27 results on '"*CARBON nanofibers"'
Search Results
2. Hydrothermal growth of FeMoO4 nanosheets on electrospun carbon nanofibers as freestanding supercapacitor electrodes.
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Khadka, Ashwin, Samuel, Edmund, Pradhan, Shrayas, Joshi, Bhavana, Aldalbahi, Ali, El-Newehy, Mohamed, Lee, Hae-Seok, and Yoon, Sam S.
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SUPERCAPACITOR electrodes , *CARBON nanofibers , *NANOSTRUCTURED materials , *SUPERCAPACITORS , *ENERGY density , *AQUEOUS electrolytes , *POWER density - Abstract
In this study, an electrospinning method was used to produce highly conductive freestanding carbon nanofibers (CNFs). The freestanding CNFs are compatible with hierarchical growth techniques, such as hydrothermal processes, for the nanostructure engineering of supercapacitor electrodes with enhanced electrochemically active sites. Therefore, the flower-like FeMoO 4 @CNF nanosheets were investigated to improve the electrochemical performance using aqueous and neutral electrolytes (Na 2 SO 4 and K 2 SO 4). The optimized FeMoO 4 @CNF electrode exhibits areal capacitances of 252 and 220 mF·cm−2 at a high current density of 2.5 mA·cm−2 with Na 2 SO 4 and K 2 SO 4 electrolytes, respectively. The wide potential window (1.6 V) of the symmetric supercapacitor delivered maximum energy densities of 22.4 and 19.6 μWh·cm−2 at a power density of 2 mW·cm−2 for Na 2 SO 4 and K 2 SO 4 electrolytes, respectively. [ABSTRACT FROM AUTHOR]
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- 2024
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3. Spinning of Carbon Nanofiber/Ni–Cu–S Composite Nanofibers for Supercapacitor Negative Electrodes.
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Li, Qiong, Wang, Yu, Wei, Ganghui, Fang, Xiaorong, Lan, Ni, Zhao, Yonggang, Liu, Qiming, Lin, Shumei, and He, Deyan
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CARBON nanofibers , *NEGATIVE electrode , *CARBON-based materials , *CARBON composites , *SUPERCAPACITOR electrodes , *ELECTRODE performance , *NANOFIBERS - Abstract
The preparation of composite carbon nanomaterials is one of the methods for improving the electrochemical performance of carbon-based electrode materials for supercapacitors. However, traditional preparation methods are complicated and time-consuming, and the binder also leads to an increase in impedance and a decrease in specific capacitance. Therefore, in this work, we reduced Ni-Cu nanoparticles on the surface of nitrogen-doped carbon nanofibers (CNFs) by employing an electrostatic spinning method combined with pre-oxidation and annealing treatments. At the same time, Ni-Cu nanoparticles were vulcanized to Ni–Cu–S nanoparticles without destroying the structure of the CNFs. The area-specific capacitance of the CNFs/Ni–Cu–S–300 electrode reaches 1208 mF cm−2 at a current density of 1 mA cm−2, and the electrode has a good cycling stability with a capacitance retention rate of 76.5% after 5000 cycles. As a self-supporting electrode, this electrode can avoid the problem of the poor adhesion of electrode materials and the low utilization of active materials due to the inactivity of the binder and conductive agent in conventional collector electrodes, so it has excellent potential for application. [ABSTRACT FROM AUTHOR]
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- 2024
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4. Fabrication of S/CoS2/NiS2/PZH composite using hydrothermal technology for high-performance supercapacitors.
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Zhang, Ya Yuan, Xue, Yan Xue, Dai, Fei Fei, Gao, Ding Ling, Liu, Yu Xiang, Qin, Na, Chen, Jian Hua, and Yang, Qian
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CARBON nanofibers , *SUPERCAPACITOR electrodes , *SUPERCAPACITORS , *ELECTRIC conductivity , *METAL sulfides , *CHARGE transfer , *TRANSITION metals - Abstract
Transition metal sulfides (TMSs) are favorable as electrode materials for supercapacitors (SCs) because of their high theoretical capacity, low cost, fascinating redox reversibility, electronic conductivity, and reduced charge transfer resistance. However, TMS electrodes suffer from weak compatibility and combination at heterogeneous interfaces, resulting in TMS stripping and electrode capacity degradation during long-term charging/discharging processes. Herein, we used a convenient, feasible, cheap, and environmentally friendly hydrothermal method to grow S/CoS2/NiS2in situ on Pien Tze Huang-based porous carbon (PZH) to promote the poor electric conductivity and unsatisfactory cycling stability of TMSs. Furthermore, TMSs can be tightly embedded on the surface of PZH to prevent falling off or collapse during long-term processes and usage. The prepared S/CoS2/NiS2/PZH electrode possessed an excellent specific capacitance of 1159.2 F g−1 at 0.5 A g−1, and after 10 000 cycles at 5 A g−1, the capacitance retention was maintained over 84.6%. This in situ method is promising for the development of stable TMS-based electrodes for supercapacitors. [ABSTRACT FROM AUTHOR]
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- 2024
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5. Promoted OH– adsorption and electron-transfer kinetics by electrospinning mono-disperse NiCo2S4 nanocrystals within porous CNFs for solid asymmetric supercapacitors.
