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Hierarchically nested groundwater flow systems have been widely investigated by numerical modeling and laboratory experiments but seldom recognized from in situ observations and testing. Groundwater age and geochemical profiles were obtained by the authors using a packer system along two wellbores drilled in the Ordos Plateau, China. Groundwater age profiles were constructed from 3H, 85Kr, 14C, and 81Kr data, with the apparent age generally increasing with depth, while exhibiting several inflection points. These inflection points were compared with geochemical profiles and numerical modeling results to delineate groundwater flow systems. Inflection points with significant increases in the gradients of age and Cl− concentration versus depth may indicate interfaces among flow systems. A concurrent decrease‐increase turning of groundwater age and Cl− concentration is influenced by a stagnation point. The groundwater age profiles are quite different from previous studies, indicating that the method can greatly reduce the uncertainty in model construction. Plain Language Summary: The provision of renewable groundwater, a crucial source of drinking water worldwide, relies on a circulation path from recharge to discharge zones with a subsurface flow in reservoirs (aquifers). Basin‐scale groundwater circulation is speculated to form hierarchically nested flow systems with differing capabilities for renewal. However, flow systems are invisible and difficult to detect through in situ observations on groundwater. In this study, nested groundwater flow systems were identified from groundwater age and geochemical profiles along wellbores. Inflection points on these profiles provide significant insights into the interfaces and stagnation points among nested groundwater flow systems. Uncertainties could be brought by the aquifer heterogeneity in the hydraulic conductivity and localized soluble salts. This adopted method is expected to be improved by incorporating geophysical survey and high‐resolution geochemical analyses to eliminate uncertainties in model construction. Key Points: Groundwater age and geochemical profiles were obtained to investigate groundwater flow systemsInflection points on profiles are used to infer interfaces or stagnation points among different groundwater flow systemsGroundwater flow models constrained by inflection points greatly reduce the uncertainty of flow system characterization [ABSTRACT FROM AUTHOR]

• Groundwater mounds resulting from nearshore recharge is identified in a sandy hillslope. • The thickness of vadose zone determines fluxes across water table along the hillslope. • Nearshore recharge temporarily changes streamlines and increases tortuosity of flowpaths. • Flowpaths near the wetland are mainly controlled by regional GW discharge and strong ET. Groundwater mounds and depressions induced by rainfall and evapotranspiration near wetlands/lakes have been widely observed, but their effects on groundwater flow field are poorly known. Here, a sandy hillslope near a wetland in the Ordos Plateau, China, which has a semi-arid climate, is selected for investigation. After identifying temporary groundwater mounds/depressions based on three water level observation wells, a HYDRUS-2D model is setup to obtain the highly transient daily flow field. The variable thickness of unsaturated zone near the wetland, which controls soil water content and unsaturated hydraulic conductivity, is found to be responsible for groundwater mounds resulting from focused recharge and groundwater depressions resulting from nonuniform evapotranspiration. On nonrainy days, evapotranspiration in the lowland is supported by flowpaths from regional groundwater discharge, and in the slope is supported by a flow cell from the upland to the upper part of the slope, which causes water table recession in the upland. On rainy days, focused recharge in the lowland leads to two temporary local flow cells, which break the regional groundwater discharge flowpaths into two temporary flow cells. The two temporary flow cells toward the upland contribute to water table rises in the uplandMoreover, we find focused recharge in rainy days does not change the overall direction of flowpaths controlled by regional groundwater discharge and strong evapotranspiration, but only increase the tortuosity of flowpaths. By coupling daily atmospheric conditions and regional groundwater discharge, this study has implications for groundwater recharge estimation and future groundwater modelling in arid regions. [ABSTRACT FROM AUTHOR]