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Karst spring water dynamic characteristics and its response to atmospheric precipitation are of great significance for water resources utilization under the background of climate change. This paper selects Longzici spring area, North China, as the study area. Based on a long series of spring water flow and precipitation data, the dynamic characteristics of spring flow were analyzed and the numerical simulation of the groundwater flow model was established. The results show that the groundwater kept the sustained decline over the past decades which is in a negative equilibrium state, with a storage variable of − 2.26 million m3/year. The sensitivity of spring flow to precipitation under different precipitation scenarios shows that the water level changes in the recharge and drainage areas are similar about (3–5 cm) and slightly larger than that in the runoff area(1.5 cm) when minimum rainfall (287.24 mm) happens. When the precipitation is at its maximum (867.66 mm), the water level change in the runoff area can reach 95 cm which is much larger than those in the recharge and discharge areas. The results indicate that Longzici karst spring has a relatively good regulation water resource capacity and the runoff area is more sensitive which plays an important role in response to climate change. [ABSTRACT FROM AUTHOR]

This paper studies the mineralization process and the ore-forming setting of the Kantian fluorite deposit in South China through the zircon U-Pb chronology, quartz Rb-Sr dating, whole rock geochemistry, H-O isotope and fluid inclusions. A mineralization model for the Kantian fluorite deposit is proposed as follows: The subduction of the Pacific plate during the late mid-Jurassic and late Jurassic led to the formation of several fault zones. As the subduction gradually decelerated and eventually ceased, continental extension and lithosphere thinning occurred, accompanied by upwelling of the asthenosphere. This asthenosphere upwelling facilitated melting of the lithospheric mantle, resulting in the ascent of magma into the lower crust. Consequently, the intrusion of magma into the lower crust caused substantial heat, triggering partial melting of the lower crust. The molten material then ascended along faults, generating a significant quantity of granites. During the Early Cretaceous period, the Yanshan cycle witnessed another notable phase of magmatic activity. The residual magmatic hydrothermal fluid from this period served as a source of heating, while the pre-existing fault structures provided favorable pathways and storage space. Atmospheric precipitation infiltrated into the depth along these faults, and the deep-seated residual magmatic hydrothermal fluid heated the infiltrated atmospheric water, inducing cyclic upwelling. The upward migration of hydrothermal fluid continuously extracted Ca and F elements from the granites. Ongoing interaction between the fluid and the surrounding rocks led to changes in pH, coupled with alterations in temperature and pressure, ultimately resulting in the precipitation of fluorite with associated alteration zones in the surrounding rocks. [Display omitted] • Ca and F element in the fluorite were derived through the surrounding rocks. • The ore-forming fluids belong to the NaCl-H 2 O system and exhibit characteristics of medium–low temperature, low salinity, and low density, and were derived from meteoric water. • The intrusion age of surrounding rock in Kantian fluorite deposit was 159.4 ± 2.2 Ma, and the ore-forming of fluorite was 135.6 ± 0.7 Ma. • The tectonic setting responsible for the diagenesis and mineralization processes is believed to be an intracontinental stretching environment associated with the subduction of the Pacific plate. The Yanshanian events have led to the development of South China as a unique granite province globally. Within South Jiangxi, numerous metallic and non-metallic deposits have a close association with Mesozoic granite formations. The Kantian fluorite deposit, a newly discovered non-metallic deposit in southern Jiangxi Province, is one such deposit that is linked to Mesozoic granites. The orebody at the Kantian fluorite deposit is identified as occurring in veined structures within the silicification fracture zone of Mesozoic granites, with strict control exerted by fault systems. Fluorite ore can be classified into two categories based on the amount of quartz and fluorite. The first category is the fluorite quartz type, which has a higher amount of quartz than fluorite. The second category is quartz fluorite type, which has more fluorite than quartz. Among these two categories, the quartz fluorite type is precipitated during the primary mineralization stage. Through the analysis of fluid inclusions within the fluorite, it was determined that the homogenization temperature is relatively low, ranging from 133 to 236℃. The fluid inclusions also display low salinity (0.18–3.39 wt% NaCl eqv.) and low density (0.75–0.96 g/cm3). Laser Raman spectroscopy revealed that the primary components of the fluid inclusions are H 2 O, with minor C 3 H 6. Isotope analysis indicated δD VSMOW values of fluorite ranging from −61.9 ‰ to −54.8 ‰ (average −59.8 ‰), while δ18O VSMOW values varied from 1.3 ‰ to 3.1 ‰ (average 2.0 ‰). This study presents chronological, petrological and geochemical data that suggest several processes. The metallogenic age is 135.6 ± 0.7 Ma. The mineralizing fluids were identified to the NaCl-H 2 O system, with heated meteoric water identified as the primary source; The ore-forming materials originated from the granite, and water–rock interactions are proposed as the primary mechanism for fluorite precipitation. Based on a tectonic setting characterized by stretching, which is closely linked to the subduction of the Pacific plate, we proposed a model for the Kantian fluorite deposit. [ABSTRACT FROM AUTHOR]

