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CeO2-8YSZ (CYSZ) composite agglomerated powder was synthesized by spray drying of 20% micron-scale CeO2 powder doped with nano-ZrO2-8 mol% Y2O3 (8YSZ) powder. The effect of the binder (carboxymethyl cellulose, CMC) ratio on the properties of the composite agglomerated powder was investigated with the aid of a laser particle size tester, scanning electron microscopy (SEM) and incidental energy spectrometry (EDS). A CYSZ thermal barrier coating with a columnar structure was prepared by PS-PVD, and EDS analysis of the coating cross-section and surface was carried out. X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) were used to analyze the physical phases of the coating. The results show that agglomerated powder with high sphericity, good flowability and uniform particle size distribution can be obtained with a binder ratio of 2%, the prepared coating has a uniform distribution of Ce element, and the coating phase is basically a t-phase structure, in which Ce4+ replaces Zr4+ and enters into the ZrO2 lattice to form a homogeneous solid solution structure, showing the inhibition of the transition from t-phase to m-phase by CeO2 doping. In addition, the prepared CYSZ coating remained intact after 100 cycles of water cooling at 1100 °C, showing high thermal shock resistance.

To solve the surface wear problem of 40Cr steel parts, incorporated with the theory of surface texture, laser phase transformation hardening technology was applied to preparate various shapes (spot and striation) of hard-soft coupling surfaces with regular distribution. Scanning electron microscopy, X-ray diffraction, friction and wear machine and ultra-depth of field microscopy were adopted to analyze the microstructure, physical phase, anti-wear performance, and wear surface morphology of the phase transformation zone. the results show that the cross-section hardness of the spot phase transformation zone is higher than the striation, with the average of (720±3) HV0.1, and the hardening layer is deeper. Martensite, Cr7C3, and Fe7C3 are generated after phase transformation. By comparing the friction coefficient between the untreated surface and the hard-soft coupling surface of 40Cr steel, the friction coefficient of the hard-soft coupling surface is inferior to 0.5 and its fluctuation is smaller which demonstrates great friction stability. In addition, the wear surface damage of the hard-soft coupling surface is small, and the reason of this is that the hard phase could resist the deformation while the soft phase could release the stress concentration and the accumulation of plastic deformations. The soft phase field is mainly pear peeling and adhesion damage, and the hard phase area is mainly small pitting pits. The 900W spot soft-hard coupling surface with the first-rate anti-wear performance. Above all, the conclusion is that the hardening phase with great plastic toughness and a certain proportion (50%) of inerratic surface distribution can markedly increase and promote the anti-wear performance of the material working surface, improve the contact surface of the fraction pair as well as stabilize the friction coefficient, this study can provide a reference for improving the surface wear of 40Cr parts. [ABSTRACT FROM AUTHOR]

In the process of laser cladding forming, the season of process parameters had a fatal influence on the quality of cladding forming. In order to solve the problems of shape control difficulty, process parameter selection and long tnal-and-error experiment period, ANSYS parametric language APDL was used to establish a three-dimensional transient model to simulate the effects of laser power, scanning speed, powder feeding amount and spot diameter on temperature and cooling rate,and the process parameters with good forming quality were optimized. Combined with three groups of experiments, the width, height and depth of the layer and the crystal phase microstructure were measured to verify the feasibility of the numerical simulation. The results show that the optimum process parameters were laser power 1 400 W, scanning speed 10 mm/s, powder feeding rate 1.8 r/min,spot daameter 2 mm, respectively. The numerical simulation results of the width, height and depth of the layer were conssstent with the experimental results, and the forming quahty of the optimized process parameters was better than that of the control group. The research results of this paper pride a valuable reference value for the problem of shape control n laser adding of IN718 nickel base superalloy. [ABSTRACT FROM AUTHOR]