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This paper examines the impact of the CO2 laser parameters on the tensile strength, which is one of the most important properties of paper packaging in the process of cutting paper material. The study was performed on a paper material sample Fbb Board/Ningbo Spark C1S Ivory Board by examination of the influence of four independent variables: paper material grammage, cutting speed, laser power, and resolution on the tensile strength by using definitive screening design. Optimum process conditions of four variables that maximize the tensile strength were predicted and validated accordingly. Results confirm that laser power, paper material grammage, and cutting speed are the main process parameters that mostly affect the tensile strength. Besides individual parameters, two statistically significant interactions were obtained: laser power and cutting speed, and cutting speed and laser resolution. Maximum tensile strength values (20.37 N/mm) were achieved using the laser power of 60.6%, cutting speed of 3.24%, resolution of 2500 Hz, and a paper material grammage of 326.85 g/m2. With laser power at middle values and at a lower speed, a maximum tensile strength value can be obtained. Increasing the laser power and cutting speed will produce a slight lowering of tensile strength. [ABSTRACT FROM AUTHOR]

Flexible calcium carbonate (FCC) was developed as a functional papermaking filler for high loaded paper, which was a fiber-like shaped calcium carbonate produced from the in situ carbonation process on the cellulose micro-or nanofibril surface. Chitin is the second most abundant renewable material after cellulose. In this study, a chitin microfibril was utilized as the fibril core for making the FCC. Cellulose fibrils for the preparation of FCC were obtained by fibrillation of the TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl radical) treated wood fibers. The chitin fibril was obtained from the β-chitin from the born of squid fibrillated in water by grinding. Both fibrils were mixed with calcium oxide and underwent a carbonation process by the addition of carbon dioxide, thus the calcium carbonate attached on the fibrils to make FCC. When used in papermaking, both the FCC from chitin and cellulose gave a much higher bulk and tensile strength simultaneously than the conventional papermaking filler of ground calcium carbonate, while maintaining the other essential properties of paper. The FCC from chitin caused an even higher bulk and higher tensile strength than those of the FCC from cellulose in paper materials. Furthermore, the simple preparation method of the chitin FCC in comparison with the cellulose FCC may enable a reduction in the use of wood fibers, process energy, and the production cost of paper materials. [ABSTRACT FROM AUTHOR]

The pulp and paper (P&P) sector is a dynamic manufacturing industry and plays an essential role in the Austrian economy. However, the sector, which consumes about 20 TWh of final energy, is responsible for 7% of Austria's industrial CO2 emissions. This study, intending to assess the potential for improving energy efficiency and reducing emissions in the Austrian context in the P&P sector, uses a bottom-up approach model. The model is applied to analyze the energy consumption (heat and electricity) and CO2 emissions in the main processes, related to the P&P production from virgin or recycled fibers. Afterward, technological options to reduce energy consumption and fossil CO2 emissions for P&P production are investigated, and various low-carbon technologies are applied to the model. For each of the selected technologies, the potential of emission reduction and energy savings up to 2050 is estimated. Finally, a series of low-carbon technology-based scenarios are developed and evaluated. These scenarios' content is based on the improvement potential associated with the various processes of different paper grades. The results reveal that the investigated technologies applied in the production process (chemical pulping and paper drying) have a minor impact on CO2 emission reduction (maximum 10% due to applying an impulse dryer). In contrast, steam supply electrification, by replacing fossil fuel boilers with direct heat supply (such as commercial electric boilers or heat pumps), enables reducing emissions by up to 75%. This means that the goal of 100% CO2 emission reduction by 2050 cannot be reached with one method alone. Consequently, a combination of technologies, particularly with the electrification of the steam supply, along with the use of carbon-free electricity generated by renewable energy, appears to be essential. [ABSTRACT FROM AUTHOR]

One of the ways in which sustainable development can be understood is through the efficient management and systematization of indicators. For this reason, the study of ecological footprints is important, given that this concept integrates the different types of environmental indicators and, from the results and their interpretation, explains the total environmental impact generated through the development of daily human activities. The objective of this research was to quantify the total ecological footprint of the National University of the Altiplano in 2023. An application-type quantitative approach was considered, and the study utilized a descriptive, non-experimental design in which source data were used. The data were obtained from a primary sample through applying a survey to teachers, students, and administrative staff. The questionnaire included questions about the operations and functioning of the university, allowing us to calculate and analyze the components of its ecological footprint. It was determined that, in 2023, the university entity generated 4721.20 t CO2 in carbon dioxide emissions due to the use and operation of infrastructure, buildings, mobility, electricity consumption, paper consumption, and water consumption. The findings indicate that the university's operations require approximately 915.67 hectares of forest annually to offset its carbon emissions and that it has an ecological footprint (in global hectares) of 1172.06 hag/year, suggesting important sustainability challenges. Finally, it was determined that the ecological footprint per capita at the National University of the Altiplano in 2023 was 0.04 ha/person/year and 0.06 hag/person/year, due to CO2 emissions, thus generating a greater ecological footprint of the university. These results underline the need to improve sustainable practices and review policies at the university level in order to better align with the objectives of sustainable development. [ABSTRACT FROM AUTHOR]

This article presents an algorithm for modelling an Adaptive Neuro Fuzzy Inference System (ANFIS) for power transformer paper conditions in order to estimate the transformer's expected life. The dielectric characteristics, dissolved gasses, and furfural of 108 running transformers were collected, which were divided into 76 training datasets and another 32 testing datasets. The degree of polymerization (DP) of the transformer paper was predicted using the ANFIS model based on using the dielectric characteristics and dissolved gases as input. These inputs were analyzed, and the best combination was selected, whereas CO + CO2, acidity, interfacial tension, and color were correlated with the paper's deterioration condition and were chosen as the input variables. The best combination of input variables and membership function was selected to build the optimal ANFIS model, which was then compared and evaluated. The proposed ANFIS model has 89.07% training accuracy and 85.75% testing accuracy and was applied to a transformer paper insulation assessment and an estimation of the expected life of four Indonesian transformers for which furfural data is unavailable. This proposed algorithm can be used as a furfural alternative for the general assessment of transformer paper conditions and the estimation of expected life and provides a helpful assistance for experts in transformer condition assessment. [ABSTRACT FROM AUTHOR]

We report herein the preparation and characterization of six readily assembled bis-coordinated homoleptic silver(I) N,N′-bis(arylimino)acenaphthene (BIAN) complexes of general structure [Ag(I)(BIAN)2]BF4 and the influence of the electronic properties of the ligand substitution pattern on their performance in electrochemical CO2 reduction (CO2R). All the explored catalysts displayed substantial current enhancements in carbon-dioxide-saturated solvents dependent on the ligated BIAN and no significant concurrent H2 evolution when utilizing 2% H2O as a proton source. Additionally, preliminary studies, employing a drop-casted ink of 0.4 mg cm−2 [Ag(I)(4-OMe-BIAN)2]BF4 (Ag4) immobilized onto carbon paper gas diffusion electrodes in a flow cell with 1M KHCO3 aqueous electrolyte, resulted in a propitious Faradaic efficiency of 51% for CO at a current density of 50 mA cm−2. [ABSTRACT FROM AUTHOR]

As a part of our research in the field of thermochemical energy storage, this study aims to investigate the potential of three fly ash samples derived from the fluidized bed reactors of three different pulp and paper plants in Austria for their use as thermochemical energy (TCES) and CO2 storage materials. The selected samples were analyzed by different physical and chemical analytical techniques such as X-ray fluorescence spectroscopy (XRF), X-ray diffraction (XRD), particle size distribution (PSD), scanning electron microscopy (SEM), inductively coupled plasma atomic emission spectroscopy (ICP-OES), and simultaneous thermal analysis (STA) under different atmospheres (N2, CO2, and H2O/CO2). To evaluate the environmental impact, leaching tests were also performed. The amount of CaO as a promising candidate for TCES was verified by XRF analysis, which was in the range of 25–63% (w/w). XRD results indicate that the CaO lies as free lime (3–32%), calcite (21–29%), and silicate in all fly ash samples. The results of STA show that all fly ash samples could fulfill the requirements for TCES (i.e., charging and discharging). A cycling stability test of three cycles was demonstrated for all samples which indicates a reduction of conversion in the first three reaction cycles. The energy content of the examined samples was up to 504 kJ/kg according to the STA results. More energy (~1090 kJ/kg) in the first discharging step in the CO2/H2O atmosphere could be released through two kinds of fly ash samples due to the already existing free lime (CaO) in those samples. The CO2 storage capacity of these fly ash samples ranged between 18 and 110 kg per ton of fly ash, based on the direct and dry method. The leaching tests showed that all heavy metals were below the limit values of the Austrian landfill ordinance. It is viable to say that the valorization of fly ash from the pulp and paper industries via TCES and CO2 storage is plausible. However, further investigations such as cycling stability improvement, system integration and a life cycle assessment (LCA) still need to be conducted. [ABSTRACT FROM AUTHOR]

