movement). The objective functions in the optimization model are the total WW flow at the outlet of the neighborhoods sewer system and the cost of the on-site GWR treatment system. The optimization routing was achieved by an evolutionary multi-objective optimization coupled with hydrodynamic simulations of a representative sewer system of a neighborhood located at the coast of Israel. The two non-dominated best solutions selected were the ones having either the smallest WW flow discharged at the outlet of the neighborhood sewer system or the lowest daily cost. In both solutions most of the GWR types chosen were the types resulting with the smallest water usage. This lead to only a small difference between the two best solutions, regarding the diurnal patterns of the WW flows at the outlet of the neighborhood sewer system. However, in the upstream link a substantial difference was depicted between the diurnal patterns. This difference occurred since to the upstream links only few homes, implementing the same type of GWR, discharge their WW, and in each solution a different type of GWR was implemented in these upstream homes. To the best of our knowledge this is the first multi-objective optimization model aimed at quantitatively trading off the cost of local/onsite GW spatially distributed reuse treatments, and the total amount of WW flow discharged into the municipal sewer system under unsteady flow conditions. [Copyright &y& Elsevier]

Abstract: The reuse of domestic greywater has become common in Australia, especially during periods of extreme drought. Greywater is typically used in a raw, untreated form, primarily for landscape irrigation, but more than a quarter of greywater users irrigate vegetable gardens with the water, despite government advice against this practice. Greywater can be contaminated with enteric pathogens and may therefore pose a health risk if irrigated produce is consumed raw. A quantitative microbial risk assessment (QMRA) model was constructed to estimate the norovirus disease burden associated with consumption of greywater-irrigated lettuce. The annual disease burdens (95th percentile; DALYs per person) attributed to greywater irrigation ranged from 2 × 10−8 to 5 × 10−4, depending on the source of greywater and the existence of produce washing within households. Accounting for the prevalence of produce-washing behaviours across Melbourne, the model predicted annual disease burdens ranging from 4 × 10−9 for bathroom water use only to 3 × 10−6 for laundry water use only, and accounting for the proportionate use of each greywater type, the annual disease burden was 2 × 10−6. We recommend the preferential use of bathroom water over laundry water where possible as this would reduce the annual burden of disease to align with the current Australian recycled water guidelines, which recommend a threshold of 10−6 DALYs per person. It is also important to consider other exposure pathways, particularly considering the high secondary attack rate of norovirus, as it is highly likely that the estimated norovirus disease burden associated with greywater irrigation of vegetables is negligible relative to household contact with an infected individual. [Copyright &y& Elsevier]

Abstract: A monitoring program was undertaken to assess the microbial quality of greywater collected from 93 typical households in Melbourne, Australia. A total of 185 samples, comprising 75 washing machine wash, 74 washing machine rinse and 36 bathroom samples were analysed for the faecal indicator Escherichia coli. Of these, 104 were also analysed for genetic markers of pathogenic E coli and 111 for norovirus (genogroups GI and GII), enterovirus and rotavirus using RT-PCR. Enteric viruses were detected in 20 out of the 111 (18%) samples comprising 16 washing machine wash water and 4 bathroom samples. Eight (7%) samples were positive for enterovirus, twelve (11%) for norovirus genogroup GI, one (1%) for norovirus genogroup GII and another (1%) for rotavirus. Two washing machine samples contained more than one virus. Typical pathogenic E. coli were detected in 3 out of 104 (3%) samples and atypical enteropathogenic E. coli in 11 (11%) of samples. Levels of indicator E. coli were highly variable and the presence of E. coli was not associated with the presence of human enteric viruses in greywater. There was also little correlation between reported gastrointestinal illness in households and detection of pathogens in greywater. [Copyright &y& Elsevier]