The intensification of anthropogenic activities (agriculture, industry, and exploitation of water resources) during urbanization has posed significant challenges to the aquatic environment, particularly in karst regions. Karst aquifers are highly susceptible to surface contaminants and exhibit minimal natural remediation capabilities. Our understanding of the anthropogenic activities involved in these sensitive karst systems remains limited. To address this gap, we conducted a comprehensive study, collecting 285 groundwater samples in Feicheng, northern China, from 1996 to 2015. The overexploitation of karst groundwater has resulted in several concerns. The whole dataset was classified into four groups according to land use. Water quality assessments revealed a yearly decline, particularly in industrial and agricultural areas. The water chemistry transitioned from Ca-Mg-HCO3 to Ca-Mg-HCO3-SO4. Such evolution was attributed to natural hydrogeochemical processes, atmospheric precipitation, and anthropogenic inputs. Natural factors included water-rock interactions (the mineral dissolution) and ion exchange. Absolute principal component scores with multiple linear regression (APCS-MLR) were used to quantitatively estimate the sources of pollution. The results showed that hydrogeological settings (recharge, runoff, and discharge) were crucial in the hydrochemistry evolution of karst groundwater systems. In agricultural areas, it is recognized that much of the NO3− accumulation in aquifers came from upstream inputs in the groundwater system, not just irrigation and fertilization. Urban areas were affected by Cl− pollution, primarily due to domestic waste. Industrial regions of recharge zones were more susceptible to atmospheric precipitation and industrial waste, with pollutants infiltrating through rainfall and degrading water quality. Mining areas exhibit higher SO42− and lower pH due to the oxidation of sulfur-containing minerals. Therefore, the rapid response and low self-purification capacity of groundwater in karst regions necessitate caution in urban planning to mitigate impacts on these fragile systems. [ABSTRACT FROM AUTHOR]

The Eastern Kunlun Fault (EKF) is situated in an area with a history of significant seismic events, yet it has witnessed a dearth of major earthquakes in recent years. This study conducted a detailed analysis of the hydrogeochemical characteristics of the springs in the EKF and their temporal variation, aiming to address the gaps in the research on the hydrogeochemistry in the region and to investigate the changes in water chemistry during the seismogenic process. In this study, the main elements, trace elements, hydrogen isotopes, oxygen isotopes, and strontium isotopes of 23 springs in the EKF were analyzed. The results indicated that the groundwater recharge in the eastern part of the Eastern Kunlun Fault Zone mainly originates from atmospheric precipitation, as supported by its isotopic characteristics. The spring water is immature, showing weak water–rock interactions. A hydrochemical analysis classified the springs into 11 main types, reflecting varying degrees of water–rock interaction. Based on measurements using quartz geothermometers, the estimated geothermal reservoir temperatures ranged from 39.6 to 120.3 °C, with circulation depths of 1.3 to 3.8 km. By means of regularly monitoring three selected springs, this study also explored the relationship between earthquakes and hot spring chemical variations. Finally, a conceptual model of hydrogeochemistry was proposed to describe the groundwater circulation in the study area. [ABSTRACT FROM AUTHOR]

