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This paper takes 30 provinces in China as the research subjects and constructs a real options model to explore the impact of carbon emissions trading market, energy storage subsidies, and their synergy on the optimal investment decision of household PV-ESS projects. The results show that a single factor has a catalytic effect on project investment, and both together have a better effect. And, project investment benefits are better in areas with abundant light resources and higher than average electricity prices. In addition, a sensitivity analysis is conducted on the initial investment cost, CO 2 price, and energy storage subsidies. The results show that immediate investment in all provincial projects can be achieved when the initial investment cost is reduced by 50%, or the CO 2 price is increased by about 33 times, indicating that the current environment is insufficient to attract investors. The results provide a reference framework for investment in household PV-ESS projects. • Use real options methods to assess investment decisions for household PV-ESS projects. • Explore the role of carbon trading market and energy storage subsidies on investment. • Research the impact of different regional power grids on investment value. [ABSTRACT FROM AUTHOR]

This study introduces a new regional feed-in tariff (FIT) pricing mechanism for solar photovoltaic (PV) energy in China, informed by real option (RO) theory and incorporating the increasing significance of tradable green certificate (TGC) policy revenues. The mechanism aims to balance government and consumer burdens with investor benefits. By factoring in additional income from green certificate sales, the study calculates the internal rate of return (IRR) to fall between 8 and 16% and uses a Monte Carlo simulation to determine optimal FITs for 30 Chinese provinces. These optimal FITs are then compared with current FITs, which are categorized by three types of solar resource regions, revealing that many current FITs are set within an inappropriate range and require adjustment. Additionally, the study observes minor differences in provincial FITs within six regional power grids, suggesting that setting FIT guide prices at the regional grid level is more practical than by solar resource regions. A sensitivity analysis examines the impact of green certificate prices, carbon prices, and technological advancements on the FIT for solar PV, comparing scenarios in a realistic environment versus a more favorable one. The results indicate that in a better environment—with higher TGC and carbon prices and encouraged corporate innovation—the FIT for solar PV is closer to the cost of coal-fired electricity, thus promoting grid parity. The study advocates for adjustments to the FIT mechanism, higher TGC and carbon prices, and the encouragement of innovation to enhance the competitiveness of solar PV energy in China's energy market. [ABSTRACT FROM AUTHOR]

In this study, polydimethylsiloxane (PDMS) was applied for overall hydrophobic modification of alkali-activated slag (AAS) mortars aiming to reduce its high water sorptivity. The effects of the amount and viscosity of PDMS on the water absorption characteristics and mechanical properties of AAS mortars were investigated. Meanwhile, MIP, the surface contact angle of AAS mortars and SEM-EDS, Inverse gas chromatography (IGC), FT-IR, XRD of hardened AAS pastes were performed for analyzing the modification mechanisms. The results indicated that the water sorptivity of PDMS-modified AAS mortar decreased by 90 %, and the contact angle of the inner surface increased from 14° to 128° when the dosage of PDMS reached 8 % (by weight of binder). The main modification mechanisms of PDMS in AAS system can be summarized as: Firstly, the formation of hydrophobic coatings on the surface due to the cross-linking reaction between C-S-H gel and PDMS reduces the surface energy and the hydrophilicity of hardened AAS pastes, achieving chemical modification; Secondly, the hierarchical structures formed by micro papillary increases the surface roughness, thus enhancing the hydrophobic effect further through physical modification. Moreover, the coarsening of capillary pores also reduces the capillary force during water absorption process. Meanwhile, the addition of PMDS maintains comparable strength development of AAS mortars, which is beneficial for the practical application. • PDMS-modified AAS mortars converted from hydrophilic to hydrophobic porous materials. • A 90 % reduction of water sorptivity of mortars was achieved by addition of PDMS. • The hardened PDMS-modified AAS pastes possessed lotus-leaf-like microstructure formed by micro papillary. • The PDMS-modified mortar exhibited stable strength development. [ABSTRACT FROM AUTHOR]

This work aims to illustrate the impact of high concentrations of Cr(VI) (based on Na 2 CrO 4 ) on the hydration assembly and microstructural development of hydrated Portland cement, and the results also present the role of calcium sulfate on the immobilization of Cr(VI) in Portland cement. The results showed that the immobilization of Cr(VI) in hydrated Portland cement was attributed to the formation of CrO 4 -U phase, an analogue of SO 4 -U phase (3CaO·Al 2 O 3 ·CaSO 4 ·0.5Na 2 SO 4 ·15H 2 O). The growth of CrO 4 -U phase on the surface of clinker particles formed a diffusion barrier and hence increased the setting time. Increasing the calcium sulfate dosage impaired the Cr(VI) immobilization due to the competition between CrO 4 2− and SO 4 2− integrated into the U phase. The generalized acid neutralization capacity (GANC) test indicated that the Cr(VI) leaching behavior was a function of the leachate pH value. As the pH decreased to 11.8, the CrO 4 -U phase was converted quickly to CrO 4 -ettringite, which generated a slight increase in Cr(VI) concentration. The most leaching sector, approximately 89.3% of added Cr (1 wt% of cement), was found in the pH range 11.8–10.5 due to the dissolution of secondary CrO 4 -ettringite. It could also be shown that the C–S–H had little chemical binding for Cr(VI). [ABSTRACT FROM AUTHOR]

As a secondary energy, electricity is an important channel between original energy and energy consumers. Electricity price is a critical factor for the interests of all involvers in the electric power market. It also plays an important role for the sustainable development of energy and environment. Smart grid is a new conception proposed in recent years to improve the intelligent level and increase the efficiency of electric power system operation. Smart grid combines and integrates information technology, communication technology and intelligent control technology with tradition power system. To achieve the many objectives of smart grid, Demand response (DR), as an effective technique of demand side management (DSM), refers to the changes in electricity consumption behavior of users in response to the dynamic price or incentive rewards. Price based demand response (PBDR) is one of the two major DR programs. In this paper, we first introduce the pricing theories in economics, the pricing of electricity and the development of electricity pricing in China. Then, we present a detailed discussion on the PBDR strategies in the DSM of smart grid. Also, the research status of PBDR is reviewed. Finally, it gives a summary of the whole paper in the last Section. [ABSTRACT FROM AUTHOR]

Distributed photovoltaics (PV) play a key role in the energy transition. We construct an investment value and timing assessment model based on the real options method to improve scientific decision-making in distributed PV investing in an uncertain environment. The model is applied to analyze projects in the East China Power Grid region under multiple self-consumption ratio scenarios. The results show that investing in distributed PV projects is beneficial, but there are differences in the optimal investment timing under different self-consumption ratios. Investors can defer investment for as early as one year to obtain optimal investment value. • Propose the distributed PV investment decision model based on the real option method. • Consider the uncertainty of initial investment cost and the on-grid price. • Investigate the impact of distributed PV power generation self-consumption ratio. • Investigate the impact of carbon trading on investment value and investment timing. [ABSTRACT FROM AUTHOR]

