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A polypropylene (PP) film is usually employed as the main insulation of the peaking capacitor, which is important in an electromagnetic pulse simulator to generate high-amplitude nanosecond pulse. The flashover voltage of PP films under nanosecond pulse limits the highest working voltage of a peaking capacitor. Surface fluorination was employed to increase the flashover voltage of PP. The flashover voltages of PP samples with different fluorination times (0, 4, and 6 h) were tested in an oven with nanosecond pulse voltage. The results showed that the flashover voltage of the PP film with 6-h surface fluorination was increased about 15% than the untreated film in the air. To clarify the influential mechanism, the physicochemical properties of PP film samples were tested and characterized. The results of thermally stimulated depolarization current (TSDC) showed that the trap density of the PP film increased obviously after fluorination treatment. With the increase in treatment time, the trap depth and density were increased obviously. The surface conductivity of PP films slightly decreased with the increase in fluorination time. The mechanism of surface fluorination on the influence of the flashover performance of the PP film under nanosecond pulse is discussed. It is concluded that surface fluorination significantly increases the carbon–fluorine (C–F) bond of the PP film, resulting in the increase in the depth and density of the surface trap, and then, a large amount of homocharges trapped in the surface trap reduces the electric field near the electrode. [ABSTRACT FROM AUTHOR]

Numerical simulation of discharge mechanism under nanosecond pulse voltage assists in the insulation performance optimization of N2-insulated switches that are widely used in the pulse power devices. This article presents a fluid dynamic model for the positive streamer propagation in N2 based on a needle-plate discharge system. The effects of the operating conditions, such as voltage amplitude, rising edge, gap width, and needle radius, are studied. Simulating results indicate that the streamer might be evoked only when the maximum electric field exceeds the critical value that is closely influenced by the needle radius and gap width, e.g., $1.3\times 10^{7}$ V/m based on a needle-to-plate electrode configuration with a 0.4-mm tip radius and 5-mm gap. The maximum electric field occurs at the head of streamer and it drops suddenly by nearly two orders of magnitude in the back of the head, which makes the streamer moves forward rapidly. Certainly, it needs a high enough voltage to ensure continuous propagation of the streamer, for example, more than 20 kV needed as the tip radius and gap set to 0.4 and 5 mm, and the electric field strength and migration speed increase with the increasing voltage amplitude. The radius of the discharge region is smaller when the rising edge time increases from 10 to 40 ns. However, if the rising edge time is too low (e.g., 2 ns), the streamer will cease before it propagates to the plate electrode and the radius of the discharge region shrink at the same time. In addition, the peak electric field and the averaged electron energy at the same position away from the needle decrease slightly with the gap width. Finally, there is an obvious decrease of the initial peak electric field as the needle radius increases. [ABSTRACT FROM AUTHOR]