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Green hydrogen exploitation plays a crucial role in achieving carbon neutrality by 2050. Hydrogen, in fact, provides a number of key benefits for the energy system, due to its integrability with other clean technologies for energy production and consumption. This paper is aimed at presenting the project of recovery of an abandoned industrial area located in central Italy by developing a site for the production of green hydrogen. To this aim, the analysis of the territorial and industrial context of the area allowed us to design the project phases and to define the sizing criteria of the hydrogen production plant. The results of a preliminary cost–benefit analysis show that a huge initial investment is required and that, in the short term, the project is sustainable only with a very large public grant. On the other hand, in the long term, the project is sustainable, and the benefits significantly overcome the costs. [ABSTRACT FROM AUTHOR]

Abstract Industry is one of the highest energy consumption sector: some facilities like steelworks, foundries, or paper mills are highly energy-intensive activities. Many countries have already implemented subsidies on energy efficiency in generation and utilisation, with the aim of decreasing overall consumption and energy intensity of gross domestic product. Meanwhile, researchers have increased interest into alternative energy systems to decrease pollution and use of fossil fuels. Hydrogen, in particular, is proposed as a clean alternative energy vector, as it can be used as energy storage mean or to replace fossil fuels, e.g. for transport. This work analyses the re-vamping of the energy generation system of a paper mill by means of reversible solid oxide cells (RSOCs). The aim is not only to increase efficiency on energy generation, but also to create a polygeneration system where hydrogen is produced. Application on a real industrial facility, based in Italy with a production capacity of 60000 t/y of paper, is analysed. First, the current energy system is studied. Then, a novel system based on RSOC is proposed. Each component of the systems (both existing and novel) is defined using operational data, technical datasheet, or models defined with thermodynamic tools. Then, the interaction between them is studied. Primary energy analysis on the novel system is performed, and saving with respect to the current configuration is evaluated. Even if the complexity of the system increases, results show that saving occurs between 2 and 6%. Hydrogen generation is assessed, comparing the RSOC integrated system with proton exchange membrane (PEM) electrolysis, in terms of both primary energy and economics. Results exhibit significant primary energy and good economic performance on hydrogen production with the novel system proposed (hydrogen cost decreases from 10 €/kg to at least 8 €/kg). Highlights • The re-vamping of the energy generation system of a paper mill is analysed. • Reversible solid oxide cells are used increasing efficiency on energy generation. • A polygeneration system where hydrogen is produced is also created. • Primary energy saving on energy facility generation occurs between 2 and 6%. • Significant primary energy and good economic performance on hydrogen production are performed. [ABSTRACT FROM AUTHOR]