With the increasing penetration of information and communication technologies (ICTs) in energy systems, traditional energy systems are being digitized. Advanced analysis of the energy production and consumption data and data-driven decision support can be combined to promote the formation and development of smart energy systems. Smart grids are a specific application of smart energy systems. Different electricity consumption patterns of residential users can be discovered and extracted by clustering analysis of the electricity consumption data collected by smart meters and other data acquisition terminals in a smart grid. This research explores daily electricity consumption patterns of low-voltage residential users in China. The service architecture of smart power use and the structure of electric energy data acquisition system of the State Grid Corporation of China (SGCC) are introduced and a process model for mining daily electricity consumption data is presented. The analysis is based on the fuzzy c-means (FCM) clustering method and a fuzzy cluster validity index (PBMF). A case study of Kunshan City, Jiangsu Province, China is presented, using the daily electricity consumption data of 1312 low-voltage users within a month. [ABSTRACT FROM AUTHOR]

This study investigated the immobilization potential of alkali-activated slag (AAS) pastes for Cr(VI) by examining compressive strength, toxicity characteristic leaching procedure (TCLP) and generalized acid neutralization capacity tests. Alkaline digestion, total acid digestion, XRD, FTIR and SEM-EDS were carried out to clarify the immobilization mechanism. The AAS pastes gave high compressive strengths, which contributed to the physical encapsulation of Cr. The addition of Cr(VI) induced an increase in compressive strength compared to Cr(VI)-free pastes. The leaching results showed that AAS pastes exhibited effective immobilization for Cr(VI) and that the leachability was strongly dependent on the NaOH dosage, water to slag ratio, initial Cr(VI) content, leachate pH and curing duration. The initial Cr(VI) content up to 1.5 wt% by weight of slag was well immobilized with the total-Cr leachability below the TCLP regulatory limit of 5 mg/L. The digestion results demonstrated that the reduction of chromium from hexavalent to trivalent played a significant role in the immobilization of Cr(VI) in AAS without any additional reductants. The XRD and SEM-EDS results suggested the formation of a clear CrO 4 -U phase as the primary retention phase for unreduced Cr(VI). Therefore, alkali-activated slag binder is effective in the immobilization of Cr(VI)-bearing wastes. [ABSTRACT FROM AUTHOR]

This study reports an experimental investigation designed to assess the influence of near-surface moisture contents on permeation properties of alkali-activated slag concrete (AASC). Five different drying periods (5, 10, 15, 20 and 25 days) and three AASC and normal concretes with compressive strength grades ranging from C30 to C60 were considered. Assessment of moisture distribution was achieved using 100 mm diameter cores with drilled cavities. Results indicate that air permeability of AASC is very sensitive to the moisture content and its spatial distribution, especially at relative humidity above 65%. To control the influence of moisture on permeation testing, the recommendation of this paper is that AASC specimens should be dried in controlled conditions at 40 °C for 10 days prior to testing. It was also concluded from this study that AASC tends to perform less well, in terms of air permeability and sorptivity, than normal concrete for a given strength grade. This conclusion reinforces the need to further examine AASC properties prior to its widespread practical use. [ABSTRACT FROM AUTHOR]

Due to new challenges from emergent markets, companies increasingly expect to be able to offer innovative products and improve the innovation ability. Thus it is necessary to use a comprehensive evaluation method to evaluate the innovation capability for companies. Firstly, the evaluation indicators system is developed in terms of process capability, organization capability and knowledge capability. Secondly, the evaluation method based on uncertain linguistic variables is proposed. Finally, the evaluation method and the indictors system are applied into a practical problem. [ABSTRACT FROM AUTHOR]

Abstract: The technology development of concrete and demand for high strength construction materials give momentum to the development of Ultra-High Performance Concrete (UHPC). Current UHPC preparation methods require costly materials and relatively sophisticated technology. To overcome these weaknesses, this paper focused on the preparation of UHPC with common technology and ordinary raw materials. Influence of binder content, water/binder ratio, ground granulated blastfurnace slag (GGBS) content, and limestone powder (LP) replacement on fluidity and compressive strength of concrete were researched, respectively. The test results show that the addition of superplasticizer and fine mineral additives enabled the UHPC to be produced at an extremely low water/binder ratio of 0.14–0.18, achieving excellent workability with a maximum slump of 268mm and compressive strengths of 175.8MPa at 90d and 182.9MPa at 365d. [Copyright &y& Elsevier]

• Ca(OH) 2 reduced the efflorescence extent of alkali-activated slag(AAS) mortar. • The mitigation mechanism of Ca(OH) 2 on the efflorescence of AAS mortar was analyzed. • Ca(OH) 2 decreased the permeability and ion leaching capacity of AAS. • The mechanical properties of AAS mortar were enhanced by addition of Ca(OH) 2. Due to the high alkali concentration, weak binding of Na+ and relatively open microstructure, the efflorescence of alkali-activated slag (AAS) cement is a critical barrier limiting its widespread application. To reduce the efflorescence, Ca(OH) 2 was added as a Ca-rich precursor into the binder with the dosage of 3, 6 and 9 wt% by slag. The efflorescence of AAS mortars was identified by visual inspection and mass weighing of efflorescence products formed on the surfaces of the mortar. Capillary porosity, water absorption rate, Na+ leaching test, XRD and TG analysis were also carried out to explain the change of microstructure and hydration products caused by the incorporation of Ca(OH) 2. The results revealed that the addition of Ca(OH) 2 significantly reduced the coverage areas and the amount of efflorescence products. However, visual inspection results were not consistent with that of mass weighing of efflorescence products, ion leaching, etc. If the impact of efflorescence on microstructure should be considered, visual inspection is not suitable. It can be concluded that the addition of Ca(OH) 2 can mitigate the efflorescence by following reasons: firstly, the capillary porosity decreased from 16.86% to 15.22% and the water absorption rate decreased from 0.0366 mm/s1/2 to 0.0179 mm/s1/2 by adding 9% Ca(OH) 2 , which means that the migration pathway of the Na+ and water within the mortar was decreased. Secondly, the leaching results indicated that fewer Na+ leached from the Ca(OH) 2 -added samples, either from powder leaching or block leaching, which means that the addition of Ca(OH) 2 may enhance the binding of Na+ by hydration products through increasing the C-A-S-H gel content. [ABSTRACT FROM AUTHOR]