Abstract: Ozonation and adsorption onto activated carbon were tested for the removal micropollutants of personal care products from aerobically treated grey water. MilliQ water spiked with micropollutants (100–1600 μgL−1) was ozonated at a dosing rate of 1.22. In 45 min, this effectively removed (>99%): Four parabens, bisphenol-A, hexylcinnamic aldehyde, 4-methylbenzylidene-camphor (4MBC), benzophenone-3 (BP3), triclosan, galaxolide and ethylhexyl methoxycinnamate. After 60 min, the removal efficiency of benzalkonium chloride was 98%, tonalide and nonylphenol 95%, octocrylene 92% and 2-phenyl-5-benzimidazolesulfonic acid (PBSA) 84%. Ozonation of aerobically treated grey water at an applied ozone dose of 15 mgL−1, reduced the concentrations of octocrylene, nonylphenol, triclosan, galaxolide, tonalide and 4-methylbenzylidene-camphor to below limits of quantification, with removal efficiencies of at least 79%. Complete adsorption of all studied micropollutants onto powdered activated carbon (PAC) was observed in batch tests with milliQ water spiked with 100–1600 μgL−1 at a PAC dose of 1.25 gL−1 and a contact time of 5 min. Three granular activated carbon (GAC) column experiments were operated to treat aerobically treated grey water. The operation of a GAC column with aerobically treated grey water spiked with micropollutants in the range of 0.1–10 μgL−1 at a flow of 0.5 bed volumes (BV)h−1 showed micropollutant removal efficiencies higher than 72%. During the operation time of 1728 BV, no breakthrough of TOC or micropollutants was observed. Removal of micropollutants from aerobically treated grey water was tested in a GAC column at a flow of 2 BVh−1. Bisphenol-A, triclosan, tonalide, BP3, galaxolide, nonylphenol and PBSA were effectively removed even after a stable TOC breakthrough of 65% had been reached. After spiking the aerobically treated effluent with micropollutants to concentrations of 10–100 μgL−1, efficient removal to below limits of quantification continued for at least 1440 BV. Both ozonation and adsorption are suitable techniques for the removal of micropollutants from aerobically treated grey water. [Copyright &y& Elsevier]

Abstract: An increasing worldwide interest in water recycling technologies such as greywater treatment and reuse suggests that additional research to elucidate the fate of xenobiotics during such practices would be beneficial. In this paper, scenario analyses supported by empirical data are used for highlighting the potential fate of a selection of xenobiotic micropollutants in decentralised greywater treatment systems, and for investigation of the possible implications of greywater recycling for the wider urban water cycle. Potential potable water savings of up to 43% are predicted for greywater recycling based on Danish water use statistics and priority substance monitoring at a greywater treatment plant in Denmark. Adsorption represents an important mechanism for the removal of cadmium, nickel, lead and nonylphenol from influent greywater and therefore the disposal route adopted for the generated sludge can exert a major impact on the overall efficiency and environmental sustainability of greywater treatment. [ABSTRACT FROM AUTHOR]

Abstract: Greywater treatment by UVC/H2O2 was investigated with regard to the removal of chemical oxygen demand (COD). A COD reduction from 225 to 30mgl−1 (overall removal of 87%) was achieved after settling overnight and subsequent irradiation for 3h with 10mM H2O2. Most of the contaminants were removed by oxidation since only 13% COD was removed by settlement. The removal of COD in the greywater followed a second-order kinetic equation, r =0.0637[COD][H2O2], up to 10mM H2O2. A slightly enhanced COD removal was observed at the initial pH of 10 compared with pH 3 and 7. This was attributed to the dissociation of H2O2 to O2H−. The treatment was not affected by total concentration of carbonate (cT) of at least 3mM, above which operation between pH 3 and 5 was essential. The initial biodegradability of the settled greywater (as BOD5:COD) was 0.22. After 2h UVC/H2O2 treatment, a higher proportion of the residual contaminants was biodegradable (BOD5:COD=0.41) which indicated its potential as a pre-treatment for a biological process. [Copyright &y& Elsevier]

Abstract: Fouling in membrane coupled photocatalytic reactors was investigated in the case of greywater treatment by establishing the link between product type, dose, irradiation time and fouling rates in a cross flow membrane cell fitted with a 0.4μm pore sized polyethylene membrane. Rapid fouling occurred only with shower gels and conditioners and was linked to changes in the organo-TiO2 aggregate size postulated to be caused by polymers within the products. Fouling was reduced to a negligible level when sufficient irradiation was applied demonstrating that the membrane component of the process is not the issue and that scale up and implementation of the process relates to effective design of the UV reactor. [Copyright &y& Elsevier]

