1. Synthesis of a 3-D porous Tb-MOF: organic dye adsorption.
- Author
-
Yun, Ruirui, Jiang, Yaqin, Wu, Hongqun, and Luo, Shizhong
- Subjects
- *
COMPLEX compounds synthesis , *METAL-organic frameworks , *ADSORPTION (Chemistry) , *METAL complexes , *POROUS materials , *RARE earth metals , *SINGLE crystals - Abstract
A 3-D lanthanide metal–organic framework, [Tb2(L)1.5(DMF)2]·2DMF (1) (L = 14-diylbis(acylamino-21-diyl))-diisophthalic acid), has been synthesized under solvothermal conditions.1was characterized by X-ray single-crystal analysis and powder X-ray diffraction. The 3-D framework of1is constructed by 2-D channels embedded in a plane. Network analysis reveals that1is a (4,5,6,6)-connected net with stoichiometry (4-c)2(5-c)2(6-c)3. As expected, this terbium(III) metal–organic framework exhibits good properties for adsorbing organic dye molecules due to its NH- group. It shows good adsorption selectivity for rhodamine B (RB) rather than methyl orange (MO) and methylene blue (MB) molecules. [ABSTRACT FROM PUBLISHER]
- Published
- 2016
- Full Text
- View/download PDF