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• A total of 196 components were characterized in Tibetan native fruit "Medog lemon" (ML) with LC-HR MS based integrated strategy. • A total of thirty-three were detected from Citrus genus for the first time, and fifty-five were identified as potential new chemicals. • More than 30 components were screened to showed outstandingly discriminative ability. • ML showed distinct morphological, chemical characters and good antioxidant activity. • ML is a promising food material as a source of abundant bioactive compounds. Tibet's native fruit resources have not been explored and remain underutilized due to geographical isolation. "Medog lemon" (ML), an ethno-species of wild citron, is an important functional food and dietary resource for the local people in southeastern Tibet. Herein comprehensive characterization of components of ML were firstly performed with an integrated strategy based on UHPLC-QE Orbitrap MS. A total of 196 components were characterized, among which 33 were detected from Citrus genus for the first time, and 55 were identified as potential new phytochemicals. The chemical comparison of ML with cultivated citron and fingered citron based on partial least squares-discriminant analysis model and univariate analysis revealed the distinct chemical composition of ML and in which more than 30 differentiated components were identified. The distinct morphological and chemical characters, as well as its good antioxidant properties, indicated ML as a potential new food resource that can be beneficial for human health. [ABSTRACT FROM AUTHOR]

The suggested Early Cretaceous timing of early formation of the Tibetan Plateau remains controversial. This study investigates this uncertainty by examining newly identified Early Cretaceous adakite-like magmatic rocks in the Rutog and Nyima areas of the northern–central Tibetan Plateau. Zircon U Pb dating indicates that these rocks formed at ca. 110 Ma and have negative to positive zircon ε Hf (t) values. They contain high concentrations of Sr and have high Sr/Y values, but contain low concentrations of Y and Yb and have low (La/Yb) N , suggesting they have an adakite affinity. They also have ε Nd (t) values that range from −4.5 to +1.3. These geochemical and isotopic data indicate that the adakite-like rocks probably formed from magmas generated by the partial melting of garnet-bearing amphibolite within a thickened region of juvenile and ancient crustal material. This magmatism also most likely occurred during the Lhasa–Qiangtang collisional event. Crustal thicknesses along the Bangong–Nujiang suture zone (BNSZ) were > 40 km in places at ca. 110 Ma, and most likely had a significant impact on the initial uplift of the Tibetan Plateau. In summary, the Early Cretaceous adakite-like magmatic rocks in the Rutog and Nyima areas suggest that the Tibetan Plateau started to form during the Early Cretaceous. • Early Cretaceous adakite-like rocks occur in the north-central Tibet. • Adakite-like rocks were derived from the thickened crust. • The Lhasa–Qiangtang collision happened before ca. 110 Ma. • The significant crustal thickening led to the early uplift in the Early Cretaceous. [ABSTRACT FROM AUTHOR]

Magmatic rocks preserve a lot of information about the formation and evolution of continental crust, and they play an important role in understanding the growth and reworking of ancient continent. Cretaceous magmatic rocks occurring in the Lhasa terrane are a window to investigate magmatic processes and continental evolution of the Tibetan Plateau. In this study, we report zircon U Pb ages and Hf isotopic data, as well as whole-rock major and trace elemental compositions for Early Cretaceous magmatic rocks, including andesite and dacite from the Zenong Group, and associated diorite and granite in the Xinji area, north-central Tibetan Plateau. Zircon from andesite and dacite yielded weighted-mean 206Pb/238U ages of 120–108 Ma and variable zircon ε Hf (t) values between −12.3 and +2.2. Geochemical compositions suggested that they both displayed high-K calc-alkaline features. Andesite was probably formed by mixing between crust- and mantle-derived melts, whereas dacite was most likely generated by partial melting of ancient crust with input of mantle-derived material. Dioritic and granitic intrusions were intruded into the Precambrian strata and Zenong Group, respectively. Zircon from diorite gave a weighted-mean 206Pb/238U age of ca. 116 Ma and zircon ε Hf (t) values of −0.5 to +7.3. Diorite displayed medium-K calc-alkaline series signatures and was most likely formed by partial melting of mantle wedge peridotite accompanied by crustal assimilation. Granite yielded zircon weighted-mean 206Pb/238U ages of 107–104 Ma, and positive zircon ε Hf (t) values of +1.5 to +6.7, indicating a major source of juvenile crust. Granitic samples show irregular REE distribution with variable Ce anomalies, which were probably inherited from subducted pelagic sediments. The Early Cretaceous magmatic rocks in the Xinji area records distinct formation processes involved partial melting of mantle, re-melting of crust, and mixing between mantle and crust. Such processes, however, had a complicated source from mantle, ancient and juvenile continental crust, and recycled pelagic sediments, suggesting simultaneous crustal growth and reworking of the Lhasa basement during the Early Cretaceous. • Early Cretaceous magmatic rocks occur in the Xinji area, central Tibet. • Ce anomalies of granites were inherited from subducted pelagic sediments. • The Bangong-Nujiang Tethys Ocean experienced southward subduction. • Simultaneous growth and reworking occurred in the Lhasa basement. [ABSTRACT FROM AUTHOR]