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Your search keyword '"Liu, Sen"' showing total 1 results
Start Over Author "Liu, Sen" Topic copper Publication Year Range Last 50 years Journal zeitschrift fur anorganische und allgemeine chemie

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1 results on '"Liu, Sen"'

1. Syntheses, Crystal Structures, and Properties of a Salamo-type Tetradentate Chelating Ligand and Its Pentacoordinated Copper(II) Complex.

Author

Dong, Wen‐Kui, Wang, Zheng‐Kun, Li, Gang, Zhao, Meng‐Meng, Dong, Xiu‐Yan, and Liu, Sen‐Hua

Subjects
*LIGANDS (Chemistry), *COORDINATION compounds, *LIGAND exchange reactions, *CRYSTAL structure, *SUPRAMOLECULAR chemistry, *HYDROGEN bonding
Abstract

A Salamo-type ligand 6,6′-diethoxy-2,2′-[1,1′-(ethylenedioxydinitrilo)dimethylidyne]diphenol (H2L) and its pentacoordinate copper(II) complex [CuL(H2O)] were synthesized and structurally characterized. The molecule of H2L is located in a crystallographic inversion center and adopts E configuration with respect to the C=N bond. In the complex [CuL(H2O)], the CuII atom has a tetragonally elongated square-pyramidal configuration with donor atoms N2O2 forming a perfect basal plane. And an infinite 2D layer supramolecular structure is formed through intermolecular C1-H1A ···O5 and C2-H2A ···O3 hydrogen bonding interactions. [ABSTRACT FROM AUTHOR]

Published
2013
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