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Xie, Feng, Zhu, Haoxian, Qu, Yaru, Hu, Jingjing, Tan, Hankun, Wang, Ke, and Sun, Li
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ADSORPTION kinetics , *CARBON nanofibers , *NANOCRYSTALS , *SUPERCAPACITORS , *ELECTROSPINNING , *NEGATIVE electrode - Abstract
The Lotus-leaf-stem-like NiCo 2 S 4 /CNF composite is prepared with mono-disperse NiCo 2 S 4 nanocrystals in-situ electrospun within porous CNFs for improved supercapacitive performance. [Display omitted] • DFT calculation results show that NiCo 2 S 4 has higher electronic conductivity and lower adsorption energy of OH– than NiS and CoS. • One-step electrospinning of metal ions and carbon sources by a very simple method. • Ex-situ XPS characterization test verifies that NiCo 2 S 4 /CNF has higher proportion of metal ions involved in electrochemical reactions and larger number of transferred electrons. • l -ASC and S-ASC devices have high-performance energy storage. S-ASC devices have excellent low-temperature performance and stability. Bimetallic sulfide NiCo 2 S 4 has been regarded as a potential supercapacitor electrode material with excellent electrochemical performance. However, the origin of its high specific capacity is little studied, and the design of a rational structure still remains a challenge to exert its intrinsic advantage. In this work, the advantage of NiCo 2 S 4 over NiS and CoS is explained by density functional theory calculation from the aspects of energy band, density of electronic states and OH– adsorption energy. It is proved that the synergistic effect of Ni and Co in NiCo 2 S 4 can reduce its OH– adsorption energy and provide more active electrons near the Fermi level, thus promoting electrochemical reaction kinetics in supercapacitors. Then, a simple electrospinning method is used to in-situ load mono-disperse NiCo 2 S 4 nanocrystals within amorphous carbon nanofibers, obtaining a porous, lotus-leaf-stem-like one-dimensional nanocomposite of NiCo 2 S 4 /CNF. Ex-situ XPS characterization confirms that the proportion of metal ions involved in electrochemical reactions and the number of transferred electrons in NiCo 2 S 4 /CNF during the redox reaction are significantly higher than those in mono-metallic sulfides (NiS/CNF and CoS/CNF), verifying the calculation results. With its boosting reaction kinetics, the NiCo 2 S 4 /CNF gives the specific capacity of 757.97C g−1 at 1 A/g and the capacity retention of 95.15 % after 10,000 cycles at 5 A/g, both greater than NiS/CNF and CoS/CNF. The NiCo 2 S 4 /CNF, as the positive electrode, and activated carbon, as the negative electrode, are assembled into liquid-state and solid-state asymmetric supercapacitor (ASC) devices, and both show high power density (760.6 W kg−1 for liquid-state device and 1067.4 W kg−1 for solid-state device), high energy density (52.25 Wh kg−1 for liquid-state device and 48.54 Wh kg−1 for solid-state device) and great cycle stability. Moreover, the solid-state ASC device possesses excellent low temperature capacity and reversibility, further demonstrating the wide application potential of the NiCo 2 S 4 /CNF composite. [ABSTRACT FROM AUTHOR]
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- 2024
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6. MnO2 Nanoparticle‐Loaded Self‐Doped (N/O) Porous Carbon Derived from Orychophragmus Violaceus for Application as a High‐Performance Supercapacitor.
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Ma, Zihan, Li, Shaoqi, Wang, Lishuang, Chen, Tingting, and Wang, Guangning
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CARBON nanofibers , *SUPERCAPACITORS , *ENERGY density , *ELECTRIC capacity , *COMPOSITE materials , *CARBON - Abstract
Waste orychophragmus violaceus was used to prepare a novel 3D self‐doped (N/O) porous carbon (OPC). The aim was to expand the application and increase the value of waste orychophragmus violaceus. In order to improve its specific capacitance, composites OPC@MnO2x of OPC and MnO2 were prepared by simple hydrothermal method. In 6 M KOH, specific capacitance obtained by OPC at 1 A g−1 is 268 F g−1, surprisingly, specific capacitance of OPC@MnO232 can be up to 419 F g−1 at 1 A g−1 and its capacitance retention rate is as high as 83.62 % after 10000 cycles (20 A g−1). The energy density of OPC@MnO232//OPC asymmetric supercapacitor in 1 M Na2SO4 can even reach 14.22 Wh kg−1 at 400 W kg−1, besides, it showed good cycling stability after 10000 cycles (20 A g−1), with capacitance retention rate of up to 86.64 %. Finally, the device is tested in an application. Connecting two identical asymmetric supercapacitors in series enables red LED to emit greater than 90 s. Overall, this study confirms that the waste orychophragmus violaceus derived porous carbon can reduce the wastage of waste resource, additionally, the composite material prepared is an electrode material for high‐performance supercapacitors with broad prospects. [ABSTRACT FROM AUTHOR]
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- 2024
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7. Impact on electrochemical performance of SiO2/Polyaniline@Carbon nanofibers composite electrode by biosilicification with different tetraethyl orthosilicate concentration.
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Jeon, Se Jin, Kim, Do Hwan, Kim, Hyun-Chel, Amna, Touseef, Hassan, Mallick Shamshi, Seo, Hae-Cheon, and Khil, Myung-Seob
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ETHYL silicate , *ENERGY density , *ENERGY storage , *ION channels , *CARBON nanofibers , *NANOFIBERS , *AQUEOUS electrolytes - Abstract
To overcome the drawback of carbon nanofibers (CNFs) such as the low energy density and low specific capacitance as electrode for supercapacitors, SiO 2 /PANI@CNFs composite was prepared by layer-by-layer (LbL) assembly technique, in which the SiO 2 served as a component for improving capacitive behavior. Polyaniline (PANI) is used as nucleation site for synthesizing SiO 2 particles as well as active material for improving capacitance. In this study, SiO 2 particles were synthesized using biosilicification process as a bioinspired, rapid, and facile synthetic route for SiO 2 particles at ambient temperature and pressure, etc. To elucidate effect of SiO 2 on the electrochemical properties, SiO 2 /PANI@CNFs samples were prepared by varying concentration ratio of tetraethyl orthosilicate (TEOS) to CNFs. It was observed that the specific surface area and the capacitance are highly dependent on the TEOS concentration. The capacitance of the composite prepared at the TEOS concentration of 0.19 mmol reaches 412 F g−1 at the current density of 1 A g−1. These results are attributed to increased specific surface area from interstitial voids between SiO 2 particles and hydrophilic nature of SiO 2 particles, which offers sufficient channels for rapid ion diffusion and leads easy accessibility to the active sites for the electrochemical reaction between electrode and aqueous electrolyte. Due to its excellent electrochemical and biocompatible properties, bioinspired SiO 2 inorganic material will promote the development of energy storage devices in biomedical and environmental electronics. [ABSTRACT FROM AUTHOR]
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- 2024
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8. Rational design of one-dimensional skin-core multilayer structure for electrospun carbon nanofibers with bicontinuous electron/ion transport toward high-performance supercapacitors.