The improvement of water usage efficiency and productivity, as well as the development of effective water management plans, necessitates a comprehensive understanding of how water utilization patterns in different soil layers within arid and semi-arid climates impact the capacity of plant roots to absorb water. However, there is currently no knowledge regarding the water use strategies employed by artificial yellow willow. So, we conducted a study on the hydrogen and oxygen isotopic composition of rainfall in yellow willow (Salix gordejevii) from the semi-arid region located at the southern edge of the Hunshandak Sandland in China. This study utilized measured data on xylem water, groundwater, soil moisture, and rainfall. By employing a combination of the direct comparison method and the MixSIAR model, we investigated the water uptake strategies employed by yellow willow throughout its growing season. The findings revealed that the mean δ D was highest in precipitation and lowest in groundwater, whereas the mean δ18O was highest in stem water and lowest in groundwater. The δ D and δ18O fluctuated significantly in precipitation but were steady in groundwater. Because precipitation was significantly less than evaporation, the slope and intercept were lower for the local than global atmospheric precipitation line. Water availability steadily declined with increasing depth. Lower δ18O values were caused by precipitation diluting the soil water. The MixSIAR results indicated that the primary source in May, September, and October was utilized at 19%, 18%, and 18%, respectively. In contrast, the utilization rate of each source varied considerably in June, July, and August (the primary source was utilized at 19%, 18%, and 18%, respectively). Comparatively high rates of water absorption and utilization were observed in June (19% of the total water source), July (18%), and August (23%). Therefore, the vertical distribution of the root system and variations in the soil water content regulate water usage for the yellow willow. To prevent excessive water usage and promote ecosystem restoration with artificial yellow willow plantations in water-limited desert settings, policy makers should consider the patterns of plant water use and soil water availability. By selecting drought-adapted plant species and optimizing irrigation management, it is possible to reduce water wastage and ensure that water is used efficiently for revegetation and ecosystem restoration, avoiding overuse of water and maintaining the sustainability of revegetation in water-stressed desert areas. [ABSTRACT FROM AUTHOR]

Held every four years, the International Workshop on Tropical Cyclone (IWTC) organized by the World Meteorological Organization has been a global leading conference in the field of tropical cyclone. In preparation for the 10th IWTC (IWTC-10) in December 2022, a summary of research advances of landfalling tropical cyclone (LTC) rainfall during past four years of 2019-2022 has been prepared. Some of the latest research advances has been summarized in Lamers et al. (2023), which reviewed the latest forecast and disaster prevention methods related to TC precipitation. As a supplement, this article mainly focuses on the recent advances in LTC asymmetric rainfall evolution mechanisms and forecast verification results over China. Some new findings have been made in the LTC inner-core size relationship with the asymmetric rainfall distribution. Some major advances focused on asymmetric microphysical characteristics in the TC rainbands. Current simulation and forecast performances of LTC precipitation have been analyzed, and different forecast error sources for rainfall during different landfall stages of TC were compared. To estimate the risk of TC rainfall hazards in China, a parameterized Tropical Cyclone Precipitation Model was reviewed as well in this article. [ABSTRACT FROM AUTHOR]

Xianxian geothermal exploitation area is one of the areas with the best occurrence conditions of geothermal resource in North China, rich in medium and low temperature geothermal resource, and is a typical carbonate geothermal field. However, its hydrogeochemical evolution process is not clear, and no complete conceptual model of geothermal genesis has been established to guide the exploration, development and utilization of geothermal resource in the area. It restricts the sustainable development of regional geothermal resource and the realization of carbon emission reduction targets. In this study, geothermal fluids in the area were collected for testing and analysis in terms of hydrochemical characteristics and stable isotopes. Based on systematic geochemical research, the formation mechanism of geothermal fluids was analyzed, and a conceptual model of geothermal genetic in the study area was established. The main understanding is as follows: the hydrochemical type of geothermal water in the study area is Cl-Na type, and the water-rock interaction is not balanced. The formation of geothermal water in the area is affected by the infiltration of atmospheric precipitation, and it is terrestrial leached water. The flow path of geothermal water is long, the water circulation is slow, and the metamorphism is deep. Dolomite, calcite and gypsum dissolution are the main sources of Mg2+, Ca2+, , and in geothermal water, besides, other minerals containing calcium and magnesium are also part of their sources. The source of geothermal water recharge is atmospheric precipitation, and the recharge elevation of geothermal water is about 619–1069 m. The age of the geothermal water is between 16 000 and 18 000 years. The sulfur in geothermal water mainly comes from the leaching of sedimentary layer. [ABSTRACT FROM AUTHOR]