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Continuous theta burst stimulation and intermittent theta burst stimulation are clinically popular models of repetitive transcranial magnetic stimulation. However, they are limited by high variability between individuals in cortical excitability changes following stimulation. Although electroencephalography oscillations have been reported to modulate the cortical response to transcranial magnetic stimulation, their association remains unclear. This study aims to explore whether machine learning models based on EEG oscillation features can predict the cortical response to transcranial magnetic stimulation. Twenty-three young, healthy adults attended two randomly assigned sessions for continuous and intermittent theta burst stimulation. In each session, ten minutes of resting-state electroencephalography were recorded before delivering brain stimulation. Participants were classified as responders or non-responders based on changes in resting motor thresholds. Support vector machines and multi-layer perceptrons were used to establish predictive models of individual responses to transcranial magnetic stimulation. Among the evaluated algorithms, support vector machines achieved the best performance in discriminating responders from non-responders for intermittent theta burst stimulation (accuracy: 91.30%) and continuous theta burst stimulation (accuracy: 95.66%). The global clustering coefficient and global characteristic path length in the beta band had the greatest impact on model output. These findings suggest that EEG features can serve as markers of cortical response to transcranial magnetic stimulation. They offer insights into the association between neural oscillations and variability in individuals' responses to transcranial magnetic stimulation, aiding in the optimization of individualized protocols. ● Machine learning based on EEG was used to identify individual response to TMS. ● Combination of different EEG features contributed to the high predictive accuracy. ● These findings help understand TMS variability and optimize TMS protocols. [ABSTRACT FROM AUTHOR]

High arsenic-containing waste acid from the heavy nonferrous metallurgical sector (Cu, Pb, Zn, Ni, Sn, etc.), one of the most dangerous arsenic hazardous wastes with extremely high arsenic concentrations, has presented enormous challenges to the environment and caused severe environmental pollution over the past few decades due to the lack of affordable and environmentally friendly disposal technologies. Here, we report a green process for the self-enhanced and efficient removal of arsenic from waste acid using magnetite as an in situ iron donator. Firstly, the room-temperature predissolution of magnetite in waste acid provides initial iron ions as a starting precipitator of arsenic, simultaneously providing a suitable pH range and an active surface that are ready for the nucleation and growth of scorodite. Afterwards, arsenic is precipitated in form the of scorodite, which is driven by a mutually improved cycle composed of arsenic precipitation and magnetite dissolution on the surface of magnetite particles. This cycle creates a low supersaturation of iron and constant pH in the waste acid, ensuring the continuous precipitation of arsenic as well-crystallized and environmentally stable scorodite by using magnetite as an in situ iron donator via the reaction of 2Fe 3 O 4 + 6H 3 AsO 4 + H 2 O 2 = 6FeAsO 4 + 10H 2 O. Under optimal conditions, including a 6-h room-temperature predissolution, a 12-h atmospheric reaction at 90 °C and a pH of 2.0 with a magnetite dosage at the Fe 3 O 4 /As molar ratio (the molar ratio of Fe 3 O 4 in magnetite to As in waste acid) of 1.33, 99.90% of arsenic was successively removed from waste acid with an initial arsenic concentration of 10300 mg/L. In combination with the good adaptability of this process, the performed case study and prospective process show the successful removal of arsenic from waste acid as well as great potential for large-scale applications. Image 102 • Arsenic removal from waste acid using magnetite as in situ iron source. • Mutually-improved relationship of arsenic precipitation and magnetite dissolution. • Prospective process for the effective treatment of arsenic-containing waste acid. [ABSTRACT FROM AUTHOR]

• The FeMnO x /S(IV) system has faster removal speed and higher adsorption capacity for As(III) compared to FeMnO x alone. • The As(III) (1079 µg/L) could be decreased to less than 10 µg/L within 10 min. • The SO 5 •− radicals generated by S(IV) acting as the driving force for the redox cycle between As(III) and Mn(II/III/IV). • The possible mechanism of As(III) oxidation and removal for the FeMnO x /S(IV) system was proposed. • The FeMnO x nanocellulose aerogel broadened the scope of FeMnO x /S(IV) system in engineering applications. Manganese (Mn)-containing composite metal adsorbents are very effective at removing arsenite (As(III)) from contaminated water, however, the low removal speed and oxidation efficiency have limited their further application. In this study, a nonhomogeneous catalytic oxidation–adsorption system was constructed by coupling iron–manganese composite oxide (FeMnO x) with sulfite (S(IV)) to enhance the recovery of oxidative capacity and accelerate the removal of As(III). Experimental results showed that the FeMnO x /S(IV) system decreased the As(III) concentration from 1079 to <10 µg/L within 10 min and almost completely oxidized As(III) to As(V). In contrast, FeMnO x alone removed only 82.4% of As(III) within 30 min, and 60.0% of the adsorbed As(III) was not oxidized. Meanwhile, the adsorption capacity of FeMnO x /S(IV) system for As(III) was considerably higher than that of the only-FeMnO x system (76.5 > 46.3 mg/g). The efficient and fast As(III) removal was attributed to the SO 5 •− radical generated by S(IV) acting as the driving force for the redox cycle between As(III) and Mn(II/III/IV). Several environmental factors (e.g., solution pH and inorganic anions) and the reusability and practicality of FeMnO x were systematically investigated, and the results further confirmed the superiority of the FeMnO x /S(IV) system in As(III) removal. In particular, the proposed FeMnO x nanocellulose aerogel effectively purified arsenic-contaminated groundwater using a fixed-bed column. Thus, FeMnO x –S(IV) coupling is very promising for the purification of arsenic-contaminated water bodies. [Display omitted] [ABSTRACT FROM AUTHOR]