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Wang, Guangpei, Hu, Guodong, Lan, Jing, Miao, Fujun, Zhang, Peng, and Shao, Guosheng
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SUPERCAPACITOR electrodes , *CARBON nanofibers , *ION transport (Biology) , *ENERGY density , *ENERGY storage , *SUPERCAPACITORS , *POWER density , *SUPERSYMMETRY - Abstract
[Display omitted] • 1D skin-core multilayer structure was fabricated by a facile template method. • Bicontinuous electron/ion transport during the charge/discharge process. • The large specific surface area and hollow hierarchical porous structure. • Adjusting active layers or sites can obviously improve the capacitive properties. • The maximum energy density of 8.77 Wh kg−1 at a power density of 0.25 kW kg−1. The fast transport of electrons and ions within electrodes is crucial to the final electrochemical properties. Herein, we have developed a unique ultra-long one-dimensional (1D) skin-core multilayer structure based on electrospun carbon nanofibers mainly through a facile Stöber method combined with resorcinol–formaldehyde resin, which not only achieves bicontinuous electron/ion transport during the charge/discharge process, but also provides large surface area for ion adsorption. Particularly, controlling the number of active layers as well as regulating the active sites in layer both can obviously improve capacitive properties. Benefiting from the synergistic effects of the desirable architecture, such the rational-designed skin-core structural carbon nanofibers as supercapacitor electrode can deliver a high specific capacitance up to 255 F g−1 at 0.5 A g−1, favorable rate capability with 89% capacitance retention of initial capacitance at 8 A g−1, and excellent cycling stability with nearly 93% capacity retention after 10,000 cycles at 2 A g−1. Furthermore, the as-assembled symmetric supercapacitor devices also present a maximum energy density of 8.77 Wh kg−1 at 0.25 kW kg−1 and a maximum power density of 3.70 kW kg−1 at 6.74 Wh kg−1. Such skin-core carbon nanofibers provide an effective strategy to design high-performance supercapacitor electrode for the next-generation energy storage devices. [ABSTRACT FROM AUTHOR]
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- 2024
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9. Biomass-based carbon nanofibers enhanced by carbon quantum dots for high-performance supercapacitors and moist-electric generators.
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Jin, Zhenxing, Cao, Qiping, Gong, Hui, Chen, Bo, Jiang, Yuewei, Su, Yingying, Zhou, Jinghui, and Li, Yao
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CARBON nanofibers , *QUANTUM dots , *ELECTRIC generators , *SUPERCAPACITORS , *LIGNIN structure , *POWER resources , *ELECTRIC power production - Abstract
Developing a simple and effective method for optimizing lignin structure is a key challenge for the application of biomass-based carbon nanofibers in energy storage and moisture-enabled electricity generation fields. In this work, an effective strategy is designed to prepare novel biomass-based carbon nanofibers. Carbon quantum dots (CQDs) are introduced as functional components into biomass-based carbon nanofibers to optimize the inherent structural defects of lignin. The introduction of CQDs effectively reduces the interaction between lignin macromolecules, thereby increasing the flexibility of lignin macromolecule chain segments. The obtained biomass-based carbon nanofibers exhibit excellent microfiber morphologies and a high degree of graphitization. The specific capacitance and energy density for biomass-based carbon nanofibers as the energy storage device reach 294.4 F/g and 28.3 W h/kg, respectively. Furthermore, the biomass-based moist-electric generator shows high power generation efficiency, the output voltage and output current of a single device reach 0.75 V and 1.8 μA, respectively. Notably, as the number of biomass-based moist-electric generators in series or parallel increases, the overall output efficiency of the device system has a linear relationship, which means that a sufficient number of biomass-based moist-electric generator devices can meet the power supply requirements of larger power systems. This work puts forward a promising strategy to prepare low-consumption, high-performance, and environmentally friendly biomass-based carbon nanofibers for the supercapacitors and moist-electric generators. [Display omitted] • The introduction of CQDs optimize the inherent structural defects of lignin. • CQDs improve the fiber morphology and graphitization degree of carbon nanofibers. • Biomass-based carbon nanofibers exhibit excellent electrochemical performance. • Biomass-based carbon nanofibers can be used for a novel moist-electric generator. • The preparation of novel biomass-based carbon nanofibers was proposed. [ABSTRACT FROM AUTHOR]
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- 2024
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10. Electrospun nickel cobalt phosphide/carbon nanofibers as high-performance electrodes for supercapacitors.
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Zhao, Zhe, Miao, Yundi, and Lu, Qingshan
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CARBON nanofibers , *SUPERCAPACITOR electrodes , *COBALT phosphide , *NICKEL phosphide , *SUPERCAPACITORS , *CARBON electrodes , *NEGATIVE electrode , *HYDROGEN evolution reactions - Abstract
Nickel cobalt phosphide/carbon nanofibers (NiCoP/C) with an average diameter of approximate 200 nm are prepared by electrospinning combined with calcinations. Carbon nanofibers with an average pore size of 10.77 nm as conductive skeletons support the dispersed NiCoP nanoparticles with the size ranging from 20 to 80 nm, providing abundant reactive sites and facilitating the electrochemical reactions. The specific capacitance of NiCoP/C reaches 478 F g−1 at 2 A g−1 in a 3 M KOH electrolyte, showing superior electrochemical properties compared to its counterparts. After 5000 charge/discharge cycles at 10 A g−1, 99.99 % of initial specific capacitance is retained. In addition, an asymmetric supercapacitor assembled using NiCoP/C as positive electrode and activated carbon as negative electrode exhibits an energy density of 16.72 Wh kg−1 at a high-power density of 7250 W kg−1. Furthermore, the capacitance loss of the supercapacitor is only 0.04 % after 5000 cycles at 10 A g−1, which is mainly attributed to the enhanced stability of NiCoP nanoparticles owing to the assistance of carbon nanofibers as the skeleton. The synergistic effects of NiCoP nanoparticles and carbon nanofibers result in the boosted electrochemical performances. This study demonstrates the potential application of carbon nanofibers as conductive skeletons for nanostructured electrodes. • NiCoP/C nanofibers were prepared by electrospinning without the emission of PH 3. • Carbon nanofibers acted as skeletons and conductive channels for NiCoP. • Assembled NiCoP/C//AC supercapacitor achieved 16.72 Wh kg−1 at 7250 W kg−1. [ABSTRACT FROM AUTHOR]
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- 2024
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11. CoS2-CoSe2 hybrid nanoparticles grown on carbon nanofibers as electrode for supercapacitor and hydrogen evolution reaction.