The papers by Yang et al. [[5]] and Wang et al. [[6]] mainly studied the corrosion of CO SB 2 sb on gathering pipelines and the monitoring of the corrosion rate. The paper by Hou et al. [[1]] investigated the microscopic adsorption pattern of CH SB 4 sb and the competitive adsorption behavior of CH SB 4 sb and CO SB 2 sb in sodium-based montmorillonite using molecular simulation methods. The CO SB 2 sb pre-pad energized fracturing technology can not only further increase oil production, but also effectively realize the geological storage and utilization of CO SB 2 sb , thus greatly reducing the greenhouse effect. [Extracted from the article]

Since reservoirs with permeability less than 10 mD are characterized by high injection difficulty, high-pressure drop loss, and low pore throat mobilization during the water drive process, CO2 is often used for development in actual production to reduce the injection difficulty and carbon emission simultaneously. However, microfractures are usually developed in low-permeability reservoirs, which further reduces the injection difficulty of the driving medium. At the same time, this makes the injected gas flow very fast, while the gas utilization rate is low, resulting in a low degree of recovery. This paper conducted a series of studies on the displacement effect of CO2-soluble foaming systems in low-permeability fractured reservoirs (the permeability of the core matrix is about 0.25 mD). For the two CO2-soluble blowing agents CG-1 and CG-2, the effects of the CO2 phase state, water content, and oil content on static foaming performance were first investigated; then, a more effective blowing agent was preferred for the replacement experiments according to the foaming results; and finally, the effects of the blowing agents on sealing and improving the recovery degree of a fully open fractured core were investigated at different injection rates and concentrations, and the injection parameters were optimized. The results show that CG-1 still has good foaming performance under low water volume and various oil contents and can be used in subsequent fractured core replacement experiments. After selecting the injection rate and concentration, the blowing agent can be used in subsequent fractured cores under injection conditions of 0.6 mL/min and 2.80%. In injection conditions, the foaming agent can achieve an 83.7% blocking rate and improve the extraction degree by 12.02%. The research content of this paper can provide data support for the application effect of a CO2-soluble blowing agent in a fractured core. [ABSTRACT FROM AUTHOR]

The heat exchanger plays a key role in the S-CO2 power cycle of power generation systems based on waste heat and has a large impact on their cost control and compactness. In this paper, we take the channel shape of a microchannel heat exchanger as the research object and combine orthogonal tests and numerical simulation, taking the microchannel cross-section length/short-axis ratio, volume ratio and filling rate as independent variables, to numerically study multi-channel thermal–fluid–solid coupling and explore the effects of different microchannel cross-section length/short-axis ratios, volume ratios and filling rates on the thermal hydraulic and mechanical properties of the heat exchanger. The results show that a change in the channel volume ratio has a greater impact on the thermal hydraulic performance of the heat exchanger and that its heat transfer performance is only marginally affected by a change in the channel filling rate. Additionally, when other geometric parameters are kept to a certain level, the closer the shape of the channel is to a circle, the better its mechanical properties are. Within the range of permissible designs, a change in the channel volume ratio does not have an obvious impact on the mechanical properties of the microchannels, while the channel filling rate has the most significant impact. The most significant effect of the channel filling rate on the mechanical properties occurs through the channel volume ratio. [ABSTRACT FROM AUTHOR]

The civil aircraft cabin is enclosed and highly occupied, making it susceptible to a decline in indoor environmental quality. The environmental quality of civil aircraft cabins not only depends on objective factors such as temperature, relative humidity, and the presence of air pollutants such as carbon dioxide (CO2), carbon monoxide (CO), ozone (O3), particle matter (PM), and volatile organic compounds (VOCs) but also the subjective factors pertaining to the perceptions and health symptoms of passengers and crew. However, few studies have thoroughly examined the air quality and thermal comfort parameters that are measured during in-flight testing in airplane cabins, as well as the passengers' subjective perceptions. In order to evaluate the in-flight thermal comfort and air quality status, this study conducted a review of the recent literature to compile data on primary categories, standard limits, and distribution ranges of in-flight environmental factors within civil aircraft cabins. Following a search procedure outlined in this paper, 54 papers were selected for inclusion. Utilizing the Monte Carlo method, the Predicted Mean Vote (PMV) distributions under different exercise intensities and clothing thermal resistance were measured with the in-cabin temperature and humidity from in-flight tests. Recommendations based on first-hand data were made to maintain the relative humidity in the cabin below 40%, ensure wind speed remains within the range of 0–1 m/s, and regulate the temperature between 25–27 °C (for summer) and 22–27 °C (for winter). The current estimated cabin air supply rate generally complies with the requirements of international standards. Additionally, potential carcinogenic and non-carcinogenic risks associated with formaldehyde, benzene, tetrachloroethylene, and naphthalene were calculated. The sorted data of in-flight tests and the evaluation of the subjective perception of the occupants provide an evaluation of current cabin thermal comfort and air quality status, which can serve as a reference for optimizing indoor environmental quality in future generations of civil aircraft cabins. [ABSTRACT FROM AUTHOR]

Through extensive data research and analysis, this paper comprehensively summarizes the status and key insights of global carbon dioxide capture and storage (CCS) development. It aims to gain a comprehensive understanding of the relevant policies, technologies, and security measures adopted by major countries in their CCS development processes. Furthermore, it explores the existing status and limitations of China's offshore development efforts, while providing valuable recommendations for enhancing China's offshore CCS initiatives, as well as serving as a reference for other nations worldwide. Offshore CCS plays a crucial role for China to achieve the development target of carbon peak and carbon neutrality, due to its energy structure and industrial distribution. While China possesses significant offshore CCS potential, achieving commercialization still requires substantial efforts. To facilitate the process and draw insights from successful experiences in other countries, this paper illustrates the characteristics and generalizes the experience of offshore CCS industry practices in America, Europe and Japan, respectively. Furthermore, it is recommended that a new round of investigation into offshore CCS potential be conducted, while promoting integrated collaboration between geological surveying and marine scientific research. Additionally, further research on industrial policies and green financial strategies should be undertaken. [ABSTRACT FROM AUTHOR]

This paper focuses on the current application of machine learning (ML) in enhanced oil recovery (EOR) through CO2 injection, which exhibits promising economic and environmental benefits for climate-change mitigation strategies. Our comprehensive review explores the diverse use cases of ML techniques in CO2-EOR, including aspects such as minimum miscible pressure (MMP) prediction, well location optimization, oil production and recovery factor prediction, multi-objective optimization, Pressure–Volume–Temperature (PVT) property estimation, Water Alternating Gas (WAG) analysis, and CO2-foam EOR, from 101 reviewed papers. We catalog relative information, including the input parameters, objectives, data sources, train/test/validate information, results, evaluation, and rating score for each area based on criteria such as data quality, ML-building process, and the analysis of results. We also briefly summarized the benefits and limitations of ML methods in petroleum industry applications. Our detailed and extensive study could serve as an invaluable reference for employing ML techniques in the petroleum industry. Based on the review, we found that ML techniques offer great potential in solving problems in the majority of CO2-EOR areas involving prediction and regression. With the generation of massive amounts of data in the everyday oil and gas industry, machine learning techniques can provide efficient and reliable preliminary results for the industry. [ABSTRACT FROM AUTHOR]