[Display omitted] • The cohesion interactions mainly determine plastic viscosity of AAS pastes. • The greater attractions between particles is the reason for its higher viscosity. • The friction interactions mainly determine the yield stress of AAS pastes. The workability and pumping performance of alkali-activated slag (AAS) concrete are affected by its rheological properties, which are related to the interactions between slag particles in the pastes. The rheological properties of AAS paste with different equivalent sodium oxide (Na 2 O eq) dosage activated by sodium hydroxide (NaOH) and sodium silicate (waterglass) with different SiO 2 /Na 2 O molar ratios were investigated in this study. The rheological mechanism was studied from the cohesion and friction interactions by calculations from parameters such as the Zeta potential of particles in the pastes, surface energy, hydrogen bond, and friction coefficient of the alkaline activators. The results indicated that the yield stress of AAS pastes was lower than that of the paste made with slag and water, whereas the plastic viscosity was higher. The yield stress of AAS pastes was mainly determined by the friction interactions between particles. The plastic viscosity was mainly affected by attractive interactions, including van de Waals interactions and Lewis acid-base interactions. The electrostatic repulsion interactions were felt at a very short distance because the AAS pastes were systems with the high ionic strength, which means that the electric double layer were severely compressed, therefore, the attractive interactions were predominant. Taken together, these results suggest that the improvement of plastic viscosity of AAS pastes should be achieved by changing the attractive interactions. [ABSTRACT FROM AUTHOR]

• Effect of Cr(VI) on the hydration of calcium aluminate cement was explored. • Conversion of metastable CAH 10 and C 2 AH 8 to stable C 3 AH 6 and AH 3 was discussed. • Leaching of Cr(VI) is sensitive to the leachate pH. • CrO 4 -U phase and CrO 4 -C 3 AH 6 phase were responsible for Cr(VI) binding. This study investigated the potential of calcium aluminate cement (CAC) to solidify/stabilize Cr(VI) (Na 2 CrO 4). The hydration and microstructure development of CAC pastes in the presence of Na 2 CrO 4 were examined by means of isothermal calorimetry, XRD, TG/DTG and SEM-EDS. The leaching properties of Cr(VI) were evaluated by TCLP and GANC methods. The results demonstrated that addition Na 2 CrO 4 significantly retarded the early-age hydration of CAC depending on the dosage, while caused an acceleration of long-term hydration. The formations of CAH 10 and C 2 AH 8 were inhibited, instead AH 3 , CrO 4 -C 3 AH 6 and CrO 4 -U phase were found as the main hydrates. These changes of hydrate assemblages led to a strong decrease in compressive strength. Complying with the TCLP regulatory limit of 5 mg/L, up to 1.0% of Cr(VI) could be effectively immobilized in the CAC paste. Two binding phases, CrO 4 -C 3 AH 6 and CrO 4 -U phase, were responsible for controlling Cr(VI) leaching in the CAC pastes. [ABSTRACT FROM AUTHOR]

Graphical abstract Prototype of end-effector for citrus harvesting robot. Highlights • Introduction of new descriptions for the stalk orientations of citruses. • Design of end-effector with bite mode by simulating mechanism of snake head. • A function evaluating harvesting postures. • Harvesting of citruses with random stalk orientations. Abstract It is difficult for harvesting robot to harvest the citrus fruits with random stalk orientations. To harvest citrus fruits with random stalk orientations by harvesting robot, some new descriptions for the stalk orientations of citrus fruits are introduced and an end-effector with the bite mode for citrus harvesting robot is designed by simulating the head mechanism of snake. According to the end-effector, an optimization method of harvesting postures is suggested and a function to evaluate the harvesting postures is obtained. Combined with the structural parameters of end-effector and the growth orientations of factual citrus fruits, the evaluation function is applied in the harvesting of citrus fruits grown in the natural environment and the optimal harvesting posture of 46° is obtained. Based on the model of end-effector, the end-effector prototype with the bite mode is assembled and then applied in a harvesting robot. The results of cutting citrus stalks and harvesting citrus experiments in laboratory indicate that the average success rate of cutting is up to about 98% in the deflection angle range of [−50°,50°] and the harvesting rate in the optimal posture is about 89%. In addition, the harvesting results in natural environments show that the harvesting rate in the optimal posture is up to 74%. The harvesting experiments in both laboratory and natural environments demonstrate that the harvesting rate in the optimal posture is higher than other harvesting posture. The results show the designed end-effector and the method of optimizing harvesting postures are acceptable and the results can contribute to the development of next-generation citrus harvesting robots. [ABSTRACT FROM AUTHOR]

Abstract The high water absorption rate of alkali-activated slag (AAS) cement, which causes concerns to designers and constructors as "long-term" durability, was addressed using an alternative admixture, calcium stearate (CaSt). The macro- and micro-performance of AAS cement with two levels of CaSt dosage (4 wt%, 8 wt% of slag) were characterised under the water to binder ratio (W/B) ranging from 0.35 to 0.45 and benchmarked against corresponding Portland cement (PC) samples by sorptivity along with compressive strength, porosity, electrical resistivity, pore connectivity, pore size distribution and pore geometries. The interpretation of results showed that CaSt played an instrumental role in pore structure features of AAS and the use of CaSt could significantly reduce its sorptivity, even lower than that of the corresponding PC samples. It is also found that the recommended usage of CaSt is 4% of slag, beyond which no significant variation in sorptivity can be detected. The performance improvement was caused by two main mechanisms, optimising the pore structure (more entrained pores, less pore connectivity factor and less microcracks) and introduce of the hydrophobic film on the pore surface. One limitation of using CaSt was noted as well. That is, the strength development of AAS can be affected and it can be avoided through modifying mix proportions according to practical requirements. Therefore, CaSt can be used as a chemical admixture for AAS to solve the concern on its high sorptivity behaviour. [ABSTRACT FROM AUTHOR]

• Passivity of mild steel embedded in MKPC-CSA blended paste were investigated. • CSA addition significantly influences the degree of passivity. • Passivity increases with increased CSA addition and 30% CSA addition leads to a much higher passivity. • 30 % CSA addition benefits the precipitation of phosphate ions and formation of Fe2+ oxide in passive film. This study did a pioneer work focused on the passivation of mild steel embedded in magnesium potassium phosphate cement (MKPC)-calcium sulphoaluminate cement (CSA) blended paste via electrochemical measurements and materials characterization techniques. Results showed that 30 % CSA addition in MKPC leads to a passivity of mild steel much higher than that in Portland cement (PC) paste. The passivity of mild steel increased with an increase in CSA content in MKPC paste due to an increase in pH and phosphate concentration in pore solution. The formation of iron phosphate and Fe2+ oxide in passive film of MKPC-30 %CSA contributes to its highest passivity. [ABSTRACT FROM AUTHOR]

