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This paper reports the first structural application of site-cast, alkali-activated slag concrete in China. Special attention was given in this office building project at Chongqing Jianke to quality control, construction procedure and assessment. The experience showed that quality and costs could be successfully managed through careful control of raw materials, suitable selection of admixtures, proper mix proportions and an efficient construction team. It was also found that alkali-activated slag concrete has the potential for use in cold weather. The ambient temperature during construction was at times below 5°C, yet no specific procedures were needed to maintain the temperature or provide additional heat. The project is a useful reference for future structural use of alkali-activated slag concrete. [ABSTRACT FROM AUTHOR]

The electrochemical tests commonly used for evaluating reinforcement corrosion in Portland cement-based concrete may not be appropriate for testing alkali-activated slag (AAS) concrete due to its different pore structure and pore solution composition. In this article, corrosion behaviour of the steel bars in 12 AAS concrete mixes with different alkali concentration and modulus of sodium silicate solution was monitored by using gravimetric mass loss measurement. The results obtained from other electrochemical tests were compared to the gravimetric mass loss to determine their suitability for assessing the corrosion of steel in AAS concrete. It was found that only 7.8–28% of the mass loss was accounted for by the macrocell current for AAS concretes, indicating that this type of test underestimates the corrosion of the steel in AAS concrete. The steel bars in the AAS concretes gave a much higher negative half-cell potential value, presumably due to the influence of sulfides. In summary, it has been established that the criteria for assessing the onset and progress of corrosion of steel in Portland cement concrete are not suitable for the same purpose in the range of AAS concretes studied. [ABSTRACT FROM AUTHOR]

The chemical compositions of the aqueous phases in alkali-activated slag (AAS) paste and Portland cement (PC) paste were determined up to 28 d with the aim of obtaining a better understanding of the stability of the hydration products in the two binder systems. The saturation levels with respect to the hydration products of PC and AAS were obtained by thermodynamic modelling. The main findings of this study were: the effective saturation index for portlandite in the AAS system was always below zero and the sulfate-bearing phases were not stable in the AAS system compared with those in the PC; strätlingite and hydrotalcite phases were stable in the AAS paste due to the high magnesium and silicon concentrations in the pore solution; both the ionic strength and alkalinity of the AAS pore solution were higher than those of the PC pore solution, which were responsible for more severe efflorescence in the AAS paste and the higher conductivity of the AAS pore solution. According to thermodynamic estimations, tobermorite-based C–S–H was dominant in the AAS system after 7 d, while jennite-based and tobermorite-based C–S–H gels were present in the PC system up to 28 d. The results suggest that in PC and AAS pastes, different solid phases are formed during the hydration, which change with time, and the reactions and equilibria in both binders are completely different. [ABSTRACT FROM AUTHOR]

This paper presents a study on sulfate resistance of mortars blended with and without silica fume or fly ash under electrical field. Performance of the mortars was determined by various means such as visual examination, sulfate concentration, flexural and compressive strength, as well as mineralogical analysis. The results showed that electrical field accelerated the deterioration induced by sulfate attack, as it sped up the ingress of sulfate ions into the mortar. The use of mineral admixtures improved the sulfate resistance of mortars. However, a relatively great amount of migrated sulfate as well as expansive sulfate products (gypsum and ettringite) were still found in the blended cement mortars under the electrical field, for which their deterioration was also notable. Therefore, the electrical field also accelerated sulfate attack on the mortars blended with mineral admixtures. [ABSTRACT FROM AUTHOR]