Removal of arsenic from aqueous solution in the form of scorodite is one of the promising processes for the disposal of arsenic-containing wastewater. While it suffers from the strict reaction conditions including high Fe/As molar ratio, narrow pH range, and low Fe/As supersaturation when the liquid iron sources of Fe2+/Fe3+ are used as the iron sources. We proposed to use limonite as an in situ solid iron source to promote scorodite crystallization via heterogeneous nucleation for the effective removal of arsenic from high-arsenic smelting wastewater. Under the condition of 90 °C, limonite dosage at an Fe/As molar ratio of 4 and pH of 1.5, 99.6% of arsenic in the smelting wastewater (As 10300 mg/L and sulphuric acid 72500 mg/L) was precipitated in the form of well-crystallized and environmentally stable scorodite with a particle size around 4.6 μm. Limonite acts as an in situ iron donator and seeds, allowing a low iron supersaturation in the solution during the arsenic precipitation and transformation into scorodite. Moreover, the residual arsenic concentration in the filtrate obtained from the abovementioned scorodite synthesis could be further lowered to 0.1 μg/L using fresh limonite in virtue of its high arsenic adsorbability. The proposed process shows a great potential for the arsenic removal from smelting wastewater, which will advance the large-scale disposal of arsenic-bearing wastewater and provide an important insight into the application of solid iron source for scorodite synthesis and arsenic fixation. Image 1 • Limonite acts neutralizer, seeds and iron donator for arsenic precipitation. • Scorodite produced from limonite in wastewater via heterogeneous nucleation. • High-efficiency arsenic removal from arsenic-bearing wastewater using limonite. [ABSTRACT FROM AUTHOR]

Heavy metals in water are critical global environmental problems. In particular, the anionic heavy metal chromium (Cr) has carcinogenic and genotoxic risks on human health. To this end, an ultralight and flexible nanofibrillated cellulose (NFC)/chitosan (CS) aerogel was developed only by freeze-drying combined with physical thermal cross-linking for efficient one step co-removal of Cr(VI) and Cr(III). The maximum adsorption capacity of Cr(VI) and total Cr calculated according to the Langmuir model was 197.33 and 134.12 mg/g, respectively. Even in the presence of competing soluble organics, anions and oil contaminants, the resulting NFC/CS-5 aerogels showed excellent selectivity. The aerogel exhibited outstanding mechanical integrity, remaining intact after 17 compressions in air and underwater. Meanwhile, after 5 adsorption-desorption cycles, the aerogel was easy to regenerate and maintained a high regeneration efficiency of 80.25%. Importantly, self-assembled NFC/CS-5 aerogel filter connected with the peristaltic pump could purify 752 mL of industrial wastewater with Cr(VI) pre-concentration capacity of 49.71 mg/g. XPS and FT-IR verified that electrostatic interactions, reduction and complexation acted as the main driving forces for the adsorption process. Moreover, such aerogel possessed broad application prospects for alleviating heavy metal pollution in agriculture. [Display omitted] • An ultralight & flexible nanofibrillated cellulose/chitosan aerogel was synthesized. • The maximum adsorption capacities of Cr(VI) and total Cr were 197.33 and 134.12 mg/g. • Aerogels exhibited superior antifouling, selectivity and recyclability. • Self-assembled aerogel filter could purify 752 mL of industrial wastewater. • Adsorption coupled reduction and chelation mechanism was revealed by FTIR and XPS. [ABSTRACT FROM AUTHOR]