In this study, the sulfate attack on mortars was accelerated using electrical pulse as an external electrical field. Meanwhile, the specimens with the same mix proportions were immersed in sulfate solution as comparison. The sulfate concentration and mechanical properties, including flexural and compressive strengths, were measured to evaluate the effects of sulfate attack. In addition, the transformation of microstructural nature and phase of the specimens were evaluated by scanning electron microscope and X-ray diffraction. The results showed that electrical pulse greatly accelerated the penetration of sulfate ions into the mortars and resulted in more ettringite and gypsum formed, leading to a greater depth of sulfate reaction. In electrical pulse test, the sulfate content in MgSO 4 solution was greater than that in Na 2 SO 4 solution, which was the opposite case in immersion test. Moreover, the electrical pulse resulted in significant mechanical strength losses in a much shorter period as compared with those in immersion test. These findings indicated that the electrical pulse accelerated sulfate attack could be a new acceleration test for evaluating the sulfate resistance of cement-based materials. [ABSTRACT FROM AUTHOR]

Ground granulated blast-furnace slag (GGBS) is widely used as supplementary cementitious material of interest for adjusting the performance of concrete. Unlike standard commercial products, characteristics of GGBS from different iron manufacturers vary significantly and assessment of its reactivity, especially at an early age, is not well-established despite numerous parameters specified in current standard systems. Three GGBSs with different setting features during the alkali-activated process were dissolved in either deionised (DI) water or NaOH solution in this study. To illustrate the fundamental processes of reaction kinetic, the dissolved ion concentrations, glassy structural changes, and chemically bound water were measured using ICP-OES, FTIR, and TG respectively. Meanwhile, thermodynamic calculations were carried out to estimate the precipitation of C–S–H gels, which is directly linked with setting behaviours. The results clearly show the differences in the dissolution of the three GGBSs, which could be used to indicate the activity of GGBS. The GGBS with higher activity (i.e. faster setting during alkali activation) tends to dissolve evenly in DI water, whilst those with lower activity show that the silicate groups with lower polymerisation dissolved faster. The chemically bound water determined by TG analysis and the effective saturation index (ESI) are promising parameters for reflecting the activity of GGBS during dissolution in the alkali media. Although this study demonstrated the dissolution rate of higher polymerised silicate groups in GGBS should be the root for the differences in its activity, more structural information on the glassy phase and the interactions of alkali with the surface of GGBS still require further understanding. It is speculated that the ratio of Al[IV]/Al[V] plays an important role in the activity of GGBS. This finding may shape a certain basic understanding of how GGBSs dissolve in neutral and high pH solutions and highlight a re-evaluation of assumptions in thermodynamic simulation under different conditions. [ABSTRACT FROM AUTHOR]

The addition of coarse aggregate in ultra-high performance concrete offers several benefits, including the reduction of self-shrinkage, cost reduction, and increased modulus of elasticity. However, it also affects the dispersion space of steel fibers, resulting in a combined effect that both enhances and limits their respective advantages. An image method was used to describe the dispersion of steel fibers and coarse aggregate in the specimens along their length, width and height directions, respectively. The impact of dispersion of steel fibers and coarse aggregate on bending performance was investigated by four-point bending tests using various surfaces as the bottom tensile zone. Furthermore, the damage occurrence mode and crack development process are discussed using micro-morphology and cross-sectional graphs. The results show that the combined effect of steel fibers and coarse aggregate is not conducive to dispersion in the length direction but prevents settling due to gravity during vibration. Differences in bending properties among various surfaces in the bottom tension zone was significant, but the synergy between steel fibers and coarse aggregate reduced these differences by 1.5–2.4 times. Steel fibers in ultra-high performance concrete containing coarse aggregate act as crack arrestors, resulting in ductile damage. Cracks develop partly through the coarse aggregate and partly along the interface transition zone, indicating that the addition of coarse aggregate does not compromise flexural strength. • Dispersion variability was observed in the length, width, and height directions, influenced by the combined effect. • The combined effect mitigated the settling of steel fibers in ultra-high performance concrete. • The coarse aggregate has a limited effect on the flexural strength but diminishes post-peak performance. • The dispersion of steel fibers is the primary factor influencing post-peak performance. • The combined effect reduced the variation in bending parameters for different surfaces acting as the bottom tension zone. [ABSTRACT FROM AUTHOR]

• Effect of Na 2 CrO 4 on the hydration kinetics of blast furnace slag were studied. • The Na 2 CrO 4 showed a strong alkaline activating on the blast furnace slag. • The compressive strength could be significantly improved by adding Na 2 CrO 4. • The main reaction products were C-(A)-S-H and CrO 4 -U phase. • A large number of alkalis was released during the reaction between slag and Na 2 CrO 4. Blast furnace slag (BFS) is a potential candidate for the immobilization of chromium-bearing wastes. This paper investigated the effect of soluble hexavalent chromium (Na 2 CrO 4) on the early hydration behavior of BFS by means of isothermal calorimetry, X-ray diffraction (XRD), thermogravimetry (TG), scanning electron microscopy (SEM) and pH measurement of pore solution. Meanwhile, the compressive strength of BFS pastes in the presence of different dosage of chromate was tested for the structural study. The primary aim was to verify the alkaline activation of Na 2 CrO 4 on the BFS. It was found that the BFS in water had scarcely hydrated in the first 7 days, whereas the addition of Na 2 CrO 4 greatly accelerated the hydration of BFS and promoted the hardening. Increasing the Na 2 CrO 4 dosage could significantly improve the compressive strength, which was sufficient to meet the requirement for immobilization of wastes. The hydration products of BFS in Na 2 CrO 4 solutions were mainly C-(A)-S-H and CrO 4 -U phase. The CrO 4 -U phase played a key role in Cr(VI) binding due to its layered structure. During the formation of CrO 4 -U phase, a large number of alkalis was released, which largely increased the pH of pore solution, thus greatly promoting the BFS hydration. The results indicated that the Na 2 CrO 4 had a strong alkaline activation on blast furnace slag. [ABSTRACT FROM AUTHOR]

In the course of an investigation on using calcium stearate (CaSt) to improve performance of the alkali-activated slag (AAS) cement, the objective of the present work is to discovery its role in the AAS system. Special interest is devoted to understand the influence of CaSt on the reaction process, reaction products and microstructural features of the AAS cement. To achieve this, isothermal calorimetry, impedance characteristics, infrared spectroscopy, X-ray diffraction, thermogravimetry, nitrogen sorption, mercury intrusion porosimetry and scanning electron microscopy were carried out. According to results obtained, the CaSt has three important effects on the AAS cement. Firstly, it inhibited slag reaction with the activator through decreasing activity of alkalis, whereas the amount of C-(A)-S-H gels in the system depended on the usage of CaSt, because the CaSt could have chemical reactions with the alkali-solution and form similar reaction products. Secondly, there is less sodium and more calcium in reaction products of the CaSt added mix, which improve their stability and uniformity. Finally, microstructure characteristics (e.g. pore size distribution, pore connectivity) are optimised and defects are reduced significantly, when CaSt is added in the AAS mix. [ABSTRACT FROM AUTHOR]