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Cui, Wenjing, Sun, Xingwei, Xu, Shaoshuai, Li, Chunping, and Bai, Jie
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CARBON nanofibers , *HYDROGEN evolution reactions , *SUPERCAPACITORS , *CARBON electrodes , *SUPERCAPACITOR electrodes , *STANDARD hydrogen electrode , *ENERGY storage - Abstract
Exploring energy storage devices and hydrogen evolution reaction electrode materials with high efficiency electrocatalytic activity, high energy density and low cost has broad prospects, but there are still huge challenges. Compared with traditional energy storage devices, supercapacitors (SCs) are a new type of energy storage device with broad development prospects. However, their practical application is significantly limited by the energy density of electrode materials. The practical application of hydrogen evolution reaction (HER) is limited by the high cost and scarcity of Pt-based precious metal catalysts. It is essential to develop materials with stable structure, low cost and abundant reserves. Here, in this paper, CoS 2 and CoSe 2 composites embedded in carbon nanofibers (CNFs) (expressed as CoS 2 -CoSe 2 /CNFs) were synthesized by electrospinning combined with in-situ growth Zeolite Imidazolate Framework-67 strategy, carbonization and subsequent selenium sulfide process. When employed as the positive material in supercapacitors, a specific capacitance of 292.2 F g−1 is achieved at a current density of 1 A g−1. The specific capacitance of asymmetric supercapacitors (ASCs) assembled with CoS 2 -CoSe 2 /CNFs-5 as positive materials remains stable with no significant change observed in specific capacitance even after undergoing 10,000 cycles. At the same time, when a current density of 10 mA cm−2 is applied in a 0.5 M H 2 SO 4 electrolyte solution, an overpotential reading of 189 mV is observed. The evidence mentioned above showcases the significant capacity of this substance for application in electrochemical energy storage and conversion. • The synergy of different components regulates the electronic structure. • The as-obtained materials exhibited a good energy storage and conversion performance. • The retention of the ZIF-67 skeleton structure can increases the number of active sites. [ABSTRACT FROM AUTHOR]
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- 2024
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12. Polymer-mediated vacancy defects of graphene sheets as high-performance cathode materials for aqueous zinc-ion hybrid supercapacitors.
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Zhang, Ran, Song, Ming, Zhu, Xingqun, and Pan, Likun
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CARBON nanofibers , *SUPERCAPACITORS , *ENERGY storage , *GRAPHENE , *ENERGY density , *CATHODES - Abstract
[Display omitted] • The vacancy-defective graphene sheets are constructed successfully through polyacrylonitrile thermally mediated. • Vacancy defects on graphene sheets can enhance electrons/ions transport kinetics • The assembled aqueous zinc-ion hybrid supercapacitors exhibit a high energy density and outstanding cycling stability. The electrochemical behavior of graphene sheets in energy storage system is closely related to its electronic structures. Specifically, structural vacancy defects can expose more active sites and enhance the electrochemical performance. However, it is still a challenging problem to realize valid defect regulation on improving the reaction kinetics of electrode materials. Herein, vacancy-defective graphene sheets were constructed through the thermal mediated method via intercalation of polyacrylonitrile nanofibers. The vacancy defects were generated from the NH 3 gas resulting from polymer decomposition at gradient carbonization temperature. The obtained composites of the graphene sheets and carbon nanofibers demonstrate that the vacancy defects benefit to charge transport, allowing more electrons to pass through the interlayered structure, and enhance the adsorption capacitance during the reversible electrochemical process. In addition, the as-assembled Zn ion hybrid supercapacitors exhibit a high energy density of 129.9 Wh kg−1 and outstanding cyclic stability (99.8 % after 10,000 cycling). The confined polymer-mediated thermal modification strategy can afford abundant vacancy defective sites and exhibit promising outlook for constructing high-performance graphene-based electrode materials for Zn ion hybrid supercapacitors. [ABSTRACT FROM AUTHOR]
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- 2024
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13. Dual-role KCl-assisted fabrication of porous carbon with controllable architecture from coal liquefaction residue for supercapacitors.
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Yang, Xiaoxia, Sun, Guoxiao, Wang, Fei, Chen, Long, Zhang, Zhuangzhuang, Zhen, Yanzhong, Wang, Danjun, Fu, Feng, and Chi, Ru'an
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CARBON nanofibers , *COAL liquefaction , *SUPERCAPACITORS , *POROSITY , *CARBON , *ENERGY density , *CARBON dioxide - Abstract
Schematic illustration of the preparation of porous carbons. [Display omitted] • The porous carbons with controllable architecture were fabricated by a dual-role KCl-assisted activation method. • KCl not only serves as an auxiliary template but also contributes to an enhancement in the melting of K 2 CO 3. • The prepared porous carbons possess well-developed pore structure and excellent electrochemical performance. • This work paves a path to prepare porous carbons via an environment-friendly and cost-effective route for supercapacitors. Preparation of high-performance electrode materials in a low-cost and simple way is of great significance for the application and development of supercapacitors. Herein, a dual-role KCl-assisted KOH activation method with low KOH consumption was employed to fabricate porous carbons with controllable architecture, using the coal liquefaction residue (CLR) as the raw material. It is indicated that KCl not only serves as an auxiliary template for pore-forming but also contributes to an enhancement in the melting of K 2 CO 3 , an intermediate of KOH activation, resulting in an improvement in the efficiency of KOH activation. As a consequence, the prepared samples possess highly developed pore structure even at a low KOH consumption, which endow them with excellent capacitive performance. The as-fabricated optimal porous carbon (LR-KPC-4) displays a maximum specific capacitance of 375 F g−1 at 0.5 A/g and superior rate capacity, which are much better than those of the porous carbon prepared without KCl. The fabricated symmetric supercapacitor shows a high specific capacitance of 256 F g−1 at 0.5 A/g, energy density of 8.9 Wh kg−1 at 125 W kg−1 and great cycling stability. This work demonstrates a facile strategy to efficiently convert CLR into porous carbons for high-performance supercapacitors. Meanwhile, it paves a promising way for value-added utilization of CLR. [ABSTRACT FROM AUTHOR]
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- 2024
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14. Harmony of nanosystems: Graphitic carbon nitride/carbon nanomaterial hybrid architectures for energy storage in supercapacitors and batteries.
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Haruna, Adamu, Dönmez, Koray Bahadır, Hooshmand, Sara, Avcı, Ertuğ, Qamar, Mohammad, Zaidi, Shabi Abbas, Shahzad, Faisal, Miller, Thomas S., Chakrabarti, Barun Kumar, Howard, Christopher A., and Bayazıt, Mustafa Kemal
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CARBON nanofibers , *CARBON-based materials , *ENERGY storage , *NANOSTRUCTURED materials , *HYBRID materials , *RENEWABLE energy transition (Government policy) - Abstract
Developing high-performing and scalable electrode materials for supercapacitors and batteries has been of tremendous interest for the world's forthcoming clean and renewable energy transition. As a versatile material, Two-dimensional graphitic carbon nitride (g-CN) has been utilized in electrochemical energy storage (EES) applications due to its nitrogen-rich adsorption sites, cost-effective production, and tunable electronic structure. The electrochemical performance of pristine g-CN has been boosted by forming hybrid architectures with highly conductive carbon-based materials, such as graphene, reduced graphene oxide, carbon nanofibers, carbon nanotubes, and beyond (e.g., MXene). Using such heterogeneous compositions for EES applications has significantly increased in recent years. This study reviews the g-CN/carbon nanomaterial (CNM) hybrids, considering the dimensionality in nanomaterials, and underscores the influence of the material's dimensionality and the synthesis/fabrication routes. The effect of structural and physicochemical changes on the electrode's electrochemical performance after hybridization is presented comparatively. Besides, the comprehensive review outlines challenges and future improvements in g-CN/CNM hybrid materials for outstanding developments in energy storage systems. [Display omitted] • Graphitic carbon nitride (g-CN)/carbon nanomaterial (CNM) hybrids are reviewed for supercapacitor and battery applications. • The impact of the CNM-type on the hybrid electrode's performance is examined through a chemical and physical perspective. • An overview of how hybrid electrode synthesis affects ion/electron transport, surface area, and porosity is provided. • Design-oriented control of the physicochemical properties for enhanced electrochemical performance is exemplified. • g-CN/CNM nanoarchitectures are emphasized as electrode materials with the potential for easy scalability. [ABSTRACT FROM AUTHOR]
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- 2024
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15. Vanadium nitride-vanadium oxide-carbon nanofiber hybrids for high performance supercapacitors.
