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Metakaolin (MK) is one of the most sustainable cementitious construction materials, which is derived through a direct heating procedure known as calcination. Calcination process takes place substantially lower temperatures than that required for Portland cement, making it a more environmentally sustainable alternative to traditional cement. This procedure causes the removal of hydroxyl water from the naturally occurring kaolin clay (Al2Si2O5(OH)4 with MK (Al2O3·2SiO2) as its product. Kaolin naturally exists in large amount within 5°29′N–5°35′N and 7°21′E–7°3′E geographical coordinates surrounding Umuoke, Obowo, Nigeria. Alumina and silica are the predominant compounds in MK, which provide it with the pozzolanic ability, known as the 3-chemical pozzolanic potential (3CPP), with high potential as a cementitious material in concrete production and soil stabilization. Over the years, researchers have suggested the best temperature at which MK is derived to have the highest pozzolanic ability. Prominent among these temperature suggestions were 800 °C (3CPP of 94.45%) and 750 °C (3CPP of 94.76%) for 2 h and 5 h' calcination periods, respectively. In this research paper, 11 different specimens of Kaolin clay obtained from Umuoke, Nigeria, were subjected to a calcination process at oven temperatures from 350 to 850 °C in an increment of 50 °C for 1 h each to derive 11 samples of MK. The MK samples and Kaolin were further subjected to X-ray fluorescence), scanning electron microscopy (SEM) and X-ray diffraction (XRD) Brunauer–Emmett–Teller (BET) tests to determine the microstructural behaviour and the pozzolanic properties via the 3CPP as to exploit the best MK with the highest cementing potential as a construction material. The results show that the MK heated at 550 °C and 800 °C produced the highest pozzolanic potentials of 96.26% and 96.28%, respectively. The enhancement in pozzolanic potential at optimum calcination temperature is attributed to an increase in the specific surface area upon calcination of kaolinite confirmed by BET results. The SEM and XRD results further supported the above result with the strengthened crystal structure of the MK at these preferred temperatures. Generally, 550 °C is more preferred due to the less heat energy needed for its formulation during 1 h of calcination, which outperforms the previous results, that suggested 750 °C and 800 °C in addition to longer hours of heat exposure. [ABSTRACT FROM AUTHOR]

Nigeria, at the 2021 Conference of Parties (COP26) meeting in Glasgow announced a commitment to transitioning her carbon economy to reach net-zero by 2060. One year after, the country's drive for carbon neutrality is shrouded with uncertainties despite numerous policies targeted at it. This study employed the Multilevel Perspective (MLP) and PESTLE (Political, Economic, Social, Technological, Legal, Environmental) analytical framework to assess the politics of low-carbon transition in Nigeria. We used a triangulation of literature review, document analysis, and survey to build the theoretical, historical, and empirical bases for the enquiry. The findings show that the current low-carbon transition process is characterised by few potential drivers and many barriers with critical uncertainty effects. The key drivers are: Nigeria's potentials for carbon sink/nature-based solutions; vast renewable energy resources; strong niche market demand; and huge opportunities for employment in the renewable energy sector. The major barriers are: poor management of the energy regime; weak infrastructural base; dependence on global climate fund; fossil fuel-based economy; cost of renewable energy options; and impacts of climate change, among others. The barriers with critical impacts outweigh the potential drivers at the ratio of 4:1 thereby playing greater role in characterizing Nigeria's transition pathway as the 'reconfiguration transition pathway' within the 'emergent transformation context.' Therefore, unless the identified regime barriers are eliminated, the current transition pathway may not deliver the low-carbon targets. Considering the huge mitigation potentials of Nigeria's vast forests and natural ecosystem for carbon sink, the study recommends investment in nature-based solutions in synergy with energy system management as the most convenient and cost-effective pathway to attaining carbon neutrality by 2060. [ABSTRACT FROM AUTHOR]