Mass transfer coefficients (kLa) were studied in two pilot scale membrane bioreactors (MBR) with different setup configurations treating 200L/h of synthetic greywater with mixed liquor suspended solids'' (MLSS) concentrations ranging from 4.7 to 19.5g/L. Besides the MLSS concentration, mixed liquor volatile suspended solids (MLVSS), total solids (TS), volatile solids (VS), chemical oxygen demand (COD) and anionic surfactants of the sludge were measured. Although the pilot plants differed essentially in their configurations and aeration systems, similar α-factors at the same MLSS concentration could be determined. A comparison of the results to the published values of other authors showed that not the MLSS concentration but rather the MLVSS concentration seems to be the decisive parameter which influences the oxygen transfer in activated sludge systems operating at a high sludge retention time (SRT). [Copyright &y& Elsevier]

Urban water services, including drinking water supply and wastewater treatment, are highly energy dependent, contributing to the challenges described under the water-energy nexus. Both future climate change and decentralized water system adoptions can potentially influence the energy use of the urban water services. However, the trend and the extent of such influences have not been well understood. In this study, a modeling framework was developed to quantify both the separate and the combined influences of climate change and decentralization on the life cycle energy use of the urban water cycle, using the City of Boston, MA as a testbed. Two types of household decentralized systems were considered, the greywater recycling (GWR) systems and the rainwater harvesting (RWH) systems. This modeling framework integrates empirical models based on multilinear regression analysis, hydrologic modeling, water balance models, and life cycle assessment to capture the complex interactions among centralized water services, decentralized water system adoptions, and climate parameters for cumulative energy demand (CED) assessment, considering all residential buildings in Boston. It was found that climate change alone will slightly increase the energy use of the centralized systems towards the end of the century, due to the cancelation effect amongst changes in water quality, flow rate, and space and water heating demand. When decentralization is considered alone, we found economically viable decentralized systems may not necessarily produce energy savings. In fact, RWH adoptions may increase energy use. When climate change and decentralization are combined, they will increase the water yield and cost savings of the decentralized systems, while reducing the energy use from the centralized systems. When the centralized systems are further added into the picture, the CED of the entire urban water cycle is projected to increase by 0.9% or 2.3% towards the end of the century under climate change if GWR or RWH systems are adopted by respective cost saving positive buildings. • Developed a water-energy model for climate and decentralization effects. • Climate's impact on water quality, flow, and heating cancels out CED changes. • Full-scale GWR and RWH adoptions have opposite energy implications. • Climate change and decentralization combined will increase energy use by 0.9–2.3%. [Display omitted]. [ABSTRACT FROM AUTHOR]

The microbial quality of raw greywater was found to be much better than that of municipal wastewater, with 1.6×107 cfuml−1 heterotrophic plate count (HPC), and 3.8×104, 9.9×103, 3.3×103 and 4.6×100 cfu100ml−1 faecal coliforms (FC), Staphylococcus aureus sp., Pseudomonas aeruginosa sp. and Clostridium perfringes sp., respectively. Further, three viral indicators monitored (somatic phage, host: Escherichia coli CN13 and F-RNA phages, hosts: E. coli F+amp, E. coli K12) were not present in raw greywater. The greywater was treated by an RBC followed by sedimentation. The treatment removed two orders of magnitude of all bacteria. UV disinfection kinetics, survival and regrowth of HPC, FC, P. aeruginosa sp. and S. aureus sp. were examined. At doses up to 69mWscm−2 FC were found to be the most resistant bacteria, followed by HPC, P. aeruginosa sp. and S. aureus sp. (inactivation rate coefficients: 0.0687, 0.113, 0.129 and 0.201cm2 mW−1 s−1, respectively). At higher doses (69–439mWscm−2) all but HPC (which exhibited a tailing curve) were completely eliminated. Microscopic examination showed that FC self-aggregate in the greywater effluent. This provides FC an advantage at low doses, since the concentration of suspended matter (that can provide shelter from UV radiation) in the effluent was very low. FC, P. aeruginosa sp. and S. aureus sp. did not exhibit regrowth up to 6h after exposure to increasing UV doses (19–439mWscm−2). HPC regrowth was proven to be statistically significant in un-disinfected effluent and after irradiation with high UV doses (147 and 439mWscm−2). At these doses regrowth resulted from growth of UV-resistant bacteria due to decreased competition with other bacteria eliminated by the irradiation. [Copyright &y& Elsevier]