Alkali-activated slag (AAS) has attracted huge attention worldwide for its low CO 2 emission. However, the high water sorptivity of AAS is an obstacle before its practical application, while conventional methods can hardly solve this issue. In this study, the water sorptivity of AAS was decreased using a novel admixture, and the admixture shows a little effect on compressive strength at long ages. In order to clarify causes for its working mechanisms, the reaction process, reaction products and pore structure were investigated. The results suggest that sodium stearate (NaSt) plays an instrumental role in reaction process of AAS. Primarily, Na+ can provide a high alkaline environment, which is conducive for the dissolving of slag and increases compressive strength at the long term. Secondly, C 17 H 35 COO− can dramatically limit the movability of ions in the liquid phase due to its long molecular chain and thus, regulates precipitation of coagulation structure, improving the of ordering structure of C(N)-A-S-H and promoting formation of hydrotalcite-like phases (LDHs), from which the pore structure is upgraded by coarsening the pore diameters at the level of harmless and less harmful pores and decreases the pore connectivity. [ABSTRACT FROM AUTHOR]

• The rheological properties of AAS pastes have been improved by low surface free energy mineral admixtures. • The surface free energy properties of low surface free energy mineral admixtures have been determined by IGC method. • The interparticle forces were calculated to reveal the mechanism for rheological improvement. This study investigates the effect of low surface free energy mineral admixtures (CaF 2 -dominated fluorite (FL) and fluorine-containing lithium slag (LS)) on the rheological behavior of alkali-activated slag (AAS) pastes. The fluidity, rheological behavior, surface charge properties and surface free energy properties were tested. The interparticle forces based on extended Derjaguin-Landau-Verwey-Overbeek (EDLVO) theory were calculated to understand the mechanism for the rheological behavior improvement. The results revealed that both FL and LS could improve the fluidity and decrease the yield stress and plastic viscosity of AAS pastes. Furthermore, the attraction is manifested by the sum of electrostatic, van der Waals, and Lewis acid-base forces, and this value decreases with increasing LF or LS content, implying that the particle dispersion in AAS pastes is improved. Furthermore, observing flocculent structures captured by the metallographic microscope proves the better dispersion of AAS pastes after adding FL and LS. Moreover, incorporating LS or FL decreases the flexural and compressive strengths of AAS mortars. [ABSTRACT FROM AUTHOR]

Highlights • Design a new field test method to determine the permeability of structural concrete. • Establish the steady state flow net theory for air permeability test. • Assess the effect of specimens on flow features to calculate the calibration factor. • Justify the reliability and repeatability of the new air permeability test. Abstract An in situ air permeability test method that does not require assumptions for the often-difficult unidirectional flow has been developed to calculate the air permeability coefficient of the near surface concrete. The proposed method involves applying a constant pressure head to a surface mounted ring and measuring the steady state air flow rates. The analysis is based on modification of the flownet theory, which needs a calibration factor accounting for the influence of specimen and ring geometries. Effects of test area, width of seal, depth and width of test specimen were investigated using numerical simulation of the air flow. The repeatability of the proposed test method was assessed by the signal noise ratio (SNR) and discrimination ratio (DR). A new formula is offered and it only requires the steady state air flow rate to calculate the coefficient of air permeability, thus assisting engineers and researchers to quickly determine this property of structural concretes. [ABSTRACT FROM AUTHOR]

Abstract Saturating high performance concrete (HPC) on site for assessing water permeability is a challenge. This paper reports a testing programme established to assess the reliability and efficiency of two field saturation approaches, viz. vacuum saturation and ponding. The water permeability test results after applying the vacuum saturation and ponding were compared with that after incremental immersion. It is found that ponding was unable to remove the influence of moisture, while vacuum saturation can achieve this for wet concretes. Although the influence of moisture can be removed for different HPCs with high initial moisture contents by using the vacuum saturation method, it is not effective when the initial moisture content is low. The results obtained from numerical simulation model and the electrical resistance measurements after incremental immersion suggested that the water permeability of HPCs can be accurately determined if the surface region (140 mm width and 25 mm depth) is fully saturated. [ABSTRACT FROM AUTHOR]

• Adding 0.5 wt% calcium stearate can reduce 25% of the autogenous shrinkage of AAS; • The use of stearates can significantly reduce the internal capillary pressure of AAS; • The dynamic elastic modulus of AAS will reduce by 20% after adding stearates; • Elastic deformation only accounts for 10% of the total autogenous shrinkage of AAS. The autogenous shrinkage of the stearates-modified alkali-activated slag (AAS) mortar was investigated in this study. The experimental results suggested that the maximum reduction (25 %) of autogenous shrinkage of AAS can be achieved by adding 0.5 wt% calcium stearate, while potassium stearate and sodium stearate seem less effective in decreasing shrinkage. According to the results obtained, the mechanisms of shrinkage mitigation are mainly associated with the retardation of hydration, the coarsening of pore structure, and the increased contact angle. It is estimated that the capillary pressure of pores was reduced by 30 % ∼ 60 % when stearates were used. However, the elastic modulus of AAS was reduced by 20 % due to the bubble-stabilizing effect of stearates, especially at higher dosages, which would partially offset its decreasing effects on autogenous shrinkage. It is also found that the traditional physical model could be used to predict the autogenous shrinkage of plain and modified AAS samples, provided the effect of both elastic and creep parts is considered. [ABSTRACT FROM AUTHOR]

The study presents the shrinkage behaviour of Ca(OH) 2 -added alkali-activated slag (AAS) concrete. A series of tests were performed to determine the plastic shrinkage, autogenous shrinkage and drying shrinkage. In order to explain shrinkage mechanisms, the moisture loss was monitored; the pore structure was examined by nitrogen adsorption test; hydration process was assessed by isothermal calorimetry; hydration products and microstructure were characterised by XRD, SEM/EDS and TG/DTG. It was found that the use of Ca(OH) 2 increased the plastic shrinkage of AAS concrete, but reduced autogenous and drying shrinkage. This is because the addition of Ca(OH) 2 accelerated the hydration at very early stage, while non-noticeable impact could be identified after 120 h. The results from nitrogen adsorption test showed a decrease in mesopores by adding Ca(OH) 2 , which was responsible for the less drying and autogenous shrinkage. Meanwhile, the Ca/Si of C-S-H (I) increased from 0.89 to around 1.40 at 28 d when adding 5% and 10% Ca(OH) 2 . XRD patterns indicated C 2 ASH 8 and C 4 AH 13 were found in Ca(OH) 2 -added samples. These changes in hydration products also contribute less drying and autogenous shrinkage in Ca(OH) 2 -added samples. [ABSTRACT FROM AUTHOR]