Key long-lived greenhouse gases (CO2, CH4, and N2O) are perhaps among the best-studied components of the Earth's atmosphere today; however, attempts to predict or explain trends or even shorter-term variations of these trace gases are not always successful. Infrared spectroscopy is a recognized technique for the ground-based long-term monitoring of the gaseous composition of the atmosphere. The current paper is focused on the analysis of new data on CO2, CH4, and N2O total columns (TCs) retrieved from high resolution IR solar spectra acquired during 2009–2022 at the NDACC atmospheric monitoring station of St. Petersburg State University (STP station, 59.88°N, 29.83°E, 20 m asl.). The paper provides information on the FTIR system (Fourier-transform infrared) installed at the STP station, and an overview of techniques used for the CO2, CH4, and N2O retrievals. Trends of key greenhouse gases and their confidence levels were evaluated using an original approach which combines the Lomb–Scargle method with the cross-validation and bootstrapping techniques. As a result, the following fourteen-year (2009–2022) trends of TCs have been revealed: (0.56 ± 0.01) % yr−1 for CO2; (0.46 ± 0.02) % yr−1 for CH4; (0.28 ± 0.01) % yr−1 for N2O. A comparison with trends based on the EMAC numerical modeling data was carried out. The trends of greenhouse gases observed at the STP site are consistent with the results of the in situ monitoring performed at the same geographical location, and with the independent estimates of the global volume mixing ratio growth rates obtained by the GAW network and the NOAA Global Monitoring Laboratory. There is reasonable agreement between the CH4 and N2O TC trends for 2009–2019, which have been derived from FTIR measurements at three locations: the STP site, Izaña Observatory and the University of Toronto Atmospheric Observatory. [ABSTRACT FROM AUTHOR]

This paper reviews the application of carbonation technology to the environmental industry as a way of reducing carbon dioxide (CO(2)), a green house gas, including the presentation of related projects of our research group. An alternative technology to very slow natural carbonation is the co-called 'accelerated carbonation', which completes its fast reaction within few hours by using pure CO(2). Carbonation technology is widely applied to solidify or stabilize solid combustion residues from municipal solid wastes, paper mill wastes, etc. and contaminated soils, and to manufacture precipitated calcium carbonate (PCC). Carbonated products can be utilized as aggregates in the concrete industry and as alkaline fillers in the paper (or recycled paper) making industry. The quantity of captured CO(2) in carbonated products can be evaluated by measuring mass loss of heated samples by thermo-gravimetric (TG) analysis. The industrial carbonation technology could contribute to both reduction of CO(2) emissions and environmental remediation.

As the second most predominant greenhouse gas, methane-targeted emission mitigation holds the potential to decelerate the pace of global warming. Satellite remote sensing is an important monitoring tool, and we review developments in the satellite detection of methane. This paper provides an overview of the various types of satellites, including the various instrument parameters, and describes the different types of satellite retrieval algorithms. In addition, the currently popular methane point source quantification method is presented. Based on existing research, we delineate the classification of methane remote sensing satellites into two overarching categories: area flux mappers and point source imagers. Area flux mappers primarily concentrate on the assessment of global or large-scale methane concentrations, with a further subclassification into active remote sensing satellites (e.g., MERLIN) and passive remote sensing satellites (e.g., TROPOMI, GOSAT), contingent upon the remote sensing methodology employed. Such satellites are mainly based on physical models and the carbon dioxide proxy method for the retrieval of methane. Point source imagers, in contrast, can detect methane point source plumes using their ultra-high spatial resolution. Subcategories within this classification include multispectral imagers (e.g., Sentinel-2, Landsat-8) and hyperspectral imagers (e.g., PRISMA, GF-5), contingent upon their spectral resolution disparities. Area flux mappers are mostly distinguished by their use of physical algorithms, while point source imagers are dominated by data-driven methods. Furthermore, methane plume emissions can be accurately quantified through the utilization of an integrated mass enhancement model. Finally, a prediction of the future trajectory of methane remote sensing satellites is presented, in consideration of the current landscape. This paper aims to provide basic theoretical support for subsequent scientific research. [ABSTRACT FROM AUTHOR]

In the realm of Natural Gas Combined Cycle (NGCC) power plants, it is crucial to prioritize the mitigation of CO2 emissions to ensure environmental sustainability. The integration of post-combustion carbon capture technologies plays a pivotal role in mitigating greenhouse gas emissions enhancing the NGCC's environmental profile by minimizing its carbon footprint. This research paper presents a comprehensive investigation into the integration of solar thermal energy into the Besmaya Natural Gas Combined Cycle (NGCC) power plant, located in Baghdad, Iraq. Leveraging advanced process simulation and modeling techniques employing Aspen Plus software, the study aims to evaluate the performance and feasibility of augmenting the existing NGCC facility with solar assistance for post-carbon capture. The primary objective of this research is to conduct a thorough simulation of the Besmaya NGCC power plant under its current operational conditions, thereby establishing a baseline for subsequent analyses. Subsequently, a solar-assisted post-combustion capture (PCC) plant is simulated and seamlessly integrated into the existing power infrastructure. To accurately estimate solar thermal power potential at the Baghdad coordinates, the System Advisor Model (SAM) is employed. The integration of solar thermal energy into the NGCC power plant is meticulously examined, and the resulting hybrid system's technical viability and performance metrics are rigorously evaluated. The paper contributes to the field by providing valuable insights into the technical feasibility and potential benefits of incorporating solar thermal energy into conventional natural gas power generation infrastructure, particularly in the context of the Besmaya NGCC plant in Baghdad. The power generation capacity of the plant was set at 750 MW. With this capacity, the annual CO2 generation was estimated at 2,119,318 tonnes/year which was reduced to 18,064 tonnes/year (a 99% reduction). The findings aim to inform future decisions in the pursuit of sustainable and efficient energy solutions, addressing both environmental concerns and energy security in the region. [ABSTRACT FROM AUTHOR]

The decrease in the calorific value of refuse-derived fuel (RDF) is an unintended outcome of the progress made toward more sustainable waste management. Plastics and paper separation and recycling leads to the overall decrease in waste's calorific value, further limiting its applicability for thermal treatment. Pyrolysis has been proposed to densify energy in RDF and generate carbonized solid fuel (CSF). The challenge is that the feedstock composition of RDF is variable and site-specific. Therefore, the optimal pyrolysis conditions have to be established every time, depending on feedstock composition. In this research, we developed a model to predict the higher heating value (HHV) of the RDF composed of eight morphological refuse groups after low-temperature pyrolysis in CO2 (300–500 °C and 60 min) into CSF. The model considers cardboard, fabric, kitchen waste, paper, plastic, rubber, PAP/AL/PE (paper/aluminum/polyethylene) composite packaging pack, and wood, pyrolysis temperature, and residence time. The determination coefficients (R2) and Akaike information criteria were used for selecting the best model among four mathematical functions: (I) linear, (II) second-order polynomial, (III) factorial regression, and (IV) quadratic regression. For each RDF waste component, among these four models, the one best fitted to the experimental data was chosen; then, these models were integrated into the general model that predicts the HHV of CSF from the blends of RDF. The general model was validated experimentally by the application to the RDF blends. The validation revealed that the model explains 70–75% CSF HHV data variability. The results show that the optimal pyrolysis conditions depend on the most abundant waste in the waste mixture. High-quality CSF can be obtained from wastes such as paper, carton, plastic, and rubber when processed at relatively low temperatures (300 °C), whereas wastes such as fabrics and wood require higher temperatures (500 °C). The developed model showed that it is possible to achieve the CSF with the highest HHV value by optimizing the pyrolysis of RDF with the process temperature, residence time, and feedstock blends pretreatment. [ABSTRACT FROM AUTHOR]

In order to reduce the production cost of the methane carbon dioxide reforming reaction, and improve its actual production efficiency, in this paper, the optimal working parameters of the methane carbon dioxide reforming reaction are studied. The influence of different factors on methane conversion is studied via a single-factor numerical simulation analysis and the response surface methodology. Firstly, a numerical model of the methane carbon dioxide reforming reaction is established using Ansys Chemkin Pro software to analyze the influence of single factors (reactor temperature, reaction pressure, gas velocity) on methane conversion rate; secondly, the response surface model with the methane conversion rate as the response value is established using the BBD (Box–Behnken design) method; and finally, the order of influence of each variable on methane conversion and the optimal reaction conditions are determined using the response surface method. The factors are listed in order of their influence on methane conversion as follows: reactor temperature > pressure > speed. The results show that when the temperature is 1135.114 K, the pressure is 0.103 MPa and the speed is 10slpm, the methane conversion rate is 93.7018%. In this paper, a method is adopted in which chemical reaction process simulation and numerical results prediction are combined, significantly reducing the simulation time and improving the calculation efficiency and accuracy, thus being of considerable scientific significance and theoretical value. [ABSTRACT FROM AUTHOR]