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Wunch, Melissa A., Garcia, Juan Alex, Mahmood, Samsuddin Faisal, Tian, Yafen, Balkus, Kenneth J., Ferraris, John P., and Yang, Duck Joo
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VANADIUM , *SUPERCAPACITORS , *ENERGY storage , *SUPERCAPACITOR electrodes , *VANADIUM oxide , *ENERGY density , *CARBON nanofibers , *NITRIDATION - Abstract
Vanadium Nitride (VN) is attractive for energy storage due to its high conductivity (1.6 × 106 S/m) and specific capacitance (1350 F/g) but limited to alkaline electrolytes for redox. In contrast, V 2 O 3 is redox active but not very conductive. In these hybrids a mixture of VN and vanadium oxide (V 2 O 3) were encapsulated in electrospun carbon-nanofibers. A combination of VN and V 2 O 3 takes advantage of the high conductivity from VN and the redox activity from V 2 O 3. Additionally, having the vanadium encapsulated within the carbon can help with the stability as the electrolyte will not have direct interaction with the surface. These hybrids were made by in-situ nitridation of the encapsulated V 2 O 5 followed by ex-situ activation with carbon dioxide. The hybrids were characterized by XPS and Raman spectroscopy. Hybrids of VN/V 2 O 3 -CNF showed increased capacitance of 245 Fg−1 with energy and power densities of 70.2 Wh kg−1 and 1751 W kg−1 in ionic liquid electrolyte. The devices showed good cycle stability with ∼90 % retention after 10,000 cycles at a current density of 1 Ag−1. These findings highlight the potential of VN/V 2 O 3 -CNF hybrids as high-performance supercapacitor electrodes. The combination of high conductivity and redox activity, along with encapsulation within CNFs, opens promising avenues for advanced energy storage. [ABSTRACT FROM AUTHOR]
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- 2024
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16. Binder-free laser induced graphene-MnO2 composite electrodes for high areal energy density flexible supercapacitors.
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Rao, Ankitha, Bhat, Somashekara, and De, Shounak
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ENERGY density , *SUPERCAPACITORS , *ELECTRODES , *ENERGY storage , *GRAPHENE synthesis , *POWER density , *CARBON nanofibers - Abstract
The synthesis of Laser-Induced Graphene (LIG) through the laser ablation process of carbon-containing materials is a rapid and scalable process which enables the production of graphene in a cost-effective manner. In recent years, metal oxide – graphene composite electrodes have gained a lot of importance due to their use in various Energy Storage Devices (ESDs). In our investigation, we manufacture composite electrodes of manganese dioxide (MnO 2) and LIG through a hydrothermal process and use it as electrodes in Flexible Supercapacitors. This method deviates from traditional procedures as it eliminates the requirement for binders in creating composite electrodes, given that MnO 2 can be directly deposited onto the LIG electrodes. The assembled all-Flexible Supercapacitor (FSC), featuring unique LIG-MnO 2 composite electrodes, showcased a remarkable areal capacitance of 66.5 mF cm−2 at 5 mV s−1 scan rate. The device also exhibited a very high areal energy density (2.3 mWh cm−2) and power density (19.7 mW cm−2) at 0.2 mA cm−2 current density. Also, 82 % capacitance retention was observed at the end of 2000 cycles and the device also exhibited a good flexibility during bending tests, as evidenced by an 80 % capacitance retention after 100 bending cycles. [ABSTRACT FROM AUTHOR]
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- 2024
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17. Rapid preparation of P/O doped nano-porous carbon by microwave method for high-performance supercapacitors.
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Li, Xusen, Sun, Bingxin, Lin, Liwei, Piao, Yuanzhe, Diao, Guowang, and Zhang, Wang
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CARBON nanofibers , *DOPING agents (Chemistry) , *SUPERCAPACITORS , *CARBON-based materials , *MICROWAVES , *PHYTIC acid - Abstract
This paper proposes a simple and rapid microwave-assisted phosphorus-oxygen doped porous carbon (P/O-PC) preparation strategy is proposed using potassium citrate, Phytic acid (PA), and ethanol under air atmosphere. PA can be used as both a phosphorus source and a microwave absorbing agent. The P/O-PC500–0.75 has a large specific surface area of 905 cm2/g. P/O doping introduces defects into the carbon structure, which enhances the capacitance of the porous carbon. The P/O-PC500–0.75 demonstrates excellent capacitance values of 330 F/g and 389.4 F/g in 6.0 M KOH and 1.0 M H 2 SO 4 , respectively (1 A/g). In addition, the symmetrical supercapacitors assembled with the P/O-PC500–0.75 exhibit good electrochemical stability over 5000 cycles at 5 A/g, with a capacitance loss of only 3.6%. This microwave-assisted strategy offers simplicity in operation and low energy consumption, providing a new and efficient pathway to prepare carbon materials in a fast and simple manner. [Display omitted] [ABSTRACT FROM AUTHOR]
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- 2024
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18. Flexible porous carbon nanofibers derived from cuttlefish ink as self-supporting electrodes for supercapacitors.
