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This article introduces a method to validate heat of sorption measurements from isotherms by comparing them to direct measurements using reaction calorimetry. We have evaluated some frequently used single-temperature isotherm models (BET, GAB) as well as two multi-temperature isotherm equations (Anderson, Heikkilä). It turned out that the isotherm models with better isotherm curve fitting characteristics did not deliver the best results for the heat of sorption. Multi-temperature isotherm models such as the Heikkilä equation are able to deliver good results in terms of modelling the isotherm data and determining the heat of sorption. Single-temperature models fit the isotherm data better than multi-temperature models, but failed to deliver correct values for the heat of sorption. We specifically investigated the heat of sorption at very low moisture content, which is most relevant for paper drying. The resulting heat of sorption curves were analyzed with respect to their saturation behavior, which is expected to occur below BET monolayer moisture. The heat of sorption from the Heikkilä’s model was the only one to show the expected saturation at very low moisture content. [ABSTRACT FROM PUBLISHER]

The extension of the Darcy law (the Forchheimer flow equation) relating second-order nonlinear pressure drop with flow velocity is studied during fast transient through air drying of sheets of porous biobased materials such as paper. A range of the paper materials with open structure consistent with tissue and towel products (basis weights 25 and 50 g/m2) made using different production processes are analyzed for the factor-specific influences with regard to changes in the fluid resistance from the removal of moisture from the material interstices. A characteristic dimension suitable for the drying process is applied from viscous and inertial momentum transport analysis. [ABSTRACT FROM AUTHOR]

The properties of recycled paper are strongly affected by shrinking during drying, which depends on the drying conditions. An experimental study of the shrinkage phenomenon during drying of paper is presented. Drying experiments were conducted in a drying oven with controlled temperature. The temperature influence on shrinkage extent, porosity, and apparent density of the paper was evaluated. Structural changes on the paper surface after drying were analyzed by scanning electronic microscopy. Thickness contraction, surface, and volumetric shrinkage were correlated as a function of the moisture content. Lower apparent density values and more porous paper samples were obtained for higher temperatures. [ABSTRACT FROM AUTHOR]

Moisture equilibrium isotherms are very important in drying and storage processes analysis. So, the DEQ/UEM process separation group is building a data bank for cellulose, paper, and textile isotherms and their fit with available literature equations. In this context, the experimental isotherms of a brazilian specific commercial paper, the KLABIN-PR KLAPAK commercial liquid package paper were obtained. The experimental equilibrium data were obtained by exposing the material to different ambient conditions of temperature and relative humidity controlled by the use of saline solutions. The samples were placed in glass flasks left inside an oven to provide a better adjust of temperature conditions, being periodically weighed until constant weight. KLAPAK moisture equilibrium isotherms were built from the obtained experimental results and temperature effects on its behavior were analyzed. Then, these results were fitted with the help of some models and equations available from literature. [ABSTRACT FROM AUTHOR]

Some current models for moisture diffusion in paper in the hygroscopic range are analyzed. In general, two types of diffusion models can be recognized. Models of the first type treat paper as a homogeneous medium with moisture flux that is proportional to the gradient in moisture content. Although useful in some instances this approach fails frequently because it homogenizes the internal dynamics and relaxation processes occurring within the paper material. Recent studies have shown that a subtler approach which treats paper as a composite of fibers and void spaces is more successful at describing moisture transport dynamics. A review of these studies along with a generalization of this approach to three dimensions is considered here. The parameters appearing in such models can be identified with the physical processes of diffusion through the void space and through the fiber matrix. Diffusivities in these individual phases are supplemented by a local kinetic coefficient representing moisture flux interchange between the void and fiber phases. When the local moisture exchange coefficient takes on large values, the fibers and the void spaces are at local equilibrium with no net exchange of moisture. Under such conditions, the model reduces to the simpler Fickian diffusion model with nonlinear moisture diffusivity equivalent to earlier models. [ABSTRACT FROM AUTHOR]

Upon application of water based coating onto silicone-coated paper and during the subsequent drying process, the water permeates through the silicone layer into the paper substrate. At the same time, water evaporates from both the surface of the coated layer and throughout the paper layer. Initially, the evaporation rate from the wet coating surface may be dominant, but at longer times the bulk evaporation from the paper can dominate. Here a three-layer diffusion model for such a system is developed. Solutions obtained by Galerkin's method with finite element basis functions show that the hygroscopic nature of the paper leads to low drying rates at low moisture contents. Further, the model predicts that initially the coating dries to a moderately low residual moisture concentration faster than a coating applied on an impermeable substrate. However, at longer times, the predicted residual moisture of coatings applied on silicon-coated paper is higher than for a coating applied on an impermeable substrate. [ABSTRACT FROM AUTHOR]

Local nonuniformity of moisture content during drying is doubly disadvantageous. Moisture nonuniformity reduces drying effectiveness, increasing drying cost or reducing drying capacity, and may decrease product quality for printing through effects such as cockling and curl. These problems can occur with the now dominant process of cylinder drying, but become much more acute with the various higher intensity drying techniques which are competing to become elements of the higher speed hybrid dryer sections of the future. For quantitative characterization of moisture nonuniformity a novel method applicable to paper being dried by various processes was developed, then demonstrated for one high intensity air convection process, through air drying. During drying, the local moisture content was determined for many 2.5 mm diameter sensing areas by very rapid scanning with a custom design 3-wavelength infrared paper moisture instrument. For local moisture nonuniformity thus determined, the coefficient of variation provides a standard basis for comparison between paper types and drying conditions. For kraft paper from 20 to 120 g/m2, the effects on local moisture nonuniformity were evaluated for drying intensity and for several paper parameters—formation, grammage, and initial moisture content. The drying nonuniformity index was found to parallel both formation quality and drying intensity. An unexpected finding was that over the 20–120 g/m2 range, local moisture nonuniformity passes through a maximum at 30 g/m2. Sheet initial moisture content produces the largest effect, with moisture nonuniformity index being both high and very sensitive to this parameter for initial moisture content above the fibre saturation point. Another finding from these unique measurements is that, for the same 2.5 mm diameter sensing areas, there is a clear correlation between moisture nonuniformity index and local grammage. [ABSTRACT FROM AUTHOR]

Vacuum freeze-drying of frozen wet papers was investigated experimentally. A freeze-drying facility was built to study the process by monitoring the various physical parameters (pressure, sample temperature, heater temperature, water content of the sample and cold panel temperature). A simple phenomenological model was developed to explain experimental results. The values of the physical parameters were optimized to make the process cost effective. [ABSTRACT FROM AUTHOR]