In the industrialization process, the difficulty in implementing environmental protection and enhancing the effect of environmental emission reduction are common problems to the developing countries, which are directly related to the quality of social development. This paper takes environmental centralization as the solution idea, takes the vertical management reform of environmental protection agencies implemented in China as the research object, and evaluates the environmental emission reduction effect and mechanism of action of centralized reform based on provincial environmental economic panel data using difference-in-differences model and intermediary model. The following conclusions are drawn: (1) The environmental centralization has significantly improved the provincial environmental emission reduction effect. After China's vertical management reforms were implemented, per capita CO2 emissions decreased by 11.1%, and industrial source SO2 emissions fell by 35.7%. (2) By increasing investment in urban environmental infrastructure construction, the reform has raised the level of investment and regulation in environmental protection construction, which in turn has effectively improved the ability to reduce environmental emissions. (3) After the implementation of the reform, the emission reduction effects of the reform on per capita CO2 and industrial source SO2 are 10.1% and 14.2% higher in provinces with lower industrial output value compared to those with higher industrial output value. At the same time, the effect of reform in provinces with a strong degree of local government intervention was significantly lower than that in provinces with a weak degree of local government intervention. The emission reduction effects of the reform implementation are 10.2% (per capita CO2) and 30.5% (industrial source SO2) lower, respectively. Based on the above findings, this paper argues that environmental centralization is an effective measure to advance the improvement of environmental quality and efficiency. In addition, China's reform experience has implications for other developing countries. [ABSTRACT FROM AUTHOR]

Solar geoengineering (SG) solutions have many advantages compared to the difficulty of carbon dioxide removal (CDR): SG produces fast results, is shown here to have much higher efficiency than CDR, is not related to fossil fuel legislation, reduces the GHG effect including water vapor, and is something we all can participate in by brightening the Earth with cool roofs and roads. SG requirements detailed previously to mitigate global warming (GW) have been concerning primarily because of overwhelming goals and climate circulation issues. In this paper, annual solar geoengineering (ASG) equations and estimated requirements for yearly solar radiation modification (SRM) of areas are provided along with the advantages of annual solar geoengineering (ASG) to mitigate yearly global warming temperature increases. The ASG albedo area modification requirements found here are generally 50 to potentially more than 150 times less compared to the challenge of full SG GW albedo mitigation, reducing circulation concerns and increasing feasibility. These reductions are applied to L1 space sunshading, Earth brightening, and stratosphere aerosol injection (SAI) SRM annual area requirements. However, SAI coverage compared to other methods will have higher yearly increasing maintenance costs in the annual approach. Results also show that because ASG Earth albedo brightening area requirements are much smaller than those needed for full mitigation, there are concerns that worldwide negative SG would interfere with making positive advances for several reasons. That is, negative SG currently dominates yearly practices with the application of dark asphalt roads, roofs, and building sides. This issue is discussed. [ABSTRACT FROM AUTHOR]

In response to the urgent need to address climate change and reduce carbon emissions, there has been a growing interest in innovative approaches that integrate AI and CDR technology. This article provides a comprehensive review of the current state of research in this field and aims to highlight its potential implications with a clear focus on the integration of AI and CDR. Specifically, this paper outlines four main approaches for integrating AI and CDR: accurate carbon emissions assessment, optimized energy system configuration, real-time monitoring and scheduling of CDR facilities, and mutual benefits with mechanisms. By leveraging AI, researchers can demonstrate the positive impact of AI and CDR integration on the environment, economy, and energy efficiency. This paper also offers insights into future research directions and areas of focus to improve efficiency, reduce environmental impact, and enhance economic viability in the integration of AI and CDR technology. It suggests improving modeling and optimization techniques, enhancing data collection and integration capabilities, enabling robust decision-making and risk assessment, fostering interdisciplinary collaboration for appropriate policy and governance frameworks, and identifying promising opportunities for energy system optimization. Additionally, this paper explores further advancements in this field and discusses how they can pave the way for practical applications of AI and CDR technology in real-world scenarios. [ABSTRACT FROM AUTHOR]

Christian environmental ethics have always navigated the thin line between the Scylla of pantheism and the Charybdis of deism. On the one hand, removing God from the world avoids pantheism but can inadvertently render the divine a distant, absentee father who cares little about what we do with the environment. On the other hand, if we bring the Creator too close to creation, we may begin to blur the distinction between them, fringing on pantheism. While making nature divine might at first seem to heighten the environmental desecration of the earth by making it a literal de-sacralizing of the sacred, this may be only a surface-level reading (or, at least, only true of very carefully nuanced versions of pantheism). For the pantheist, God would not just be the trees but the machines that log them; God would not just be the polar bears but the carbon dioxide that is evicting them. God would be no more present in that which is desecrated than in that which does the desecration (e.g., God would be one with the pesticides, bulldozers, and factory smoke). By making God everything, it becomes difficult to call any person, act, legislation, or event godless. This paper offers Henry More's view of divine space as a constructive, Platonic Christian middle way between these two extremes, charting a God who is spatially present to nature without being pantheistically reducible to it, in the same way that space is intimately close to the objects within it while nonetheless remaining distinct from them. The bulk of the paper counters potential opponents to this proposal, specifically defending Morean space from the charge that it would break down the Creator–creature distinction and/or cave to the environmental Scylla of pantheism. [ABSTRACT FROM AUTHOR]

The extensive utilization of fossil fuels has led to a rapid increase in atmospheric CO2 concentration, resulting in various environmental issues. To reduce reliance on fossil fuels and mitigate CO2 emissions, it is important to explore alternative methods of utilizing CO2 and H2 as raw materials to obtain high-value-added chemicals or fuels. One such method is CO2 methanation, which converts CO2 and H2 into methane (CH4), a valuable fuel and raw material for other chemicals. However, CO2 methanation faces challenges in terms of kinetics and thermodynamics. The reaction rate, CO2 conversion, and CH4 yield need to be improved to make the process more efficient. To overcome these challenges, the development of suitable catalysts is essential. Non-noble metal catalysts have gained significant attention due to their high catalytic activity and relatively low cost. In this paper, the thermodynamics and kinetics of the CO2 methanation reaction are discussed. The focus is primarily on reviewing Ni-based, Co-based, and other commonly used catalysts such as Fe-based. The effects of catalyst supports, preparation methods, and promoters on the catalytic performance of the methanation reaction are highlighted. Additionally, the paper summarizes the impact of reaction conditions such as temperature, pressure, space velocity, and H2/CO2 ratio on the catalyst performance. The mechanism of CO2 methanation is also summarized to provide a comprehensive understanding of the process. The objective of this paper is to deepen the understanding of non-noble metal catalysts in CO2 methanation reactions and provide insights for improving catalyst performance. By addressing the limitations of CO2 methanation and exploring the factors influencing catalyst effectiveness, researchers can develop more efficient and cost-effective catalysts for this reaction. [ABSTRACT FROM AUTHOR]

Using an aerosol–climate coupled model, this paper has investigated the changes in distributions of anthropogenic and natural particles due to 4 × CO2-induced global warming, under the low emission scenario of Representative Concentration Pathway 4.5 (RCP4.5). Special attention is paid to the seasonal variations of aerosol size modes. With rising CO2 levels, surface warming, and changes in atmospheric circulations and hydrologic cycles are found during both summer (JJA) and winter (DJF). For anthropogenic particles, changes in fine anthropogenic particulate matter (PM2.5, particles with diameters smaller than 2.5 μm) decrease over high-latitude regions and increase over the tropics in both DJF and JJA. Global mean column concentrations of PM2.5 decrease by approximately 0.19 mg m−2, and concentrations of coarse anthropogenic particles (CPM, particles with diameters larger than 2.5 μm) increase by 0.005 mg m−2 in JJA. Changes in anthropogenic particles in DJF are similar to those in JJA, but the magnitudes of maximum regional changes are much smaller than those in JJA. The coarse anthropogenic particles (CPM, particles with diameters larger than 2.5 μm) increase over northern Africa and the Arabian Peninsula during JJA, whereas changes in anthropogenic CPM during DJF are minimal. During both JJA and DJF, changes in anthropogenic CPM are about two orders of magnitude smaller than those of anthropogenic PM2.5. Enhanced wet deposition by large-scale precipitation under rising CO2-induced surface warming is the critical factor affecting changes in anthropogenic particles. For natural particles, the distribution of change in the natural PM2.5 burden is similar to that of natural CPM, but much larger than natural CPM during each season. Both natural PM2.5 and CPM burdens increase over northern Africa and the Arabian Peninsula during JJA, but decrease over most of the continental regions during DJF. Changes in surface wind speed, divergence/convergence of surface wind, and precipitation are primary reasons for the variation of natural particles. [ABSTRACT FROM AUTHOR]