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Wang, Dawei, Lian, Yue, Fu, Hongliang, Zhou, Qiuping, Zheng, Yujing, and Zhang, Huaihao
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SUPERCAPACITORS , *CARBON nanofibers , *CUTTLEFISH , *CARBON-based materials , *CARBON electrodes , *SUPERCAPACITOR electrodes , *ENERGY density - Abstract
Using renewable biomass precursors to develop high-performance carbon electrodes is a promising approach for the advancement of supercapacitors. This work proposes a feasible strategy to prepare self-supporting flexible porous carbon nanofibers by electrospinning and carbonizing the mixture of cuttlefish ink, polyacrylonitrile (PAN) and polymethyl methacrylate (PMMA). The impacts of cuttlefish ink precursor on the structure, elemental composition, and capacitance properties of carbon nanofibers have been studied. Herein, the unique structural advantage of cuttlefish ink can significantly optimize the porous structure of carbon nanofibers. Due to the hierarchical porous structure, large specific surface area, hollow channels and high nitrogen content, the carbon nanofibers offer a high specific capacitance of 364.8 F g−1 at 0.5 A g−1 current density, alongside desirable rate performance and cycle life. Furthermore, the carbon nanofiber electrode performs good mechanical flexibility. The flexible solid-state supercapacitor based on this electrode exhibits 14.1 Wh kg−1 energy density at 0.4 kW kg−1 power density, and 97.8% capacitance retention after 5000 cycles. The favorable capacitive properties make this carbon nanofiber material a potential candidate for supercapacitor electrodes. [Display omitted] • Electrospun porous carbon nanofibers (CPP–CNF) were prepared from cuttlefish ink. • CPP-CNF features hierarchical pores and hollow channels. • CPP-CNF is mechanically flexible with superior capacitive performance. • The flexible supercapacitor achieves high energy density and cycling stability. [ABSTRACT FROM AUTHOR]
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- 2024
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19. Regulating medical wasted cotton into porous carbons for high-performance supercapacitors and zinc-ion hybrid capacitors.
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Chen, Gui, Lu, Binxiong, Li, Jiabin, Wu, Caijuan, Xiao, Yong, Dong, Hanwu, Liang, Yeru, Liu, Yingliang, Hu, Hang, and Zheng, Mingtao
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CARBON nanofibers , *SUPERCAPACITORS , *CAPACITORS , *MEDICAL wastes , *ENERGY storage , *ENERGY density - Abstract
Although high-rate, long-cycle energy storage devices play a crucial role in the field of energy storage, they are relatively under-reported. This work reports the preparation of fibrous porous carbons ultra-high specific surface area of 3384 m2g-1 derived from medical waste degreased cotto. As electrode material for supercapacitors, the resulted porous carbons demonstrate an ultra-high specific capacitance of 505.5 F g−1 at 0.5 A g−1 in a three-electrode system with 6 M KOH as electrolyte. Assembled symmetric supercapacitors show a specific capacitance of 403.84 F g−1 at 0.5 A g−1 and 294.95 F g−1 at 20 A g−1, with a capacity retention rate of 73.62 %, impressively retaining 82.66 % of the capacity after 300000 cycles at 10 A g−1. The average capacity loss is minimal, at 0.000557 % per cycle. The as-assembled zinc-ion hybrid capacitors (ZIHCs) demonstrate a high energy density of 69.33 Wh kg−1 at 2400 W kg−1 in 2 M ZnSO 4 electrolyte and retain 99.3 % capacity after 120000 cycles at 7 A g−1, suggesting the excellent long cycling stability. These outstanding performances demonstrate a promising solution for recycling and utilizing medical waste-degreased cotton in energy storage devices, also addressing the research gap in high-rate, long-cycle applications. • Medical decreased waste cotton is efficiently transformed into porous carbons. • Porous carbons exhibit an ultra-high specific surface area of 3384 m2g-1. • As For supercapacitors (SCs), it exhibits high capacitance of 505.5 F g−1. • After 300000 cycles, SCs maintain a high-capacity retention rate of 82.66 %. • After 120000 cycles, the ZIHCs maintain a high-capacity retention rate of 99.3 %. [ABSTRACT FROM AUTHOR]
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- 2024
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20. Enhancing the performance of quasi-solid-state flexible supercapacitors with Ag and MnO2 co-decorated carbon nanofibrous electrodes.
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Yang, Sang-Ren, Cheng, Shao-Liang, Hsu, Hao-Teng, Wardhana, Bayu Satriya, Jiang, Ming-Xun, Tsao, I-Yu, Hung, Wei-Hsuan, Wang, Kuan-Wen, and Lee, Sheng-Wei
- Subjects
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SUPERCAPACITORS , *CARBON electrodes , *ENERGY density , *STANDARD hydrogen electrode , *ENERGY storage , *POWER density , *NANOFIBERS - Abstract
• MnO 2 /CNF/Ag nanofabric electrodes are developed for flexible supercapacitors. • The brittle issue in the CNF electrode is greatly improved by an Ag incorporation. • The optimized MnO 2 /CNF/Ag electrode has a specific capacitance of 184 F/g at 1 A/g. • An energy density of 16.3 Wh/kg and a power density of 400 W/kg was achieved. • A capacitance retention rate of 87 % was demonstrated when subjected to bending. Flexible supercapacitors are gaining increasing popularity due to their potential in powering portable, wearable, and lightweight electronic devices. In this study, we have successfully developed a high-performance flexible electrode for quasi-solid-state supercapacitors by incorporating Ag into carbon nanofibers (CNF) through electrospinning, and growing MnO 2 as an active material on the electrode using an in-situ redox method. The Ag and MnO 2 co-decorated CNF electrode offers several advantages over conventional CNF electrodes, including an enlarged reaction area, higher charge storage capacity, and improved resistance to brittleness issues. Among all the quasi-solid-state supercapacitors tested, the MnO 2 -decorated electrode with an optimized Ag incorporation exhibited the highest specific capacitance of 184 F/g at a current density of 1 A/g, representing a remarkable 17-fold increase compared to the reference CNF electrode. Furthermore, the Ag and MnO 2 co-decorated electrode demonstrated an energy density of 16.3 Wh/kg and a power density of 400 W/kg at the same current density. Notably, the electrode exhibited excellent flexibility, with a capacitance retention rate of 87 % when subjected to bending with a curvature ranging from 5 to 1.25 cm. Our results suggest that the Ag and MnO 2 co-decorated CNF electrode holds great promise for flexible energy storage applications. [Display omitted] [ABSTRACT FROM AUTHOR]
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- 2024
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21. N, O, S Co-doped activated carbon nanofibers derived from hydroxyl-containing polyimides as self-supporting electrodes for supercapacitors.
