1. Experimental investigation on hydrophilic functionalized CaCl2@UIO-66 composites for water adsorption and heat storage.
- Author
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Lou, Bo, Zhou, Daheng, Ding, Jiaxin, and Huang, Qiongyi
- Subjects
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ADSORPTION (Chemistry) , *METAL-organic frameworks , *ENERGY storage , *POROUS materials , *HEAT capacity , *HEAT storage - Abstract
Porous materials with high adsorption capacity can enhance the efficiency of water-based adsorption heat transformation systems. The composites salt in porous matrix (CSPM) are considered to be very promising materials. In this paper, the UIO-66-NH 2 and UIO-66-NO 2 metal-organic framework were used as the porous matrix to synthesize composites with CaCl 2 as the hygroscopic salt. The water adsorption and desorption performance of the composite materials were studied, and the cycle stability was investigated in a continuous adsorption-desorption experiment. As a result, the hydrophilic UIO-66 based composites exhibited higher water adsorption and heat storage capacity. CaCl 2 @UIO-66-NH 2 achieved a water adsorption capacity of 0.84 g/g at 60% relative humidity (RH) and an energy storage density of 1858 J/g. In addition, the hydrophilic UIO-66 based composites exhibited excellent cycle stability, with the quality decreasing by less than 5% after ten adsorption-desorption cycles. By introducing hydrophilic functional groups, the adsorption capacity, adsorption rate, and thermal storage capacity of CSPMs were improved. [Display omitted] • The hydrophilic functionalized UIO-66 based composites exhibit enhanced water absorption properties. • The hydrophilic functionalized samples have higher energy storage densitywith CaCl 2 @UIO-66-NH 2 reaching 1858J/g. • All samples exhibited good cycle stability and the water adsorption quantity decreased by less than 5% after 10 cycles. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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