The accumulation of carbon dioxide in the atmosphere due to fossil fuel burning and deforestation has caused global warming and an increase in extreme weather events. To complement the shift towards clean energy, it is crucial to adopt methods for carbon dioxide removal, known as negative emission technologies. Enhanced weathering is one such approach that involves accelerating the natural process of rock weathering by spreading finely ground rocks over large areas, such as agricultural land or coastal areas. This exploratory review paper provides an overview of the fundamental mechanisms behind enhanced weathering, and outlines the techniques for its implementation. The environmental benefits of enhanced weathering are highlighted, including carbon dioxide removal, and improvement of soil fertility. Furthermore, potential impacts on ecosystems and biodiversity are examined, along with the effects on water, soil and air quality. The paper also considers the risks and challenges associated with large-scale implementation and long-term stability of enhanced weathering. Additionally, the integration of enhanced weathering with Sustainable Development Goals is explored, along with the potential co-benefits and trade-offs with other sustainability objectives. To conclude, this exploratory review paper summarizes the key findings and proposes avenues for further research in this field of enhanced weathering. [ABSTRACT FROM AUTHOR]

Carbon dioxide (CO2) capture and separation constitute an important field of research as we seek to reduce the effects of climate change. Because of their porosity, resilient crystallinity, high adsorption capacity, and affinity for CO2, cyclodextrin-based metal-organic frameworks (CD-MOFs) have emerged as attractive materials for carbon capture. This paper gives an overview of CD-MOFs and their applications in CO2 capture and separation. Several studies have been conducted to synthesize and characterize CD-MOFs for CO2 capture. The causes of the high binding affinity of CO2 in CD-MOFs were discovered through mechanistic studies on CO2 adsorption. Furthermore, CD-MOF modifications have been carried out to improve the sorption capacity and selectivity of CO2 adsorption. Meanwhile, several researchers have reported using CD-MOFs for gaseous CO2 membrane separation. This paper also highlights the current gaps in CD-MOF research and future outlooks in carbon capture and separation using CD-MOFs. [ABSTRACT FROM AUTHOR]

The interaction between CO2, formation water, and rock surfaces after CO2 flooding and the mechanism by which it affects CO2 storage were studied in this paper. The results show that variations in the solubility of CO2 in crude oil under pressure are similar to those observed in formation water. The solubility of CO2 increases as pressure increases under a low-pressure conditions. The solubility of CO2 in crude oil increases significantly when crude oil is in a low-viscosity state, and this makes it easier to diffuse CO2 into the oil phase at high temperatures. More resistance is encountered when CO2 diffuses into the liquid-containing space of an irregular core, making the coefficient of diffusion into the oil–water two-phase flow in the porous medium smaller. After the core is corroded by a CO2-saturated aqueous solution, the quartz content in the mineral component increases and the plagioclase and potassium feldspar content significantly decrease. The dissolution of the feldspar leads to the formation of a large amount of secondary kaolinite, thus increasing the kaolinite content. In the early stage of CO2 erosion during dynamic displacement, the combined effect of particle migration and inorganic precipitation leads to a slow growth in core permeability and porosity. As the erosion progresses, the influence of particle migration and inorganic precipitation on permeability gradually decreases, while the porosity of the core gradually increases. The secondary pores play a role, and the erosion of the CO2–water system makes the permeability and porosity of the core gradually increase. During dynamic displacement, CO2 is mainly stored in the reservoir in free and irreducible states. Under the pressure of the reservoir, some of the CO2 participates in erosion reactions and is stored in the rock or the solution in the form of minerals or ions. In addition, a small portion of the CO2 is dissolved in the residual water and residual oil that remain after the dynamic displacement. The results of this paper can provide some theoretical support for the design of a CO2 storage site. [ABSTRACT FROM AUTHOR]

Low-permeability reservoirs have become an important field of oil and gas development in China. CO2 flooding technology is an effective technical means for tertiary oil recovery. Although the asphaltene in the system is deposited in the form of a solid after CO2 injection into the reservoir in contact with crude oil, which causes a certain blockage to the reservoir, the dissolution during the injection process improves the seepage capacity of the reservoir as a whole, and the damage degree of CO2 flooding to low-permeability reservoirs under different injection modes is different. In this paper, the damage degree of asphaltene precipitation to low-permeability reservoirs under different injection modes of CO2 flooding is quantitatively characterized. The mechanism experiment of organic scale plugging after continuous CO2 flooding and CO2–water alternate flooding, the wettability experiment of reservoirs, and the evaluation experiment of CO2–water solution on rock dissolution are carried out, and the variation characteristics of relative permeability curve parameters are evaluated. In this paper, the damage degree of asphaltene precipitation to low-permeability reservoirs under different injection modes of CO2 flooding is quantitatively characterized. The mechanism experiment of organic scale plugging after continuous CO2 flooding and CO2–water alternate flooding, the wettability experiment of reservoirs, and the evaluation experiment of CO2–water solution on rock dissolution are carried out. The variation characteristics of relative permeability curve parameters are evaluated. The results show that the organic scale produced by CO2 flooding will block the pore throat of the rock, but, on the whole, the dissolution caused by the reaction of CO2 and chlorite is stronger, which makes the recovery rate of low-permeability reservoirs effectively improved. The organic scale blockage caused by CO2–water alternating flooding is weaker than that caused by continuous CO2 flooding. The dissolution effect is better and the permeability is higher. It can achieve a better oil displacement effect in pores with a pore size greater than 0.2 μm. On the whole, it can increase the core pore space and seepage channel, so that the recovery rate of low-permeability reservoirs can be effectively improved. This study has important theoretical and practical significance for improving oil recovery in low-permeability reservoirs. [ABSTRACT FROM AUTHOR]

Pt nanoparticles were successfully deposited on uncatalyzed carbon paper by the supercritical CO2 deposition (SCD) method using platinum (II) acetylacetonate as a precursor followed by thermal conversion. A full 24 factorial design (four factors, each with two levels) was used to investigate the main effect of four factors (deposition temperature, deposition time, reduction temperature, and reduction time) and the interaction effects between them. The morphological structures and surface properties of the Pt/carbon paper composite were analyzed by X-ray diffraction (XRD), scanning electron microscope (SEM)/energy-dispersive X-ray spectroscopy analyzer (EDS), and high-resolution transmission electron microscopy (HR-TEM). The results of the 24 factorial design showed that Pt loading on the substrate correlated significantly with deposition time, while Pt aggregation slightly increased with the thermal reduction temperature. Data obtained from both XRD and HR-TEM were in good agreement and showed that Pt nanoparticles were homogeneously dispersed on the substrate with diameters of 7.2–8.7 nm. [ABSTRACT FROM AUTHOR]

Carbon dioxide (CO2) capture and storage (CCS) is frequently identified as a potential component to achieving a decarbonized power system at least cost; however, power system models frequently lack detailed representation of CO2 transportation, injection, and storage (CTS) infrastructure. In this paper, we present a novel approach to explicitly represent CO2 storage potential and CTS infrastructure costs and constraints within a continental-scale power system capacity expansion model. In addition, we evaluate the sensitivity of the results to assumptions about the future costs and performance of CTS components and carbon capture technologies. We find that the quantity of CO2 captured within the power sector is relatively insensitive to the range of CTS costs explored, suggesting that the cost of CO2 capture retrofits is a more important driver of CCS implementation than the costs of transportation and storage. Finally, we demonstrate that storage and injection costs account for the predominant share of total costs associated with CTS investment and operation, suggesting that pipeline infrastructure costs have limited influence on the competitiveness of CCS. [ABSTRACT FROM AUTHOR]