This paper describes the results of a study investigating early age changes in pore structure of alkali-activated slag cement (AASC)-based paste. Capillary porosity, pore solution electrical conductivity and electrical resistivity of hardened paste samples were examined and the tortuosity determined using Archie's law. X-ray computed micro-tomography (X-ray μCT) and Scanning electron microscope (SEM) analysis were also carried out to explain conclusions based on electrical resistivity measurements. AASC pastes with 0.35 and 0.50 water-binder ratios (w/b) were tested at 3, 7, 14 and 28 days and benchmarked against Portland cement (PC) controls. Results indicated that for a given w/b, the electrical resistivity and capillary porosity of the AASC paste were lower than that of the PC control, whilst an opposite trend was observed for the pore solution conductivity, which is due to AASC paste's significantly higher ionic concentration. Further, capillary pores in AASC paste were found to be less tortuous than that in the PC control according to estimations using Archie's law and from the results of X-ray μCT and SEM analysis. In order to achieve comparable levels of tortuosity, therefore, AASC-based materials are likely to require longer periods of curing. The work confirms that the electrical resistivity measurement offers an effective way to investigate pore structure changes in AASC-based materials, despite threshold values differing significantly from PC controls due to intrinsic differences in pore solution composition and microstructure. [ABSTRACT FROM AUTHOR]

[Display omitted] • The role of CGS on the workability of cement paste with and without PCE was investigated. • The decrease of interparticle force leads to the improvement of fluidity when added CGS. • The aggregation of PCE in pore solution leads to its efficiency decrease in the cement pastes blended with CGS. Coal gasification slag (CGS) is the main by-product of coal gasification technology, and the utilization of CGS as mineral admixture is environmentally sound. In this paper, the effect and mechanisms of CGS on the workability (i.e., fluidity and rheological behaviors) of ordinary Portland cement (OPC) paste with and without polycarboxylate superplasticizer (PCE) were studied. The zeta potential and surface free energies of OPC and CGS were tested to calculate the electrostatic force and Van der Waals force variations due to the addition of CGS particles. The results revealed that CGS mainly decreases the van der Waals attraction force between binder particles, enhancing the fluidity and reducing cement pastes' yield stress and plastic viscosity. When blended with PCE, the dissolution of CGS mainly increased the ionic concentrations of Si(OH) x (4-x), which promoted the aggregation of PCE and decreased its adsorption, thus decreasing the fluidity and increasing the rheological parameters. [ABSTRACT FROM AUTHOR]

From a material viewpoint, modern concrete’s frequent propensity to plastic shrinkage cracking can be attributable to a combination of low water-binder ratio use and ever-changing properties of binding materials. To obtain a better understanding of this phenomenon, this paper explores the effects of cement fineness and alkali content on the plastic shrinkage cracking of concrete manufactured with two water-binder ratios. Results indicate that within the range 275–385 m 2 /kg, cement specific surface area is approximately directly and inversely proportional to hydration rate and evaporation rate respectively; a trend generally leading to higher plastic shrinkage and resulting areas of plastic cracking. Similar effects were observed for alkali contents which resulted in increased levels of plastic shrinkage. Furthermore, while decreasing crack tendency was noted as alkali content increased from 0.4 to 0.8% by mass of cement, further increases in alkali content caused significant decreases of compressive strength and slump; thereby lowering overall concrete performance. It is also found that plastic shrinkage cracking is closely related to the kinetics of plastic shrinkage. In summary, the experimental programme confirmed that cement with relatively low surface area (less than 340 m 2 /kg) and low alkali content (less than 0.8%) is preferred for modern concretes with minimal plastic cracking problems. [ABSTRACT FROM AUTHOR]

The damage process of plain and blended cement mortars subjected to sulfate attack under electrical field was investigated in this paper. The deterioration of mortars was investigated by measuring the loss of compressive strength. To identify the changes of microstructure and mineral phases after the test, scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction analysis were performed on the selected samples. The results indicated that compared with sulfate attack alone, the combination of sulfate attack and electrical field accelerated the damage process of mortars, which can be explained through two different mechanisms. On the one hand, Ca 2+ ions directionally moved and then leached out from mortars under the electrical field, leading to the dissolution of portlandite as well as the decomposition of C–S–H gel at the later stage. On the other hand, the electrical field accelerated the migration of sulfate ions and then they reacted with hydration products to form massive ettringite and gypsum, which resulted in the microcracks and strength loss of mortars. Moreover, the deterioration of the mortar blended with fly ash was still visible in spite of its better chemical resistance. The strength loss of limestone powder incorporated mortar increased in comparison with Portland cement mortar as a result of an increase in porosity. [ABSTRACT FROM AUTHOR]

Increasing attention is concentrated on the alkali-activated slag (AAS) as an alternative binder owing to its low environmental impact and high mechanical strength, whereas the carbonation resistance of AAS can be quite problematic. In this work, calcined Mg/Al layered double hydroxide (CLDH) was synthesized and used to improve the carbonation resistance of AAS mortars activated by NaOH. The effect of CLDH on the carbonation depth, mechanical strength, and microstructure before and after carbonation was investigated. The results show that CLDH reconstructed the lamellar structure and formed a hydrotalcite-like phase because of its memory effect. The hydrotalcite-like phase acted as a buffer system to absorb CO 2 intruding into the AAS mortars from the atmosphere, which retarded the decalcification of C-(A)-S-H. Meanwhile, the porosity decreased and the mortars become denser by the addition of CLDH, which prevented the diffusion of CO 2 into the mortars. The compressive strength of AAS mortars was enhanced by the carbonation regardless of CLDH addition. Calcite and vaterite were the main carbonation products. The addition of CLDH did not significantly change the polymorphs of carbonates but mitigated their production. • The effect of CLDHs on the carbonation depth of AAS mortars is studied. • The effects of CLDHs on the phase composition and microstructure of AAS are discussed. • The CO 3 2− is absorbed by the process of CLDHs recrystallized to LDHs. • The porosity of AAS mortars is significantly reduced by adding CLDHs. • Adding CLDHs effectively reduces the susceptibility of AAS mortars to carbonation. [ABSTRACT FROM AUTHOR]

