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Start Over Author "Zhai, Bin" Topic coordination polymers Journal zeitschrift fur anorganische und allgemeine chemie
1 results on '"Zhai, Bin"'

1. A two dimensional GdIII coordination polymer based on isonicotinic acid N‐oxide with large magnetocaloric effect.

Author

Wu, Dong‐Qing, Zhang, Ming‐Liang, Li, Zhong‐Yi, Zhang, Ping‐Ping, Zhang, Meng‐Ying, Wu, Chao‐Fei, Zhang, Chi, and Zhai, Bin

Subjects
*MAGNETOCALORIC effects, *ISONICOTINIC acid, *COORDINATION polymers
Abstract

One two‐dimensional (2D) GdIII coordination polymer based on isonicotinic acid N‐oxide (HINNO), {[Gd(INNO)2(HCOO)] ⋅ 2H2O}n (1), was successfully synthesized and characterized. Magnetic studies reveal the presence of weak antiferromagnetic couplings between adjacent GdIII ions in the 1D chain units of 1 and large cryogenic magnetocaloric effect with maximum −ΔSm of 31.84 J kg−1 K−1 at T=2 K and ΔH=7 T. [ABSTRACT FROM AUTHOR]

Published
2021
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