• An overview from the regulatory, technological and management aspects is provided. • The requirements on both water quantity and quality for irrigation are summarized. • Reuse of non-conventional water such as cooling and wastewater is evaluated. • Available water technologies, such as RO, CDI and UV, are comprehensively reviewed. • Three priority research directions based on the provided overviews are proposed. Due to the growing and diverse demands on water supply, exploitation of non-conventional sources of water has received much attention. Since water consumption for irrigation is the major contributor to total water withdrawal, the utilization of non-conventional sources of water for the purpose of irrigation is critical to assuring the sustainability of water resources. Although numerous studies have been conducted to evaluate and manage non-conventional water sources, little research has reviewed the suitability of available water technologies for improving water quality, so that water reclaimed from non-conventional supplies could be an alternative water resource for irrigation. This article provides a systematic overview of all aspects of regulation, technology and management to enable the innovative technology, thereby promoting and facilitating the reuse of non-conventional water. The study first reviews the requirements for water quantity and quality (i.e., physical, chemical, and biological parameters) for agricultural irrigation. Five candidate sources of non-conventional water were evaluated in terms of quantity and quality, namely rainfall/stormwater runoff, industrial cooling water, hydraulic fracturing wastewater, process wastewater, and domestic sewage. Water quality issues, such as suspended solids, biochemical/chemical oxygen demand, total dissolved solids, total nitrogen, bacteria, and emerging contaminates, were assessed. Available technologies for improving the quality of non-conventional water were comprehensively investigated. The potential risks to plants, human health, and the environment posed by non-conventional water reuse for irrigation are also discussed. Lastly, three priority research directions, including efficient collection of non-conventional water, design of fit-for-purpose treatment, and deployment of energy-efficient processes, were proposed to provide guidance on the potential for future research. [Display omitted] [ABSTRACT FROM AUTHOR]

• PFAS occurrence information is not available for most developing countries. • Monitoring is required for ultra-short chain and new generation replacement PFAS. • Majority of studies report higher PFAS concentrations in effluents than influents. • Biodegradation transforms PFAS precursors to PFAA at a secondary stage. • Adsorption, electrochemical, and filtration are the most studied PFAS treatments. Poly- and perfluoroalkyl substances (PFAS) comprise more than 4,000 anthropogenically manufactured compounds with widescale consumer and industrial applications. This critical review compiles the latest information on the worldwide distribution of PFAS and evaluates their fate in wastewater treatment plants (WWTPs). A large proportion (>30%) of monitoring studies in WWTPs were conducted in China, followed by Europe (30%) and North America (16%), whereas information is generally lacking for other parts of the world, including most of the developing countries. Short and long-chain perfluoroalkyl acids (PFAAs) were widely detected in both the influents (up to 1,000 ng/L) and effluents (15 to >1,500 ng/L) of WWTPs. To date, limited data is available regarding levels of PFAS precursors and ultra-short chain PFAS in WWTPs. Most WWTPs exhibited low removal efficiencies for PFAS, and many studies reported an increase in the levels of PFAAs after wastewater treatment. The analysis of the fate of various classes of PFAS at different wastewater treatment stages (aerobic and/aerobic biodegradation, photodegradation, and chemical degradation) revealed biodegradation as the primary mechanism responsible for the transformation of PFAS precursors to PFAAs in WWTPs. Remediation studies at full scale and laboratory scale suggest advanced processes such as adsorption using ion exchange resins, electrochemical degradation, and nanofiltration are more effective in removing PFAS (~95–100%) than conventional processes. However, the applicability of such treatments for real-world WWTPs faces significant challenges due to the scaling-up requirements, mass-transfer limitations, and management of treatment by-products and wastes. Combining more than one technique for effective removal of PFAS, while addressing limitations of the individual treatments, could be beneficial. Considering environmental concentrations of PFAS, cost-effectiveness, and ease of operation, nanofiltration followed by adsorption using wood-derived biochar and/or activated carbons could be a viable option if introduced to conventional treatment systems. However, the large-scale applicability of the same needs to be further verified. [Display omitted] [ABSTRACT FROM AUTHOR]