Abstract: The structure of 7-(N,N′-diethylamino)-coumarin-3-carboxylic acid (DCCA) was verified by single crystal X-ray crystallography. The UV–vis absorption and fluorescence of DCCA were discussed. The compound exhibits strong blue emission under ultraviolet light excitation. The molecular structure of DCCA was optimized using density function theory (DFT) at B3LYP/6-31G level, showing that the optimized geometers parameters are in good agreement with experiment data. In addition, the HOMO and LUMO levels of DCCA were deduced. [Copyright &y& Elsevier]

Abstract: An aromatic bridged Schiff base ligand, N,n′-bis((4,4′-diethylamino)salicylidene)-1,2-phenylenediamine (H2L3), and its trinuclear Zinc(II) complex, , were synthesized and characterized by means of elemental analyses, FT-IR and UV–Vis absorption spectra, and single crystal X-ray crystallography. The X-ray crystal structure of the complex reveals that the zinc ion (Zn1 or Zn1A) is coordinated by two oxygen atoms in phenolate and two nitrogen atoms in imines of the ligand and one oxygen atom of the acetate, the zinc ion (Zn2) is coordinated by four oxygen atoms in phenolate of the ligands and two oxygen atoms of the acetates. Two acetates coordinate to three zinc ions through Zn–O–C–O–Zn bridges. The complex exhibits blue-green emission as the result of the fluorescence from the intraligand emission excited state. In addition, the ground-state geometries, the lowest energy transition and the UV–Vis spectrum of the ligand have been studied with density functional theory (DFT) and time-dependent density functional theory (TD-DFT) at B3LYP/6-31G(d) level, showing that the calculation outcomes are in good agreement with experimental data. [Copyright &y& Elsevier]

• Proper use of LS can increase fluidity and prolong setting time without losing strength. • LS can affect reaction products of AAS and its function depends on mix proportions. • Variations of pore structure of modified AAS cement relies on the dosage of LS. • Around 30% hydration degree of LS was achieved at 28 d for AAS with 40% LS. This study aims at discussing physical and chemical influence of limestone powder (LS) on the AAS system. General properties, including fluidity, setting time, drying shrinkage, and mechanical strength of AAS pastes/mortars, were examined. Pore structure change and phase assemblages of LS-AAS composites were studied. The results showed that the addition of 50 wt% LS increased the fluidity and setting time of AAS pastes, but reduced the total drying shrinkage of AAS mortars. Meanwhile, around 30% reduction in mechanical properties were found at the same replacement ratio. The pore structure was refined in the pastes with LS replacement<25 wt%, but was coarsened in the sample with 40 wt% LS. Limited new phase was formed in the sodium silicate activated slag samples, which was believed to depend on the modulus of the activator. Around 30% hydration degree of LS was achieved in 40 wt% LS-replaced AAS pastes hydrated for 7 ~ 28 d as determined by TG-DSC analysis. The main drawbacks of AAS, fluidity, setting time, and drying shrinkage, are improved by using high-volume LS, so use of high-volume LS in AAS system can be an option for the purpose of environmental protection. [ABSTRACT FROM AUTHOR]

Municipal solid waste incineration (MSWI) fly ash can cause serious early volume expansion when stabilized and solidified by cementitious materials. Many pretreatment processes have been reported, such as alkali solution, milling and chelating etc. However, these processes may lead to second pollution or higher costs. This study proposed an original pretreatment process of MSWI fly ash, and investigated its effect on the immobilization efficiency by alkali-activated slag (AAS) cement. The possible reasons for volume instability were assumed and analyzed by gas chromatography, scanning electron microscopy, X-ray diffraction, hydrostatic testing and leaching tests. It was found that the 0.377 wt% of metallic aluminum is the main expansive source of volume expansion in early stage (within 24 h). Due to the amphoteric characteristic of Al, it is possible to eliminate it using either acid or alkaline. Considering the fact that alkali-activated system and the fly ash were both alkaline, this study chose water immersion to pre-treat the fly ash, aiming to avoid the possible neutralization process of acid treatment and the entrained extra alkali component of alkali treatment, which may greatly affect many characteristics of alkali-activated slag. After pretreatment, the solidified specimens showed lower water demand (with a water to cement ratio of merely 0.27) and higher compressive strength due to the refined and smoothed particles. The volume expansive rate was greatly reduced, giving the better volumetric stability and encapsulation rate. Up to 90% MSWI fly ash-added solidified bodies feature a volume expansive rate of less than 0.09%. The alkali-activated slag pastes can effectively immobilize up to 70% treated fly ash with the leaching rate of solidified particles lower than the limits recommended by Chinese standard, Identification for extraction toxicity (CSEPA GB 5085.1, 2007). Therefore, the pretreatment process is easy to operate and is a promising way to increase the immobilization efficiency of alkali-activated slag cement. • Taking advantage of MSWI fly ash's own alkalinity to reduce volume expansion. • The pretreatment process won't produce waste water which brings second pollution. • Solidified bodies gained early and long-term volume stability after pretreatment. • The effective immobilization amount increased up to 70% after pretreatment. • AAS shows better potential than PC in immobilizing MSWI fly ash. [ABSTRACT FROM AUTHOR]

This study investigates the long-term (570 days) performance of alkali-activated slag (AAS) mortar exposed to combined wet-dry cycles and sodium sulphate solutions (i.e. 5 wt% and 10 wt%). Physical and mechanical characteristics of AAS mortars (i.e. visual appearance, compressive/flexural strength, mass change, capillary porosity, water sorptivity) as well as mineralogical and chemical parameters were determined using XRD, FTIR, DSC and BSE. Findings were compared to Portland cement (PC) and high sulphate resistant (HSR) samples. Results indicate that AAS mortars perform better than PC and HSR samples with minimal changes to compressive strength at 570 days (1.7% increasement). The main failure mode for AAS mortar was external spalling, which could be due to the crystallisation/dissolving pressure of sodium sulphate. Moreover, the results indicate key differences in the deterioration mechanism of AAS. Unreacted slag, exposed during sodium sulphate attack under wet-dry cycles, can continue to react in sodium sulphate to form silicon-rich gels. The formation of highly siliceous gel regions has beneficial impacts, such as the increase in flexural strength. While no calcium sulphate phases were detected via XRD and FTIR after 570 days of exposure, it is evident that the molecular changes in the microstructure reveal depolymerisation and enhanced formation of Si–O phases after long-term sodium sulphate exposure. These results are important to understand the long-term degradation mechanisms of AAS materials exposed to sodium sulphate under wet-dry cycles. [ABSTRACT FROM AUTHOR]

