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Abstract The growing demand for energy and the accelerating threats from climate change call for innovative and sustainable solutions to decrease dependency on fossil fuels. Biomass-based, small-scale Combined Cooling, Heating and Power (CCHP) systems are one of these solutions, because they can satisfy the energy demands of the consumer with enhanced flexibility, lower losses, less costs and less environmental pollution as compared to centralized facilities. Due to recent advances in several scientific subfields with relevance to small-scale CCHP, a rapidly increasing amount of literature is now available. Therefore, a structural overview is essential for engineers and researchers. This paper presents a review of the current investigations in small-scale CCHP systems covering biomass-fired concepts and solar extensions. To this end, critical system components are described and analysed according to their specific advantages and drawbacks. Recent case studies have been collected and key findings are highlighted according to each type of prime mover. The results indicate a scientific bias towards the economic viability of such systems and the need for real-life and experiment system data. However, the potential of biomass-fired CCHP systems and of such systems with solar extensions has clearly been recognised. Based on the results, future policy implementations should focus on fostering such systems in areas with high energy costs and to increase energy resilience in developed regions. Additionally research and industry applying novel prime mover technologies should be financially supported. Highlights • Small-scale, biomass-fired CCHP is gaining interest in science and industry. • Summary on biomass conversion, prime mover and cooling technologies. • The findings are put into context with current and future technology trends. • Entrepreneurial bias of scientist towards feasibility of CCHP systems. • Policies should promote CCHP in areas with high energy costs and low grid stability. [ABSTRACT FROM AUTHOR]

This paper presents the development of nanoparticulate indium tin oxide (ITO) inks for the continuous manufacture of ultrathin (∼280 nm) ITO layers on PET substrates by roller coating at very high coating speeds. Ethanol- and water-based ITO inks containing polyvinylpyrrolidone as binder were prepared and rheologically characterized. The influence of different ink compositions on coating properties was evaluated by the concept of the dimensionless capillary number Ca. The ITO films were characterized concerning optical and electrical properties in dependence on ink composition and coating parameters. The organic solvent ethanol could be replaced by water, being cheap and environmental friendly. These inks allow the manufacture of sub-μm thin ITO layers with high layer quality and low specific electrical resistance of 3 Ω cm. Flexible and highly transparent ITO films with an inline-transmission of 88% in the regime of visible light which absorbed simultaneously up to 96% in the NIR region were produced. [ABSTRACT FROM AUTHOR]

Renewable energy polygeneration systems are a viable alternative to fossil-fuel based systems, but storage solutions may be necessary when aiming for high sustainability and autonomy. As each storage technology has different strengths and weaknesses, combinations of various storage solutions may lead to better techno-economic performance than singular approaches. To this purpose, an optimization model including a novel dispatch control strategy for a hybrid energy storage system (HESS) is proposed, which uses biogas for long-term and batteries for short-term storage. The model optimizes for minimum lifetime costs while exploiting the biomass resources with maximum efficiency and quantifying the additional solar and battery capacities needed. It is applied in a case study with an innovative biomass-based polygeneration system in a rural locality of Bolivia to serve electricity, potable water, and bio-slurry as fertilizer. The results indicate that even with maximized efficiency of the biomass resource conversion, large PV and battery capacities are necessary to satisfy the electricity demand of the locality. Despite of the high investment costs, the biomass-based polygeneration system would cost 22% less over the project lifetime than the fossil-fuel based reference system while being less dependent on fuel price changes. It would also reduce CO 2 -emissions by over 98%. • Presenting a control strategy for polygeneration systems using biogas and batteries • Development of a model for such systems enhanced with PV and membrane distillation • Application of the model in a case study for a rural locality in Bolivia • Results show 22% lower lifetime costs and 98% less emissions but high capital costs • The model including the control strategy facilitate designing polygeneration HESS [ABSTRACT FROM AUTHOR]

• Cost-optimal design method for CCHP-assisted HP systems for varying climate scenarios. • Numerical transient model for demand and CCHP/HP system analysis. • Techno-economic analysis of Montjuic Castle, Barcelona, based on the model. • Small CCHP leads to more sustainable autonomy without unreasonable extra costs. • Climate change has a relatively small effect on comparative economic performance. An innovative modelling approach for the design of biomass-based, solar-assisted combined cooling, heating, and power (CCHP) and heat pump (HP) systems for various climate scenarios is proposed in this work. The modelling approach is comprised of three sub-models (a demand sub-model, a supply sub-model, an economic sub-model) allowing for cost-optimal sizing of the system components based on net present cost (NPC). Subsequently a transient optimization model has been developed, which computes the technical and economic performance for each component size and for each ambient temperature of the different climate scenarios. Additionally, the model provides data on energy efficiency, exergy efficiency, and CO 2 -emissions of a given CCHP/HP system. The model has then been employed in a case study in order to analyse the performance of a CCHP/HP system for a tourist, museum, and guest accommodation structure located at the Montjuïc castle in Barcelona, Spain. The results show that the smallest simulated biomass-based CCHP system using a 25 kW e syngas-fuelled engine would reduce lifetime costs by 7% compared to an only-HP system while operating with a high total energy efficiency of over 60%. The combined CCHP/HP system would operate with an exergy efficiency of 18%. However, larger CCHP systems cannot offset the much higher capital costs despite increasing electricity sales. The findings also reveal that for the high climate change scenario the overall project costs drop by up to 2.5%, however the effects have little impact on the optimal CCHP/HP system sizing. Even the smallest CCHP system would reduce emissions already by 75% with an increasing trend for larger systems. Although CCHP/HP systems would lead to lower NPC and emissions, the high investment costs and the complexity of the combined system remain considerable obstacles. [ABSTRACT FROM AUTHOR]

CO 2 reduction offers an attractive alternative green synthetic route for ethylene, especially where CO 2 could be sourced from industrial exhausts and in combination with green power sources. However, practical applications are currently limited due to the unfortunately low selectivity of cathode materials towards ethylene. This work uses polymers with intrinsic microporosity (PIMs) to improve the performance of copper gas diffusion electrodes for CO 2 reduction to ethylene. We report an improved selectivity and activity towards ethylene with the addition of a thin PIMs layer, which is seen as improved Faradaic efficiency, increased stability and a shift in the reduction to lower overpotential. This improvement is highly dependent on the thickness of the added polymer layer, with too thick a layer having a detrimental impact on the hydrophobicity of the gas diffusion layer. With a compromise in loading, PIMs can be used to enhance the activity and selectivity of catalysts for targeted CO 2 reduction to ethylene. Image 10694 • Gas diffusion electrodes allow CO 2 reduction to ethylene, but selectivity is low. • Polymers with intrinsic microporosity can increase ethylene production. • Using too much polymer has a detrimental impact. • A compromise polymer thickness increases ethylene yield and electrode stability. [ABSTRACT FROM AUTHOR]