The over-reliance on tetracycline antibiotics (TC) in the animal husbandry and medical field has seriously affected the safety of the ecological environment. Therefore, how to effectively treat tetracycline wastewater has always been a long-term global challenge. Here, we developed a novel polyethyleneimine (PEI)/Zn-La layered double hydroxides (LDH)/cellulose acetate (CA) beads with cellular interconnected channels to strengthen the TC removal. The results of the exploration on its adsorption properties illustrated that the adsorption process exhibited a favorable correlation with the Langmuir model and the pseudo-second-order kinetic model, namely monolayer chemisorption. Among the many candidates, the maximum adsorption capacity of TC by 10 %PEI-0.8LDH/CA beads was 316.76 mg/g. Apart from that, the effects of pH, interfering species, actual water matrix and recycling on the adsorption of TC by PEI-LDH/CA beads were also analyzed to verify their superior removal capability. The potential for industrial-scale applications was expanded through fixed-bed column experiments. The proven adsorption mechanisms mainly included electrostatic interaction, complexation, hydrogen bonding, n-π EDA effect and cation-π interaction. The self-floating high-performance PEI-LDH/CA beads exploited in this work provided fundamental support for the practical application of antibiotic-based wastewater treatment. [Display omitted] [ABSTRACT FROM AUTHOR]

[Display omitted] • An integrated calculation framework for anthropogenic pollution discharges was developed. • Effects of migration on anthropogenic discharges during 1980–2019 were characterized. • Population migration has positively influenced pollutant reduction from 2010 onwards. • The hotspot pollutant in urban and rural areas shifted from C to N and P, respectively. • Demographic bonus is a key factor in migration-induced pollution reduction. Unprecedented urbanization-induced population migration in China severely affects the scale and geographic distribution of anthropogenic pollutant discharge. Understanding how pollutant discharge patterns respond to population migration can help guide future efforts to maintain water sustainability. Here, based on a new calculation framework with 18 dynamic parameters designed for anthropogenic discharges, we finely tracked and visualized the effects of population migration on the spatial and temporal changes in anthropogenic discharge from 1980 to 2019 in the Minjiang River basin. The results indicate that the increasing effect of population migration on anthropogenic discharges peaked in 2002 and started to contribute to pollutant reduction from 2010 onward. The direct impact of population migration only contributes to the shift of anthropogenic discharges from rural to urban areas, while the migration bonus is the key factor leading to the reduction in anthropogenic discharges. Population migration is highly beneficial for chemical oxygen demand (COD) reduction, which has contributed to a shift from COD to NH 4 + -N and total phosphorus (TP) as hotspot pollutants in the whole basin (NH 4 + -N in urban areas and TP in rural areas). Moreover, pollution reduction resulting from the demographic bonus phenomenon has remained limited only to urban areas. Since approximately 2010, the per capita amount and total amount of anthropogenic pollutant discharges in rural areas have exceeded those in urban areas; in particular, the per capita COD and TP discharges in rural areas reached four times those in urban areas. This suggests that future pollution control strategies should give more attention to rural areas and focus on the differentiation and targeting of urban and rural areas. [ABSTRACT FROM AUTHOR]

• Short intracortical facilitation predicted the ability of inhibitory control. • Short intracortical inhibition does not relate to the ability of inhibitory control. • The interaction between short intracortical inhibition and facilitation matters. • The mean approach for estimating stop signal reaction time is relatively unreliable. The ability of motor-inhibitory control is important in daily life. Inhibitory control deficits are commonly observed in psychiatric conditions with enhanced impulsivity. The physiological mechanisms underlying the inhibitory control deficits are not well elucidated. We systematically investigated the relationship between resting-state intracortical inhibition or facilitation and inhibitory control (indicated by stop signal reaction time, SSRT) to determine whether reduced intracortical inhibition or increased intracortical facilitation was related to the poorer inhibitory control. Thirty-three healthy subjects (age: 21.46 ± 1.40 years) participated in this study. We used paired-pulse transcranial magnetic stimulation to induce short intracortical inhibition, intracortical facilitation, long intracortical inhibition, and short intracortical facilitation at rest. SSRT was derived from stop signal task. We performed all measurements in two repeat sessions conducted two weeks apart. A negative correlation between short intracortical inhibition and SSRT was only observed in session 1; however, the correlation did not persist after controlling for short intracortical facilitation. Positive correlation between short intracortical facilitation and SSRT was observed in both sessions, indicating that individuals with greater resting-state short intracortical facilitation tend to have less efficient stopping performance. Our results help explain the inconsistency with respect to the relationship between short intracortical inhibition and SSRT in the existing literature. Short intracortical facilitation may be used as a potential physiological biomarker for motor-inhibitory control, which may have clinical implications for disorders associated with inhibitory control deficits. [ABSTRACT FROM AUTHOR]