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Li, Rui, Lu, Yunhua, Zheng, Wenyue, Xiao, Guoyong, Zhao, Hongbin, Hu, Zhizhi, Zhu, Jianmin, and Liu, Zhaobin
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- *
CARBON nanofibers , *ACTIVATED carbon , *DOPING agents (Chemistry) , *POLYIMIDES , *SUPERCAPACITOR electrodes , *SUPERCAPACITORS , *NANOFIBERS , *ENERGY density - Abstract
Herein, a kind of hydroxyl and sulfonyl-containing diamine 2,2-bis[4-(3-hydroxy-4-aminophenoxy)phenyl]sulfone (BHAPS) was first synthesized and polymerized with pyromellitic dianhydride (PMDA) to obtain poly(amic acid) (PAA) solution. Then, the PAA nanofibers were fabricated by electrospinning technology, which were further thermally treated at 300 °C for imidization, 450 °C for rearrangement and a certain final temperature for carbonization to obtain carbon nanofibers (CNFs). The PAA concentration, carbonization temperature and thermal rearrangement time were separately optimized, and the HPI-CNF-20-2-800 exhibited better electrochemical properties. Next, the HPI-CNF-20-2-800 was chemically activated with KOH to enhance specific surface area. The preferred A-HPI–CNF–1/3 demonstrated a specific capacitance maximum of 335.0 F g−1 at 0.5 A g−1, with a 73 % capacitance retention at 10 A g−1. Furthermore , the SC device was symmetrically assembled with self-supporting A-HPI–CNF–1/3 membranes, which showed a maximum energy density of 10.42 Wh kg−1 at a power density of 250.0 W kg−1. In addition, the capacitance retention rate of the SC reached 99.94 % even after 50,000 charge/discharge cycles at a current density of 1 A g−1. Thus, this work reports a new precursor to prepare N, O, S co-doped active CNFs with better electrochemical performance, which will provide a reference for the preparation of co-doped self-supporting SC electrodes. • A new kind of diamine monomer containing hydroxyl and sulfonyl was synthesized. • The N, O, S co-doped activated carbon nanofibers were prepared. • The capacitive performance of self-supporting electrode was effectively boosted. [ABSTRACT FROM AUTHOR]
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- 2024
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22. Self-single-doped hierarchical porous carbon nanofiber derived Alpinia galanga stem-based for boosted supercapacitor performance.
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Taer, Erman, Nursyafni, Nursyafni, Febriani, Widya, Apriwandi, Apriwandi, Manjunatha, Jamballi G., Deraman, Mohamad, and Taslim, Rika
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- *
CARBON nanofibers , *SUPERCAPACITOR performance , *ALPINIA , *SUPERCAPACITOR electrodes , *SUPERCAPACITORS , *ENERGY density , *OXIDATION-reduction reaction , *CARBON - Abstract
[Display omitted] • Self-O-doped Alpinia galanga stem-based carbon nanofiber succesfully synthesis. • The hierarchical porous carbon exhibit high specific surface area of 1065.58 m2/g. • The porous carbon was performed in solid-free binder form. • In 2-electrode system, supercapacitor possessed specific capacitance of 226F g−1. In this study, activated carbon with hierarchical pores and a nanofiber structure doped with oxygen was prepared using a pure biomass-based sustainable strategy involving integrated chemical impregnation and pyrolysis. Alpinia galangal stem was chosen as it functions as fast conductive network with abundant electrochemical active sites for high-grade electrode materials. The optimal precursor exhibited self-doping of oxygen ranging from 6.15 to 15.69 % with 1065.58 m2/g, which contributed to the redox reaction of the electrode material. When tested in a 2-electrode system, the porous carbon nanofibers showed a high specific capacitance of 226F g−1 at 1 A g−1 in 1 M H 2 SO 4 electrolyte, producing an energy density of 9.3483 Wh kg−1 with a coulombic efficiency of 89.01 %. The results showed that oxygen-doped hierarchical porous carbon nanofibers produced from Alpinia galangal stem biomass and designed to be solid-free of binders are highly promising as high-quality electrode materials that can improve sustainable supercapacitor performance. [ABSTRACT FROM AUTHOR]
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- 2024
- Full Text
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23. Freestanding electrodes based on nitrogen-doped carbon nanofibers and zeolitic imidazolate framework-derived ZnO for flexible supercapacitors.
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Gao, Hao, Joshi, Bhavana, Samuel, Edmund, Khadka, Ashwin, Wung Kim, Si, Aldalbahi, Ali, El-Newehy, Mohamed, and Yoon, Sam S.
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CARBON nanofibers , *DOPING agents (Chemistry) , *ZINC oxide , *SUPERCAPACITORS , *ELECTRICAL energy , *ENERGY density - Abstract
[Display omitted] • PVP/ZIF-7/PAN nanofibers carbonized at 900 °C yielded flexible ZnO P /C. • A capacitance of 382.5 mF cm−2 was obtained at a current density of 1 mA cm−2. • ZnO P /C demonstrated a capacitance retention of ∼ 101 % over 10,000 cycles. • ZnO P /C delivered an energy density of 49 μWh cm−2 at a power density of 2 mW cm−2. This study investigates the carbonization of electrospun fibers derived from zeolitic imidazolate framework (ZIF)-7/polyacrylonitrile solutions containing urea or polyvinylpyrrolidone (PVP). The carbonization yields highly flexible composites comprising nitrogen-doped carbon nanofibers and ZnO. Notably, using PVP as a nitrogen source generates a composite exhibiting excellent electrochemical performance. Specifically, it delivers a high capacitance of 382.5 mF cm−2 at a current density of 1 mA cm−2. Furthermore, this composite demonstrates capacitance retentions of approximately 101 % and 80 % after 10,000 cycles and a 90° bending test, respectively. The charge-storage capability of the PVP-based ZnO P /C composite surpasses that obtained without PVP by 1.4 times. Additionally, a composite fiber mat of ZnO P /C obtained via one-step electrospinning exhibits exceptional electrical conductivity and an energy density of 49 μWh cm−2 at a power density of 2 mW cm−2. These findings highlight the potential of this material as an electrode for supercapacitors. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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24. Nanohole-created carbon nanofibers for graphene-based supercapacitors.
