The light absorption of organic components in PM 2.5 was investigated at a suburban site in northern Nanjing from September 2018 to September 2019, and PM 2.5 compositional data and principal component analysis (PCA) were used to identify the sources of light-absorbing organic carbon (brown carbon, BrC). The results showed that the average light absorption coefficients of water-soluble organic carbon (WSOC) and methanol extractable organic carbon (MEOC) were (3.22±2.18) Mm -1 (Abs 365,w ) and (7.69±4.93) Mm -1 (Abs 365,m ), respectively. Significant correlations were observed between Abs 365,w and mass concentrations of WSOC ( r =0.72, P <0.01) and between Abs 365,m and mass concentrations of MEOC ( r =0.62, P =0.04). Both Abs 365,w and Abs 365,m exhibited seasonal variations, with higher values during winter than during summer,and higher diel variations at night than during the day. This can be attributed to meteorological characteristics during the winter and nighttime, i.e., decreased boundary layer height and increased atmospheric stability, enhanced primary emissions in winter,and stronger photobleaching effects during the summer and during the day. The annual average Abs 365,m /Abs 365,w ratio (2.60±0.92) was much larger than the average mass ratio of MEOC/WSOC (1.37±0.30), indicating that the water-insoluble fraction of MEOC had a stronger light absorption effect and dominated BrC absorption. No strong correlation ( r <0.60) was observed between WSOC, MEOC, Abs 365,m , and mass concentrations of K + , indication that biomass burning was not the main source of BrC in the study location. The mass absorption efficiency of WSOC (MAE 365,w ) and MEOC (MAE 365,m ) and their ratios (MAE 365,m /MAE 365,w ) showed similar seasonal variations to Abs 365 . The average MAE 365 value of the water-insoluble fraction of MEOC (4.10±5.15) m 2 ·g -1 was 6.0 and 2.9 times higher than that of MAE 365,w and MAE 365,m , respectively, suggested that BrC absorption was primarily attributable to water-insoluble components. In comparison to the absorption Ångström exponent of WSOC ( Å WSOC ), Å MEOC displayed marked temporal variability, which might be related to the seasonal variation in the emission of water-insoluble chromophores. According to the PCA results, the light absorption of PM 2.5 organic was mainly attributed to secondary formation and anthropogenic primary emissions rather than biomass burning.