• Rainfall and AC condensate only partially meet large building non-potable demand • RWH and ACH systems require suitable climates to be competitive with MBR systems • MBR systems meet all non-potable demands but more heavily rely on electricity use • Benefits of thermal recovery to offset hot water heating greatly depend on grid mix • WWMBR systems are generally the most cost-competitive Onsite non-potable reuse (NPR) is a way for buildings to conserve water using onsite sources for uses like toilet flushing, laundry and irrigation. Although early case study results are promising, aspects like system suitability, cost and environmental performance remain difficult to quantify and compare across broad geographic contexts and variable system configurations. In this study, we evaluate four NPR system types – rainwater harvesting (RWH), air-conditioning condensate harvesting (ACH), and source-separated graywater and mixed wastewater membrane bioreactors (GWMBR, WWMBR) – in terms of their ability to satisfy onsite non-potable demand, their environmental impacts and their economic cost. As part of the analysis, we developed the Non-potable Environmental and Economic Water Reuse Calculator (NEWR), a publicly available U.S. EPA web application that allows users to generate planning-level estimates of system cost and environmental performance using location and basic building characteristics as inputs. By running NEWR for a range of scenarios, we find that, across the U.S., rainfall and air-conditioner condensate are only able to satisfy a fraction of the non-potable demand typical of large buildings even under favorable climate conditions. Environmental impacts of RWH and ACH systems depend on local climate and were comparable to the ones of MBR systems where annual rainfall exceeds approximately 10 in/yr or annual condensate potential exceeds approximately 3 gal/cfm. MBR systems can meet all non-potable demands but their environmental impacts depend more on the composition of the local energy grid, owing to their greater reliance on electricity inputs. Incorporation of thermal recovery to offset building hot water heating requirements amplifies the influence of the local grid mix on environmental impacts, with mixed results depending on grid composition and whether thermal recovery offsets natural gas or electricity consumption. Additional environmental benefits are realized when NPR systems are implemented in water scarce regions with diverse topography and regions relying on groundwater sources, which increases the benefits of reducing reliance on centralized drinking water services. In terms of cost, WWMBRs were found to have the lowest cost under the largest range of building characteristics and locations, achieving cost parity with local drinking water rates when those rates were more than $7 per 1000 gallons, which occurred in 19% of surveyed cities. Image, graphical abstract [ABSTRACT FROM AUTHOR]

• Literature information is used to complement local data via hierarchical modelling. • Different statistical approaches on performance target calculations are compared. • Depending on the statistical approach the required log-removal can vary by > 1log. • Model comparison by expected log-predictive density favors hierarchical modelling. • Benefits of hierarchical modelling largest in small (local) sample size situations. Probabilistic quantitative microbial risk assessment (QMRA) studies define model inputs as random variables and use Monte-Carlo simulation to generate distributions of potential risk outcomes. If local information on important QMRA model inputs is missing, it is widely accepted to justify assumptions about these model inputs by using external literature information. A question, which remains unexplored, is the extent to which previously published external information should influence local estimates in cases of nonexistent, scarce, and moderate local data. This question can be addressed by employing Bayesian hierarchical modeling (BHM). Thus, we study the effects and potential benefits of BHM on risk and performance target calculations at three wastewater treatment plants (WWTP) in comparison to alternative statistical modeling approaches (separate modeling, no-pooling, complete pooling). The treated wastewater from the WWTPs is used for restricted irrigation, potable reuse, or influences recreational waters, respectively. We quantify the extent to which external data affects local risk estimations in each case depending on the statistical modeling approach applied. Modeling approaches are compared by calculating the pointwise expected log-predictive density for each model. As reference pathogens and example data, we use locally collected Norovirus genogroup II data with varying sample sizes (n = 4, n = 7, n = 27), and complement local information with external information from 44 other WWTPs (n = 307). Results indicate that BHM shows the highest predictive accuracy and improves estimates by reducing parameter uncertainty when data are scarce. In such situations, it may affect risk and performance target calculations by orders of magnitude in comparison to using local data alone. Furthermore, it allows making generalizable inferences about new WWTPs, while providing the necessary flexibility to adjust for different levels of information contained in the local data. Applying this flexible technique more widely may contribute to improving methods and the evidence base for decision-making in future QMRA studies. [ABSTRACT FROM AUTHOR]

