1. Synthesis, Crystal Structure, and Properties of Two Zinc Tubular Coordination Polymers Based on Fluconazole.
- Author
-
Pan, Gang-Hong, Yin, Xian-Hong, Xu, Wen-Jia, Liang, Peng, Tian, Wei-Man, and Huang, Zhong-Jing
- Subjects
ZINC compounds synthesis ,COORDINATION polymers synthesis ,FLUCONAZOLE ,CRYSTAL structure ,ZINC ions ,METAL complexes ,PHTHALIC acid - Abstract
Two Zn(II)-containing complexes based on fluconazole, {[Zn(HFlu)2(IPA)]·9H2O}n(1), {[Zn(HFlu)2(OH-BDC)]·8H2O}n(2) (HFlu = fluconazole; 2-(2,4-difluoro- phenyl)-1,3-bis(1,2,4-triazol-1-yl)-propan-2-ol; H2IPA = isophthalic acid; OH-H2BDC = 5-hydroxyisophthalic acid) have been synthesized and structurally characterized. Complex1and2are both a one-dimensional (1D) tubular structure with the distorted dinuclear zinc rectangular-shaped cavity, and large free water molecules involved in strong O‒H···O and O‒H···N hydrogen bonds are accommodated in the 1D tubular structure. The thermal stabilities and photoluminescent properties of the coordination polymers have also been investigated. [ABSTRACT FROM AUTHOR]
- Published
- 2014
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