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In this paper, the stratigraphic occurrence of n -alkanes (C n) is investigated in three peat cores (Mildred, JPH4 and McMurray) from the ombrotrophic peatlands in northeastern Alberta, Canada, to determine their origin, biomass input, and paleoclimatic significance. The molecular composition of n -alkanes is dominated by the >C 21 medium- to long-chain homologues, with a strong odd over even predominance. A number of n -alkane-based indices (e.g. predominant n -alkane, C 23 /C 29 , C 23 /(C 27 + C 31), P aq , ACL, and CPI), show changing conditions in the organic matter (OM) input from Sphagnum species or terrestrial vascular plants, which increasingly contributed upwards in the peat profiles, and through time. P aq and C 23 /(C 27 + C 31) proxies are similar in the three cores, and allow us to infer vegetation variations that coincide with the climate alternations of the Medieval Warm Period (MWP), Little Ice Age (LIA), and modern Recent Warming (RW). The utilization of ACL-ket and (C 23 + C 25)/(C 27 + C 29 + C 31)-ket proxies, performed in comparison with n -alkane proxies, further support the biomarker-based reconstructions of paleoclimate variations over recent centuries. This study suggests that n -alkane homologues are sensitive to vegetation and climate changes and thus are reliable biomarkers for tracking past shifts in vegetation and climate variations in peat archives. • Determine organic matter source of peat sediments from n -alkane biomarkers. • C 23 /(C 27 +C 31) n -alkane proxy is proposed and can effectively characterize climate changes. • P aq proxy indication could be misleading when the contribution of Sphagnum fuscum to the peat is large. • n -Alkan-2-one proxy is studied to further confirm the biomarker-based reconstruction of paleoclimatic changes. [ABSTRACT FROM AUTHOR]