Direct air capture (DAC) systems that capture carbon dioxide (CO2) directly from the atmosphere are garnering considerable attention for their potential role as negative emission technologies in achieving net-zero CO2 emission goals. Common DAC technologies are based either on liquid–solvent (L-DAC) or solid–sorbent (S-DAC) to capture CO2. A comprehensive multi-factor comparative economic analysis of the deployment of L-DAC and S-DAC facilities across various United States (U.S.) cities is presented in this paper. The analysis considers the influence of various factors on the favorability of DAC deployment, including local climatic conditions such as temperature, humidity, and CO2 concentrations; the availability of energy sources to power the DAC system; and costs for the transport and storage of the captured CO2 along with the consideration of the regional market and policy drivers. The deployment analysis in over 70 continental U.S. cities shows that L-DAC and S-DAC complement each other spatially, as their performance and operational costs vary in different climates. L-DAC is more suited to the hot, humid Southeast, while S-DAC is preferrable in the colder, drier Rocky Mountain region. Strategic deployment based on regional conditions and economics is essential for promoting the commercial adoptability of DAC, which is a critical technology to meet the CO2 reduction targets. [ABSTRACT FROM AUTHOR]

Numerical simulations of the leakage and diffusion behavior of liquid CO2 vessels and security analyses were conducted in this paper, based on a CO2 compression energy storage system. With isentropic choking model, the leakage of vessels under specific conditions was numerically simulated. The influence of different wind speeds on leakage in near-zone field was studied. Meanwhile, the diffusion characteristics of CO2 under three different influencing factors were investigated with the UDM (Unified Dispersion Model) diffusion model, and the diffusion ranges of certain concentrations were detected in the far-zone field. The results show that the low-temperature zone of the 50 mm leak aperture can reach 0.74 m downwind, and basically does not change with wind speed. In the leakage direction, the maximum damage zone of high-speed flow can reach 7.70 m. For the far-zone field, the diffusion area and downwind distance of a dangerous concentration decrease with the increasing of wind speed, and the hazardous area of the low concentration is greatly affected. Based on specific conditions, the maximum diffusion area is 78.46 m2 at 1 m/s wind speed, and the dangerous range reaches 36.32 m downwind. The larger the leakage aperture, the faster the growth trend of the low concentration area under the same conditions. As the equivalent radius of the leakage aperture is less than 50 mm, the maximum diffusion area is proportional to the cubic of the leakage aperture radius. The higher the height of the leakage source, the smaller the concentration range at 1.5 m, which is the average human breathing height. The overall cloud moves upward, meaning that the ground risk decreases. When the leakage aperture is 50 mm and the wind speed is 1 m/s, the maximum cloud diffusion range is 857.35 m2 at the leakage height of 2 m, and the dangerous range reaches 109.53 m downwind, where the maximum concentration is 14.65%. [ABSTRACT FROM AUTHOR]

Ecofuels and their feedstock come in three main product classes: electrofuels (e-Fuels), biofuels, and non-biowaste-derived fuels. Ecofuels originate from non-fossil sources, derived from circular raw materials such as non-food organic waste, renewable hydrogen, and captured CO2 through a rapid process of carbon fixation. Proposed regulation drafts under discussion indicate that new fuels would need to reach a substantial degree of climate neutrality. The manufacture of all ecofuels, however, requires energy input to accomplish the conversion of the initial feedstock; their climate neutrality claims stem from the use of renewable electric energy and/or biomasses in the production process, but fossil fuels are still the main primary sources of global (and the EU's) electric power, and most biofuels consumed in the EU transport mix are still crop-based, with potential conflicts with food and land use. Furthermore, entirely neglecting GHG emissions from renewable energy generation is scientifically debatable, as the impact of the energy (and the related GHG emissions) embedded in the materials used to build renewable energy facilities is small, but not nil. The paper reports ecofuel trends according to the above-mentioned originating technologies and discusses the issues related to their development. [ABSTRACT FROM AUTHOR]

As the main contributor of carbon emissions, the low-carbon transition of the industrial sector is important for achieving the goal of carbon dioxide peaking. Hydrogen-enabled industrial energy systems (HIESs) are a promising way to achieve the low-carbon transition of industrial energy systems, since the hydrogen can be well coordinated with renewable energy sources and satisfy the high and continuous industrial energy demand. In this paper, the long-term capacity expansion planning problem of the HIES is formulated from the perspective of industrial parks, and the targets of carbon dioxide peaking and the gradual decommissioning of existing equipment are considered as constraints. The results show that the targets of carbon dioxide peaking before different years or with different emission reduction targets can be achieved through the developed method, while the economic performance is ensured to some extent. Meanwhile, the overall cost of the strategy based on purchasing emission allowance is three times more than the cost of the strategy obtained by the developed method, while the emissions of the two strategies are same. In addition, long-term carbon reduction policies and optimistic expectations for new energy technologies will help industrial parks build more new energy equipment for clean transformation. [ABSTRACT FROM AUTHOR]

As an advanced energy storage technology, the compressed CO2 energy storage system (CCES) has been widely studied for its advantages of high efficiency and low investment cost. However, the current literature has been mainly focused on the TC-CCES and SC-CCES, which operate in high-pressure conditions, increasing investment costs and bringing operation risks. Meanwhile, some studies based on the phase-change CO2 energy storage system also have had the disadvantages of low efficiency and the extra necessity of heat or cooling sources. To overcome the above problems, this paper proposes an innovative compressed CO2 phase-change energy storage system. During the energy charge process, molten salt and water are used to store heat with a smaller temperature difference in heat exchangers, and high-pressure CO2 is reserved in liquid form. During the energy discharge process, throttle expansion is applied to realize the evaporation at room temperature, and CO2 absorbs the reserved heat to improve the power capacity in the turbine and the system energy storage efficiency. The thermodynamic and exergoeconomic studies are performed firstly by using MATLAB. Then, the parametric study based on energy storage efficiency, system unit product cost, and exergy destruction is analyzed. The results show that energy storage efficiency can be improved by lifting liquid CO2 pressure as well as compressor and turbine isentropic efficiencies, and CO2 evaporation pressure has the optimal pressure point. The system unit product cost can be reduced by decreasing liquid CO2 pressure and compressor isentropic efficiency, while CO2 evaporation pressure and turbine isentropic efficiency both have optimal points. Finally, the optimization of two performances is performed by NSGA-II, and they can reach 75.30% and 41.17 $/GJ, respectively. Moreover, the optimal energy storage efficiency is obviously higher than that of other energy storage technologies, indicating the great advantage of the proposed system. This study provides an innovative research method for a new type of large-scale energy storage system. [ABSTRACT FROM AUTHOR]

Carbon dioxide (CO2) emissions from the construction of road infrastructure have been of growing interest in recent years. This paper proposes a binary statistical method for highway construction based on project cost control and a construction management system. A quantitative analysis of the CO2 emissions from highway construction activities was also conducted to guide the formulation of a carbon reduction strategy. Taking an expressway in central China as a case study, the CO2 emissions from different construction activities were calculated. The results revealed that the CO2 emissions for the whole construction project reached 10,605.2 t·km−1·lane−1, with the raw material production and on-site construction phases accounting for 95.2% and 4.8%, respectively. The values for bridge and tunnel engineering were much higher than those for other engineering types. In the raw material production phase, steel and cement production contributed the most to emissions (more than 99%). During the on-site construction phase, diesel and electricity consumption contributed 90% to CO2 emissions, especially from earthwork, subgrade protection, bridge engineering, tunnel excavation, and pavement surfacing. Accordingly, efforts should be focused on the key points and directed toward using recycled and low-carbon materials and improving working efficiency, machinery performance, and construction technology. [ABSTRACT FROM AUTHOR]

As the conventional inert gas, it is used for the prevention and control of coal's spontaneous combustion, mainly N2 and CO2. However, there is limited research focusing on the inerting effect of composite inert gas. This paper studied the impact of using a premixed inert gas (N2 accounted for 50%, 60%, 70%, and 80%) instead of CO2 on the inerting effect of nearly horizontal and gently inclined goaf by building a physical similarity simulation experiment platform. The experimental results showed that the inerting effect of premixed inert gas was better than that of CO2. For instance, in a nearly horizontal goaf, the inerting effect of the premixed inert gas was optimal when the N2 accounted for 70%. The average O2 concentration in the monitored area decreased from 9.7% with CO2 to 6.4%. In addition, in the gently inclined goaf, the premixed inert gas exhibited an accumulation state similar to CO2, primarily occurring in the lower part region adjacent to the working face. Furthermore, the accumulation state of premixed inert gas was inversely proportional to its inerting effect. This study has important reference significance for applying inert gas fire prevention and extinguishing technology in mines. [ABSTRACT FROM AUTHOR]