Greywater reuse can allow substantial improvements in the efficiency of potable water systems. However, widespread uptake of greywater reuse depends on its acceptability by the population. Previous studies have assessed the implementation costs of greywater reuse technology, and considered its acceptability in principle. Although cost is clearly very important in terms of adopting/installing the technology, the actual perception of greywater reuse is crucial in driving the acceptability of use and the long-term success of the technology. This study uses discrete choice models to quantify, for the first time, the preferences of different socio-economic groups for greywater of different quality (colour, odour) and for different uses inside homes. A stated choice survey that removed the influence of installation costs was developed, and implemented in Santiago, Chile. Although legislation allows greywater use in Santiago, it does not take place at any meaningful scale. Results show that, in decreasing order of preference, there is an overall acceptance for using high quality treated greywater for toilet flushing, laundry, garden irrigation, hand washing and, shower/bathtub use, but not for drinking. When the quality of appearance in terms of colour and odour gets worse, monetary incentives could be needed even for those uses that do not involve human contact. Gender, age, educational level, water expenditure level, and in particular previous knowledge about greywater reuse, are important determinants of acceptability and thus willingness to pay for greywater use; however, their importance varies according to the type of use. Our results provide important insights for understanding the conditions that would precipitate rapid and wide uptake of greywater reuse in cities, and thereby make better use of limited water resources. Image 1 • Choice modelling analysis of potential demand for greywater reuse in Santiago. • Big differences across potential types of reuse. • Substantial variation in acceptability across socio-demographic groups. • Monetary incentives required depend on quality of greywater, use, gender, education level, water reuse background. [ABSTRACT FROM AUTHOR]

Increased water demands have led to a notable interest in the use of treated wastewater for reuse. Typically, this results from the implementation of advanced treatment of final effluent from wastewater treatment plants prior to reuse for potable or non-potable purposes. Soil aquifer treatment (SAT) is a natural treatment process in which water from sources of varying quality is infiltrated into the soil to further improve its quality. The goal of this study was to determine the log 10 reduction values (LRVs) of viruses naturally present in treated effluent and evaluate two potential indicators of virus removal and transport, pepper mild mottle virus (PMMoV) and crAssphage, during SAT of treated effluent. Groundwater was sampled at three wells with different attributes within the Sweetwater Recharge Facility (SWRF) in Tucson, AZ. These sites vary greatly in operational parameters such as effluent infiltration rates and wetting/drying cycles, which may influence virus removal efficiency. Detection of adenovirus, enterovirus, PMMoV, and crAssphage were determined by qPCR/RT-qPCR and log 10 reduction values (LRVs) were determined. PMMoV and crAssphage were detected in groundwater associated with a set of recharge basins that exhibited shorter wetting/drying cycles and faster infiltration rates. LRVs for crAssphage and PMMoV at this site ranged from 3.9 to 5.8, respectively. Moreover, PMMoV was detected downflow of the SAT sites, indicating the potential degradation of microbial groundwater quality in the region surrounding managed aquifer recharge facilities. Overall, PMMoV and crAssphage showed potential as conservative process indicators of virus removal during SAT, particularly for attribution of LRV credits. Moreover, the detection of these viruses indicated the potential influence of wetting/drying cycles on virus removal by SAT, a parameter that has not yet been studied with respect to biological contaminants. Image 1 • Virus removal examined at three sites within soil aquifer (SAT) treatment facility. • Overall virus removal ranged from >3.4 to >6.2 • Virus detected from site with faster infiltration rates/shorter wet-dry cycles. • Pepper mild mottle virus and crAssphage have potential as process indicators of virus removal. • Pepper mild mottle virus detected in groundwater downflow of SAT facility. [ABSTRACT FROM AUTHOR]