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Seol, Jaechang, Lim, Gil Hwan, Lee, Jimin, David, Selvaraj, and Kahng, Yung Ho
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CARBON nanofibers , *ELECTRODE performance , *SUPERCAPACITORS , *STANDARD hydrogen electrode , *ELECTROCHEMICAL analysis , *POTASSIUM hydroxide - Abstract
Manifold graphene-based supercapacitor (GSC) electrodes have been extensively studied recently. Numerous studies have aimed to improve the performance of GSCs by amending the surface using various treatments or by incorporating diverse materials. However, few studies have been conducted on the treatments for the back electrodes which support the active material in the GSCs. Herein, the activation of carbon nanofibers (CNFs) back electrodes was achieved through simple thermal activation using potassium hydroxide (KOH) as an activating agent to enhance the electrochemical performance of GSC electrodes. The optimized sample exhibited a specific capacitance (C sp) of 210 F/g at 100 mV/s without adversely affecting the self-discharge behavior of the electrodes. Compared to the reference electrodes formed on the nonactivated CNFs, the C sp at high rate operations of the GSC electrodes was markedly increased by 1.6 times. Morphological, elemental, and electrochemical analyses were conducted to study the effects of KOH activation on the performance enhancement of GSC electrodes. Our results present a novel research approach for enhancing GSC performance. [Display omitted] • KOH thermal activation for carbon nanofiber back electrodes was conducted. • An optimum temperature for the activation was found to be 800 °C. • The activation increased the specific capacitance for graphene supercapacitors. • The self-discharging did not worsen, indicating the practicality of this discovery. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
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25. Self-supported heterojunction nanofibrous membranes for high-performance flexible asymmetric capacitors.
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Zhang, Xunlong, Yan, Guilong, Li, Zhenyu, Chen, Jingyu, Wang, Li, Li, Han, and Wu, Yuanpeng
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SUPERCAPACITORS , *SUPERCAPACITOR electrodes , *CAPACITORS , *ENERGY density , *ENERGY storage , *CARBON nanofibers , *HETEROJUNCTIONS - Abstract
[Display omitted] • The NB-PCNF and MnO 2 /Co 3 O 4 /NB-PCNF were successfully fabricated via needleless electrospinning. • The co-doping of multiple non-metallic atoms enhances the electrochemical capability of carbon nanofibers. • The heterogeneous structure in MnO 2 /Co 3 O 4 /NB-PCNF can effectively improve the electrical conductivity. • A flexible asymmetric solid-state supercapacitor (FASS-SC) exhibits excellent electrochemical performance. Rational design of an electrode material with high flexibility and electrochemical performance is the key to wearable energy storage devices. Herein, a facile and productive needleless electrospinning method was introduced to prepare self-supported and flexible nanofibrous electrode materials for asymmetric capacitor. The MnO 2 nanoclusters and ZIF67-derived Co 3 O 4 nano-sheets were sequentially deposited on the surface of N, B-doped carbon nanofibers (hetero-junction MnO 2 /Co 3 O 4 /NB-PCNF). Attributing to the constructed multi-pathway for redox reactions on electrode, the specific capacitance of NB-PCNF and MnO 2 /Co 3 O 4 /NB-PCNF can reach up to 204.2F/g and 141.43F/g at a small current density of 0.1 A/g, respectively. In long-term cycling tests, the electrode materials exhibited excellent cycling stability and good rate capability. The electrodes were assembled with Potassium-ion hydrogel electrolyte to form a flexible asymmetric solid-state supercapacitor (FASS-SC). FASS-SC can reach a voltage window of 1.6 V. It provided 28.2 W h/kg at an energy density of 600 W/kg and a specific capacitance retention of 94.18 % after 10,000 cycles. The FASS-SC offers new research ideas for future flexible devices and wearable technologies. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
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26. Nanocellulose/carbon nanotube/manganese dioxide composite electrodes with high mass loadings for flexible supercapacitors.
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Zhang, Sufeng, Li, Lei, Liu, Yali, and Li, Qinglu
- Subjects
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MANGANESE dioxide , *CARBON nanotubes , *ENERGY density , *ENERGY storage , *SUPERCAPACITORS , *POWER density , *SUPERCAPACITOR electrodes , *CARBON nanofibers - Abstract
The increasing commercialization of flexible electronic products has sparked a rising interest in flexible wearable energy storage devices. Supercapacitors are positioned as one of the systems with the most potential due to their distinctive advantages: high power density, rapid charge and discharge rates, and long cycle life. However, electrode materials face challenges in providing excellent mechanical strength while ensuring sufficient energy density. This study presents a method for constructing a flexible composite electrode material with high capacitance and mechanical performance by electrochemically depositing high-quality manganese dioxide (MnO 2) onto the surface of a nanocellulose (CNF) and carbon nanotube (CNT) conductive film. In this electrode material, the CNF/CNT composite film serves as a flexible conductive substrate, offering excellent mechanical properties (modulus of 3.3 GPa), conductivity (55 S/cm), and numerous active sites. Furthermore, at the interface between MnO 2 and the CNF/CNT substrate, C-O-Mn bonds are formed, promoting a tight connection between the composite materials. The assembled symmetric flexible supercapacitor (FSC) demonstrates impressive performance, with an areal specific capacitance of 934 mF/cm2, an energy density of 43.10 Wh/kg, a power density of 166.67 W/kg and a long cycle life (85 % Capacitance retention after 10,000 cycles), suggesting that they hold promise for FSC applications. [Display omitted] [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
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27. Biomass-derived multifunctional nanoscale carbon fibers toward fire warning sensors, supercapacitors and moist-electric generators.
- Author
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Huang, Chen, Su, Yingying, Gong, Hui, Jiang, Yuewei, Chen, Bo, Xie, Zhanghong, Zhou, Jinghui, and Li, Yao
- Subjects
- *
CARBON fibers , *CARBON nanofibers , *DEIONIZATION of water , *FIRE detectors , *ENERGY density , *SUPERCAPACITORS , *DETECTORS , *ENERGY function , *ENERGY storage - Abstract
Nowadays, great effort has been devoted to designing biomass-derived nanoscale carbon fibers with controllable fibrous morphology, high conductivity, big specific surface area and multifunctional characteristics. Herein, a green and renewable strategy is performed to prepare the biomass-based nanoscale carbon fibers for fire warning sensor, supercapacitor and moist-electric generator. This preparation strategy thoroughly gets over the dependence of petroleum-based polymeride, and effectually improves the energy storage capacity, sensing sensitivity, humidity power generation efficiency of the obtaining biomass-based carbon nanofibers. Without the introduction of any active components or pseudocapacitive materials, the specific capacitance and energy density for biomass-based nanoscale carbon fibers achieve 143.58 F/g and 19.9 Wh/kg, severally. The biomass-based fire sensor displays excellent fire resistance, stability, and flame sensitivity with a response time of 2 s. Furthermore, the biomass-based moist-electric generator shows high power generation efficiency. The output voltage and current of five series connected and parallel-connected biomass-based moist-electric generators reaches 4.30 V and 43 μA, respectively. Notably, as the number of biomass-based moist-electric generators in series or parallel increases, the overall output voltage and current of the device system have a linear relationship. This work proposes a self-powered fire prediction system based on nanoscale carbon fibers that integrates sensing, power generation, and energy storage functions. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
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