• Chloride transport coefficient of alkali-activated slag (AAS) cement could be predicted using electrical responses. • Temporal variation of strength, pore solution and transport properties of AAS is assessed. • AAS cement is more sensitive to mix proportions and additional care is needed to achieve high quality. Relatively few studies currently exist concerning temporal variation of the overall performance of alkali-activated slag (AAS) cement; a topic essential for quality control in practice. This study uses microstructural characteristics and electrical responses to reflect performance variation of AAS cement. To achieve this, four key performance parameters were assessed, pore formation factor, chloride transport coefficient, permeability coefficient and compressive strength. Classical theories used for PC-based materials were applied to estimate the performance of AAS paste. It is found that the formation factor of AAS can be assessed by combining bulk conductivity and pore solution conductivity and the permeation properties of AAS cement cannot be reliably assessed by the Katz-Thomoson (KT) model, while the Millington-Quirk (MQ) model works better. To assess the relationship between compressive strength and permeable porosity, the Balshin and Ryshkevitch equations performed best in terms of describing the relationship between these two parameters. Meanwhile, AAS cement is more sensitive to the mix proportions and additional care is needed to ensure its quality. It is the first time to use electrical response to predict the chloride transport coefficients of AAS cement, which would provide a powerful tool for its quality control and service life prediction. [ABSTRACT FROM AUTHOR]

Fourteen raw slag samples were collected from different steel companies from China, using which setting, mechanical and early-age microstructural behaviours of alkali-activated slag (AAS) cements were investigated. To assess the reaction process between ground granulated blast furnace slag (GGBS) and activator, isothermal calorimetry tests were conducted on three selected AAS pastes for 50 h, while TG, FTIR, and Raman tests were conducted to characterise the early microstructural changes. Main findings include that the setting behaviour of AAS pastes depends primarily on the fineness and chemical compositions of GGBS, and statistical analysis results indicate that three of the constituents namely, SiO 2 , MgO and K 2 O, have a strong impact compared to the rest constituents. It is also found that commonly-used parameters to describe characteristics of GGBS are not sufficient to predict setting behaviours of AAS paste made by different GGBSs. Furthermore, the 28-d compressive strength of AAS mortars cannot be considered as a reliable indicator to assess its reaction potential at early age, at least, has no relationship to its setting behaviour. The early age microstructural analysis indicates that one possible reason behind the huge different setting and early age compressive strengths of AAS pastes is the variation in the releasing speed of Ca ions. [ABSTRACT FROM AUTHOR]

• Steel-concrete interface in different directions and heights were characterized. • Defect area of steel-concrete interface increased with the higher height. • Interface defect size significantly affected the corrosion initiation time of steel bars. • Chloride permeability of concrete was non-uniform at different casting heights. Corrosion is the most important factor affecting the durability of reinforced concrete structures. Previous studies show that the formation and evolution of steel-concrete interface have a significant impact on the corrosion process of steel bars. The main purpose of this paper is to reveal the characteristics of steel-concrete interface and their effect on the corrosion of steel bars. Reinforced concrete specimens with vertically arranged and horizontally arranged steel bars of different heights (50 mm, 250 mm, 450 mm, 650 mm and 850 mm) were designed. The steel-concrete interface was examined by backscattered electron (BSE) imaging and nanoindentation technology. The specimens were exposed to wetting/drying cycles in chloride solution, while open circuit potential (OCP) of steel bars was conducted to monitor the corrosion state. After 80 cycles, one specimen was artificially broken to check the corrosion condition of steel bars by autopsy test. The results show that for the specimens with vertically arranged steel bars, there were few defects in the steel-concrete interface. For ones with horizontally arranged steel bars, however, many defects formed in the steel-concrete interface and the majority appeared at the bottom of steel bars. The area of these defects increased with the height of steel bars, from 0.27 mm2 to 10.83 mm2 for the steel bars at 50 mm and 850 mm respectively. In addition, the chloride penetration depth along the bottom part of the steel-concrete interface also increased significantly with the height growth. The OCP and autopsy results indicated that the corrosion of steel bars at the heights of 850 mm and 650 mm initiated after 30 cycles and 80 cycles respectively. Whereas no corrosion was found on other steel bars. Hence it was confirmed that the defects in steel-concrete interface accelerated the corrosion initiation of steel bars. [ABSTRACT FROM AUTHOR]

Abstract: Two novel triethylene-glycol dicoumarin-3-carboxylates were synthesized and characterized by element analysis, 1H NMR, FT-IR and UV–vis absorption spectra. The photoluminescent behaviors of triethylene-glycol dibenzo[5,6]coumarin-3-carboxylate doped in PMMA were discussed. These compounds exhibit strong blue emission under ultraviolet light excitation. Compared to coumarin-3-triethylene glycol diester, the absorption and emission spectra of benzo[5,6]coumarin-3-triethylene glycol diester was bathochromically shifted due to the larger conjugation of benzene moiety. These derivatives have potential possible to explore organic electroluminescent materials. [Copyright &y& Elsevier]

Abstract: A aromatic Schiff base ligand, N, N′-bis((4,4′-diethylamino)salicylidene)-1,2-phenylenediamine (H2L), and its trinuclear zinc(II) complex, Zn3L2(CH3COO)2, were synthesized. The X-ray crystal structure of the complex reveals that two zinc ions show the coordination number of five and the third one has the coordination number of six. The complex exhibits blue-green emission as the result of the fluorescence from the intraligand emission excited state. [Copyright &y& Elsevier]

Technical innovation promotes manufacturing industry to achieve energy conservation and emission reduction. As an area that accounts for more than 50% of China's economy, east region of China has taken the lead in developing and focusing on promoting industrial upgrading based on the innovation-driven development strategy. The potential solution of transforming China's manufacturing industry is to enhance the capability of independent innovation by increasing the investment in research and development. Research on the sustainable development capacity of east region manufacturing industry has been giving important guidance for upgrading the manufacturing industry all over China. However, few studies explore the research and development effect on the energy-saving potential of manufacturing at the regional level, and study the individual dynamic behavior to reflect industry heterogeneity. In this paper, the dynamic panel data research method is employed to explore the influence of the research and development on energy conservation while introducing macroeconomic variables. Additionally, block bootstrap-based scenario analysis is employed to predict the energy conservation of manufacturing in east region in 2020 and 2025 based on historical annual data from 1990 to 2016. Compared with the business-as-usual scenario, the advanced scenario could reduce the energy demand of 427.53Mtce and 1066.28 million tons of coal equivalent in 2020 and 2025, respectively. The results indicate that there is much room for improvement in terms of the energy efficiency for China's east region. • We investigate the effect of R&D on energy conservation potential in eastern China. • The modeling framework is designed based on dynamic panel data model. • A block bootstrap based scenario analysis is employed to this study. • We provide long-term perspective for energy conservation potential prediction. [ABSTRACT FROM AUTHOR]