Ion exchange is widely used to treat nitrate-contaminated groundwater, but high salt usage for resin regeneration and management of waste brine residuals increase treatment costs and add environmental burdens. Development of palladium-based catalytic nitrate treatment systems for brine treatment and reuse has showed promising activity for nitrate reduction and selectivity towards the N 2 over the alternative product ammonia, but this strategy overlooks the potential value of nitrogen resources. Here, we evaluated a hybrid catalytic hydrogenation/membrane distillation process for nitrogen resource recovery during treatment and reuse of nitrate-contaminated waste ion exchange brines. In the first step of the hybrid process, a Ru/C catalyst with high selectivity towards ammonia was found to be effective for nitrate hydrogenation under conditions representative of waste brines, including expected salt buildup that would occur with repeated brine reuse cycles. The apparent rate constants normalized to metal mass (0.30 ± 0.03 mM min−1 g Ru −1 under baseline condition) were comparable to the state-of-the-art bimetallic Pd catalyst. In the second stage of the hybrid process, membrane distillation was applied to recover the ammonia product from the brine matrix, capturing nitrogen as ammonium sulfate, a commercial fertilizer product. Solution pH significantly influenced the rate of ammonia mass transfer through the gas-permeable membrane by controlling the fraction of free ammonia species (NH 3) present in the solution. The rate of ammonia recovery was not affected by increasing salt levels in the brine, indicating the feasibility of membrane distillation for recovering ammonia over repeated reuse cycles. Finally, high rates of nitrate hydrogenation (apparent rate constant 1.80 ± 0.04 mM min−1 g Ru −1) and ammonia recovery (overall mass transfer coefficient 0.20 m h−1) with the hybrid treatment process were demonstrated when treating a real waste ion exchange brine obtained from a drinking water utility. These findings introduce an innovative strategy for recycling waste ion exchange brine while simultaneously recovering potentially valuable nitrogen resources when treating contaminated groundwater. Image 1 • Introduce a hybrid ion exchange/catalytic hydrogenation/membrane distillation process. • Ru/C shows high activity for selective nitrate reduction to ammonia. • Membrane distillation used to recover ammonia product as a fertilizer. • Nitrate hydrogenation and ammonia recovery demonstrated with real IX waste brine. [ABSTRACT FROM AUTHOR]

Iron-based coagulants are dosed in enormous amounts and play an essential role in various segments of our urban water infrastructure. In order for the water industry to become circular, a closed-loop management strategy for iron needs to be developed. In this study, we have demonstrated for the first time that in-sewer dosed iron, either in the form of FeCl 3 or ferric-based drinking water sludge (Fe-DWS) as a means to combat sewer corrosion and odour, can be recovered in the form of vivianite in digested sludge in down-stream wastewater treatment plants. Importantly, about 92 ± 2% of the in-sewer dosed Fe was estimated to be bound in vivianite in digested sludge. A simple insertion of Neodymium magnet allowed to recover 11 ± 0.2% and 15.3 ± 0.08% of the vivianite formed in the digested sludge of the in-sewer dosed iron in the form of FeCl 3 and Fe-DWS, respectively. The purity of recovered vivianite ranged between 70 ± 5% and 49 ± 3% for in-sewer dosed FeCl 3 and Fe-DWS, respectively. Almost complete (i.e. 98 ± 0.3%) separation of Fe in the form of ferrihydrite was achieved from vivianite after alkaline washing. Subsequent batch experiments demonstrated that the recovered ferrihydrite can be directly reused for efficient sulfide control in sewers. At a ferrihydrite-Fe:S molar ratio of 1.2:1, sewage dissolved sulfide concentrations was reduced from 15 mgS/L to below 0.5 mgS/L within 1 h of reaction. Overall, the results obtained in our study flag a first step for utilities towards a closed-loop iron-based coagulant management approach. • Fe dosed to sewers as FeCl 3 was recovered from digested sludge as vivianite. • Ferric DWS dosed to sewers formed vivianite in down-stream anaerobic digestion. • Fe dosed to sewers as ferric DWS was recovered from digested sludge as vivianite. • Recovered Fe in the form of ferrihydrite effectively removed sulfide in sewage. • Practical feasibility of a closed-loop iron dosing strategy demonstrated. [ABSTRACT FROM AUTHOR]

Risk-based treatment of onsite wastewaters for decentralized reuse requires information on the occurrence and density of pathogens in source waters, which differ from municipal wastewater due to scaling and dilution effects in addition to variable source contributions. In this first quantitative report of viral enteric pathogens in onsite-collected graywater and wastewater, untreated graywater (n = 50 samples) and combined wastewater (i.e. , including blackwater; n = 28) from three decentralized collection systems were analyzed for two norovirus genogroups (GI/GII) and human adenoviruses using droplet digital polymerase chain reaction (ddPCR). Compared to traditional quantitative PCR (qPCR), which had insufficient sensitivity to quantify viruses in graywater, ddPCR allowed quantification of norovirus GII and adenovirus in 4% and 14% of graywater samples, respectively (none quantifiable for norovirus GI). Norovirus GII was routinely quantifiable in combined wastewater by either PCR method (96% of samples), with well-correlated results between the analyses (R2 = 0.96) indicating a density range of 5.2–7.9 log 10 genome copies/L. These concentrations are greater than typically reported in centralized municipal wastewater, yet agree well with an epidemiology-based model previously used to develop pathogen log-reduction targets (LRTs) for decentralized non-potable water systems. Results emphasize the unique quality of onsite wastewaters, supporting the previous LRTs and further quantitative microbial risk assessment (QMRA) of decentralized water reuse. Image 1 • New ddPCR application for virus quantification in wastewater and graywater. • Improved sensitivity relative to qPCR allows greater quantification frequency. • Measured concentrations agree well with previous epidemiology-based simulation. • Results support published pathogen reduction targets for onsite non-potable reuse. [ABSTRACT FROM AUTHOR]

