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1. Asymmetric Construction of a Ferrocenyl Phosphapalladacyclefrom Achiral Enones and a Demonstration of Its Catalytic Potential.

Author

Gan, Kennard, Sadeer, Abdul, Xu, Chang, Li, Yongxin, and Pullarkat, Sumod A.

Subjects
*PALLADACYCLES, *CARBONYL compounds, *FERROCENE, *ASYMMETRY (Chemistry), *CHIRALITY, *CATALYTIC activity, *CARBON-carbon bonds
Abstract

A newapproach toward ferrocenyl phosphapalladacycle construction from achiralenones via asymmetric hydrophosphination and subsequent diastereoselectiveC–H activation is described. Its catalytic efficacy towardC–C bond formation is subsequently illustrated. [ABSTRACT FROM AUTHOR]

Published
2014
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