The urgent need to find mitigating pathways for limiting world CO2 emissions to net zero by 2050 has led to intense research on CO2 sequestration in deep saline reservoirs. This paper reviews key advancements in lab- and simulation-scale research on petrophysical, geochemical, and mineralogical changes during CO2–brine–rock interactions performed in the last 25 years. It delves into CO2 MPD (mineralization, precipitation, and dissolution) and explores alterations in petrophysical properties during core flooding and in static batch reactors. These properties include changes in wettability, CO2 and brine interfacial tension, diffusion, dispersion, CO2 storage capacity, and CO2 leakage in caprock and sedimentary rocks under reservoir conditions. The injection of supercritical CO2 into deep saline aquifers can lead to unforeseen geochemical and mineralogical changes, possibly jeopardizing the CCS (carbon capture and storage) process. There is a general lack of understanding of the reservoir's interaction with the CO2 phase at the pore/grain scale. This research addresses the gap in predicting the long-term changes of the CO2–brine–rock interaction using various geochemical reactive transport simulators. Péclet and Damköhler numbers can contribute to a better understanding of geochemical interactions and reactive transport processes. Additionally, the dielectric constant requires further investigation, particularly for pre- and post-CO2–brine–rock interactions. For comprehensive modeling of CO2 storage over various timescales, the geochemical modeling software called the Geochemist's Workbench was found to outperform others. Wettability alteration is another crucial aspect affecting CO2–brine–rock interactions under varying temperature, pressure, and salinity conditions, which is essential for ensuring long-term CO2 storage security and monitoring. Moreover, dual-energy CT scanning can provide deeper insights into geochemical interactions and their complexities. [ABSTRACT FROM AUTHOR]

In recent years, CO2 flooding has become an important technical measure for oil and gas field enterprises to further improve oil and gas recovery and achieve the goal of "dual carbon". It is also one of the concrete application forms of CCUS. Numerical simulation based on CO2-EOR plays an indispensable role in the study of the mechanism of CO2 flooding and buried percolation, allowing for technical indicators to be selected and EOR/EGR prediction to be improved for reservoir engineers. This paper discusses the numerical simulation techniques related to CO2 flooding and storage, including mathematical models and solving algorithms. A multiphase and multicomponent mathematical model is developed to describe the flow mechanism of hydrocarbon components–CO2–water underground and to simulate the phase diagram of the components. The two-phase P-T flash calculation with SSI (+DEM) and the Newton method is adopted to obtain the gas–liquid phase equilibrium parameters. The extreme value judgment of the TPD function is used to form the phase stability test and miscibility identification model. A tailor-made multistage preconditioner is built to solve the linear equation of the strong-coupled, multiphase, multicomponent reservoir simulation, which includes the variables of pressure, saturation, and composition. The multistage preconditioner improves the computational efficiency significantly. A numerical simulation of CO2 injection in a carbonate reservoir in the Middle East shows that it is effective for researching the recovery factor and storage quantity of CO2 flooding based on the above numerical simulation techniques. [ABSTRACT FROM AUTHOR]

In this work, we focus on the prediction of the influence of CO2 laser parameters on the kerf properties of cut spruce wood. Laser kerf cutting is mainly characterized by the width of kerf and the width of the heat-affected zone, which depend on the laser power, cutting speed, and structure of the cut wood, represented by the number of cut annual rings. According to the measurement results and ANN prediction results, for lower values of the laser power (P) and cutting speed (v), the effect of annual rings (ARs) is non-negligible. The results of the sensitivity analysis show that the effect of v increases at higher energy density (E) values. With P in the range between 100 and 500 W, v values between 3 and 50 mm·s−1, and AR numbers between 3 and 11, the combination of P = 200 W and v = 50 mm·s−1, regardless of the AR value, leads to the best cut quality for spruce wood. In this paper, the main goal is to show how changes in the input parameters affect the characteristics of the cutting kerf and heat-affected zones for all possible input parameter values. [ABSTRACT FROM AUTHOR]

The objective of this paper was to study the sCO2 cycle as a waste heat recovery system for a 180 kW biogas engine. The research methodology adopted was numerical simulations through two models built in different programs: Aspen HYSYS and GT Suite. The models were used to optimize the design and thermodynamic parameters of a CO2 cycle in terms of system power, system efficiency, expander, and compressor efficiency. Depending on the objective function, the sCO2 cycle could provide additional power ranging from 27.9 to 11.3 kW. Based on the calculation performed, "Recuperated cycle at maximum power" was selected for further investigation. The off-design analysis of the system revealed the optimum operating point. The authors designed the preliminary dimensions of the turbomachinery, i.e., the rotor dimension is 16 mm, which will rotate at 100,000 rpm. [ABSTRACT FROM AUTHOR]

Supercritical fluid extraction (SFE) techniques have garnered significant attention as green and sustainable methods for obtaining biologically active substances from a diverse array of plant byproducts. This paper comprehensively reviews the use of supercritical fluid extraction (SFE) in obtaining bioactive compounds from various plant residues, including pomace, seeds, skins, and other agricultural byproducts. The main purpose of supercritical fluid extraction (SFE) is the selective isolation and recovery of compounds, such as polyphenols, essential oils, vitamins, and antioxidants, that have significant health-promoting properties. Using supercritical carbon dioxide as the solvent, supercritical fluid extraction (SFE) not only eliminates the need for hazardous organic solvents, e.g., ethanol, and methanol, but also protects heat-sensitive bioactive compounds. Moreover, this green extraction technique contributes to waste valorisation by converting plant byproducts into value-added extracts with potential applications in the food, pharmaceutical, and cosmetic industries. This review highlights the advantages of SFE, including its efficiency, eco-friendliness, and production of residue-free extracts, while discussing potential challenges and future prospects for the utilisation of SFE in obtaining biologically active substances from plant byproducts. [ABSTRACT FROM AUTHOR]

The preparation of CO2-containing polymers with improved degradation properties is still very challenging. An elegant method for preparing these polymers is to use CO2-containing monomers in ring-opening polymerizations (ROP) which are particularly gentle and energy-saving methods. However, cyclic carbonates are required for this which are not readily available. This paper therefore aims to present the optimization and comparison of two synthesis methods to obtain cyclic carbonates for ROP. Within this work, cyclic styrene carbonate was synthesized from readily available raw materials by using a Jacobsen catalyst for the reaction of styrene oxide and carbon dioxide or an organocatalyst for the transesterification of methyl carbonate with 1-phenyl-1,2-ethanediol. The latter performed with 100% selectivity to the desired styrene carbonate, which was succesfully tested in ROP, producing an amorphous thermoplastic polymer with a TG of 185 °C. [ABSTRACT FROM AUTHOR]

Increased warming in the Arctic is of great concern. This is particularly due to permafrost degradation, which is expected to accelerate microbial breakdown of soil organic carbon, with its further release into the atmosphere as carbon dioxide (CO2). The fine-scale variability of CO2 fluxes across highly mosaic Arctic tundra landscapes can provide us with insights into the diverse responses of individual plant communities to environmental change. In the paper, we contribute to filling existing gaps by investigating the variability of CO2 flux rates within different landscape units for dominant vegetation communities and plant species across typical tundra of the southern part of the Taimyr Peninsula, Siberia. In general, the variability of soil CO2 flux illustrates a four-fold increase from non-vascular vegetation, mainly lichens and mosses (1.05 ± 0.36 µmol m−2 s−1), towards vascular plants (3.59 ± 0.51 µmol m−2 s−1). Barren ground ("frost boils") shows the lowest value of 0.79 ± 0.21 µmol m−2 s−1, while considering the Arctic "browning" phenomenon, a further substantial increase of CO2 flux can be expected with shrub expansion. Given the high correlation with top soil temperature, well-drained and relatively dry habitats such as barren ground and non-vascular vegetation are expected to be the most sensitive to the observed and projected temperature growth in the Arctic. For mixed vegetation and vascular species that favor wetter conditions, soil moisture appears to play a greater role. Based on the modeled seasonal pattern of soil CO2 flux and precipitation records, and applying the rainfall simulations in situ we outlined the role of precipitation across enhanced CO2 emissions (i.e., the "Birch" effect). We found that a pulse-like growth of soil CO2 fluxes, observed within the first few minutes after rainfall on vegetated plots, reaches 0.99 ± 0.48 µmol m−2 s−1 per each 1 mm of precipitation, while barren ground shows 55–70% inhibition of CO2 emission during the first several hours. An average additive effect of precipitation on soil CO2 flux may achieve 7–12% over the entire growing season, while the projected increased precipitation regime in the Arctic may strengthen the total CO2 release from the soil surface to the atmosphere during the growing season. [ABSTRACT FROM AUTHOR]

