1. 改性Fe3O4@MIL-100(Fe)对Cu(Ⅱ)的吸附研究.
- Author
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石小雪, 董季玲, 钟晨晨, 杨灵医, 蒋 伟, and 钟国媛
- Abstract
Traditional liquid-phase adsorbents have limitations in Cu (11) adsorption such as low adsorption difficult separation and recovery, while metal-organic frameworks (MOF) exhibit great potential in the field of heavy metal ion adsorption. Tn this study Fes ()i @MTL-1 0()(Fe) magnetic material was created by an economical and environmentally friendly low-energy room-temperature aqueous-phase method using Fes()i as a nucleus and then modified NH2-Fe3 ()4 ©MTL-1 0()(Fe) was prepared by post-synthesis modification method. The materials before and after modification were characterized using XRD? FT-TR SEM TEM VSM and EA. The adsorption performance of Cu(11) was studied by investigating the effects of pH time concentration and temperature. Due to the coordination reaction and electrostatic interaction between NH-Fes ()i @MTL-1 0()(Fe) and Cu(11) the adsorption capacity of Cu(11) (46.77 mg/g) was significantly higher than that before modification. The ad sorption process of Cu(11) conformed to the Pseudo 1st order and the Freundlich adsorption model in both modified and unmodified materials. Thermodynamic study showed that the adsorption of Cu (11) to the modified material was a spontaneous endothermic process while that was a spontaneous exothermic process before the modification. Tn addition after 5 sorption-desorption cycles the adsorption capacity of Cu(11) by NH-Fes()i @MTL-1 0()(Fe) was still slightly higher than that by Fes()i ©MTL-100(Fe). [ABSTRACT FROM AUTHOR]
- Published
- 2025
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