There is a pressing need for efficient biological treatment systems for the removal of organic compounds in greywater given the rapid increase in household wastewater produced as a consequence of rapid urbanisation. Moreover, proper treatment of greywater allows its reuse that can significantly reduce the demand for freshwater supplies. Herein, we demonstrate the possibility of enhancing the removal efficiency of solid contaminants from greywater using MHz-order surface acoustic waves (SAWs). A key distinction of the use of these high frequency surface acoustic waves, compared to previous work on its lower frequency (kHz order) bulk ultrasound counterpart for wastewater treatment, is the absence of cavitation, which can inflict considerable damage on bacteria, thus limiting the intensity and duration, and hence the efficiency enhancement, associated with the acoustic exposure. In particular, we show that up to fivefold improvement in the removal efficiency can be obtained, primarily due to the ability of the acoustic pressure field in homogenizing and reducing the size of bacterial clusters in the sample, therefore providing a larger surface area that promotes greater bacteria digestion. Alternatively, the SAW exposure allows the reduction in the treatment duration to achieve a given level of removal efficiency, thus facilitating higher treatment rates and hence processing throughput. Given the low-cost of the miniature chipscale platform, these promising results highlight its possibility for portable greywater treatment for domestic use or for large-scale industrial wastewater processing through massive parallelization. Image 1 • Exposure of greywater to MHz-order SAWs leads to fivefold improvement in the removal efficiency. • Enhancement can be attributed to the homogenization and size reduction of bacterial clusters. • Increasing the magnitude of the acoustic pressure leads to an increase in the removal efficiency. • Enhancement is more significant with MHz-order SAWs as compared to kHz ultrasound. • Compact size and low cost of the SAW device is suitable for scale out through massive parallelization. [ABSTRACT FROM AUTHOR]

Development of sustainable and resilient water infrastructure is an urgent challenge for urban areas to secure long-term water availability and mitigate negative impacts of water consumption and urban development. A hybrid system that combines centralized water infrastructure and household decentralized water facilities, including rainwater harvesting and greywater recycling, may be a solution to more sustainable and resilient water management in urban areas. Understanding household and community preferences for decentralized water facilities is important to inform the design and ultimately the promotion and adoption of such systems. In this study, we conducted a discrete choice experiment, via Amazon Mechanical Turk, to collect data on household choices of different decentralized water facility designs in two U.S. cities, Atlanta, Georgia and Boston, Massachusetts. Based on the responses to the choice experiment, we then developed a latent-class choice model to predict households' preferences of decentralized system design features and examine the influence of socioeconomic and personal characteristics on heterogeneous class membership. We identified six major classes of preferences in Atlanta and Boston, respectively, and evaluated how readily each class is likely to choose a decentralized water facility. Atlanta and Boston have some classes sharing similar preferences for decentralized water systems, but the socioeconomic and personal characteristics of these classes in the two cities are different. We found that the early adoption of decentralized water facilities is positively related to neighbors' adoptions and pressure of water scarcity increases households' willingness to share a decentralized facility. The visualization of spatial distribution of the classes highlighted early demand of decentralized water facilities is likely to emerge in low-property-value communities, which creates a unique opportunity for introducing decentralized water facilities during water infrastructure renovations. Our study provides a framework through citizen engagement to understand social demand and to inform the promotion of decentralized water facilities. Image 1 • A choice experiment on decentralized water systems was conducted in two US cities. • Six unique social classes were identified in each city using latent-class analysis. • Notable preference heterogeneity among residents was found in both cities. • Neighbors' choice and perception of water scarcity influence class memberships. • Downtown Atlanta and southeastern Boston have higher proportions of quick adopters. [ABSTRACT FROM AUTHOR]