Under-deposit corrosion is widely present in the pipelines of oil and gas production, causing significant corrosion damage. In this paper, a novel electrochemical cathodic-polarization method was carried out to accelerate the formation of CaCO3 scale on a X65 steel surface in a simulated solution containing scaling ions. Subsequently, pre-scaled X65 steel was placed in a high temperature and pressure autoclave to conduct corrosion weight-loss experiments and in situ electrochemical measurements. The study mainly compared the corrosion inhibition behavior of four quaternary ammonium salt corrosion inhibitors, pyridinium quaternary salt (BPC), quinolinium quaternary salt (BQC), 8-hydroxyquinolinium quaternary salt (BHQ) and pyridinium (1-chloromethyl naphthalene) quaternary salt (1-CPN), in a simulated oilfield scale under corrosive conditions. The results of the weight-loss experiments demonstrated that the inhibition efficiencies of the corrosion inhibitors from high to low were as follows: 1-CPN < BHQ < BQC < BPC. The in situ electrochemical measurements showed that the immersion time and type of corrosion inhibitor had a pronounced influence on the corrosion and corrosion inhibition behavior of X65 steel with CaCO3 coating. It was also proved using both EIS and PC that 1-CPN shows the best inhibition performance in all. Lastly, the inhibition mechanism of corrosion inhibitors at under-deposit conditions was analyzed via a surface morphology observation of SEM. [ABSTRACT FROM AUTHOR]

The reservoir type of the MH oil field in the Junggar Basin is a typical low-permeability conglomerate reservoir. The MH oilfield was developed by water injection in the early stage. Nowadays, the reservoir damage is serious, and water injection is difficult. There is an urgent need to carry out conversion injection flooding research to improve oil recovery. The use of CO2 oil-flooding technology can effectively supplement formation energy, reduce greenhouse gas emissions, and improve economic benefits. In order to clarify the feasibility of CO2 flooding to improve oil recovery in conglomerate reservoirs with low permeability, strong water sensitivity, and severe heterogeneity, this paper researched the impact of CO2 miscibility on production characteristics and mechanisms through multi-scale experiments. The aim was to determine the feasibility of using CO2 flooding to enhance oil recovery. This study initially elucidated the oil displacement characteristics of varying degrees of miscibility in different dimensions using slim tube experiments and long core experiments. Subsequently, mechanistic research was conducted, focusing on the produced oil components, changes in interfacial tension, and conditions for pore mobilization. The results indicate that the minimum miscibility pressure (MMP) of the block is 24 MPa. Under the slim tube scale, the increase in the degree of miscibility can effectively delay the gas breakthrough time; under the core scale, once the pressure reaches the near mixing phase, the drive state can transition from a non-mixed "closed-seal" to a "mixed-phase" state. Compared to the immiscible phase, the near-miscible and completely miscible phase can improve the final recovery efficiency by 9.27% and 18.72%. The component differences in the displacement products are mainly concentrated in the high-yield stage and gas breakthrough stage. During the high-yield stage, an increase in miscibility leads to a higher proportion of heavy components in the produced material. Conversely, in the gas breakthrough stage, extraction increases as the level of mixing increases, demonstrating the distinct extracting characteristics of different degrees of mixed phases. The core experiences significant variations in oil saturation mostly during the pre-gas stage. CO2 miscible flooding can effectively utilize crude oil in tiny and medium-sized pores during the middle stage of flooding, hence reducing the minimum threshold for pore utilization to 0.3 μm. [ABSTRACT FROM AUTHOR]

CO2-enhanced coalbed methane recovery (CO2-ECBM) has been demonstrated as an effective enhanced oil recovery (EOR) technique that enhances the production of coalbed methane (CBM) while achieving the goal of CO2 sequestration. In this paper, the grand canonical Monte Carlo simulation is used to investigate the dynamic mechanism of CO2-ECBM in anthracite pores. First, an anthracite pore containing both organic and inorganic matter was constructed, and the adsorption and diffusion characteristics of CO2 and CH4 in the coal pores under different temperature and pressure conditions were studied by molecular dynamics (MD) simulations. The results indicate that the interaction energy of coal molecules with CO2 and CH4 is positively associated with pressure but negatively associated with temperature. At 307.15 K and 101.35 kPa, the interaction energies of coal adsorption of single-component CO2 and CH4 are −1273.92 kJ·mol−1 and −761.53 kJ·mol−1, respectively. The interaction energy between anthracite molecules and CO2 is significantly higher compared to CH4, indicating that coal has a greater adsorption capacity for CO2 than for CH4. Furthermore, the distribution characteristics of gas in the pores before and after injection indicate that CO2 mainly adsorbs and displaces CH4 by occupying adsorption sites. Under identical conditions, the diffusion coefficient of CH4 surpasses that of CO2. Additionally, the growth rate of the CH4 diffusion coefficient as the temperature increases is higher than that of CO2, which indicates that CO2-ECBM is applicable to high-temperature coal seams. The presence of oxygen functional groups in anthracite molecules greatly influences the distribution of gas molecules within the pores of coal. The hydroxyl group significantly influences the adsorption of both CH4 and CO2, while the ether group has a propensity to impact CH4 adsorption, and the carbonyl group is inclined to influence CO2 adsorption. The research findings are expected to provide technical support for the effective promotion of CO2-ECBM technology. [ABSTRACT FROM AUTHOR]

Pressurized liquefied natural gas (PLNG) is a new natural gas liquefaction solution proposed in recent years for reducing the construction and operating costs of floating liquefied natural gas (FLNG). For natural gas, the liquefaction temperature is strongly influenced by the pressure; when the pressure increases, the liquefaction temperature of natural gas increases accordingly. The increase in the liquefaction temperature of natural gas leads to a higher solubility of impurities such as carbon dioxide, which means that the pretreatment standards for liquefied natural gas can be reduced. Therefore, the use of PLNG technology can simplify pretreatment plants and significantly reduce construction and operating costs. In order to better apply PLNG technology to FLNG, it is necessary to understand the solubility of carbon dioxide in pressurized LNG and the phase change during liquefaction. To achieve this, experimental setups are needed to simulate the temperature and pressure environment of the LNG to obtain the relevant data and observe the relevant phenomena. After a literature research and analysis of the advantages and disadvantages of previous experimental setups, several improvements are proposed in this paper, and based on this, a visualization device is designed for studying the liquid–solid-phase equilibrium experiment of CO2 in PLNG. The device has a pressure resistance of 20 MPa, a minimum operating temperature of 77 K, and a variable volume function. It is also equipped with a sapphire window to be able to observe the inside of the device. In order to verify the superiority of the device, experiments were conducted using the device to verify the pressure resistance, variable volume, and visualization functions of the device. The experimental results show that the experimental device designed in this paper does have a certain superiority. [ABSTRACT FROM AUTHOR]

Near-surface oceanic turbulence plays an important role in the exchange of mass, momentum, and energy between the atmosphere and the ocean. The climate modifying the air–sea CO 2 transfer rate varies linearly with the surface turbulent kinetic energy dissipation rate to the 1 / 4 power in a range of systems with different types of forcing, such as coastal oceans, river estuaries, large tidal freshwater rivers, and oceans. In the first part of this paper, we present a numerical study of the near-surface turbulent kinetic energy spectra deduced from a direct numerical simulation (DNS) compared to turbulent kinetic energy spectra deduced from idealized infrared (IR) images. The DNS temperature fields served as a surrogate for IR images from which we have calculated the underlying kinetic energy spectra. Despite the near-surface flow region being highly anisotropic, we demonstrated that modeled isotropic and homogeneous turbulence spectra can serve as an approximation to observed near-surface spectra within the inertial and dissipation ranges. The second part of this paper validates our numerical observations in a laboratory experiment. In this experiment, we compared the turbulent kinetic energy spectra near the surface, as measured using a submerged shear sensor with the spectra derived from infrared images collected from above the surface. The energy dissipation measured by the shear sensor was found to be within 20% of the dissipation value derived from the IR images. Numerically and experimentally, we have demonstrated that IR-based and remote measurement techniques of the aquatic near surface offer a potentially accurate and non-invasive way to measure near-surface turbulence, which is needed by the community to improve models of oceanic air–sea heat, momentum, and gas fluxes. [ABSTRACT FROM AUTHOR]