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This paper presents an investigation of the underlying mechanism behind the interface charge barrier between oil and oil immersed paper. Two types of oils and two types of cellulose papers are selected in the study. The interface charges of the samples are measured by the pulsed electro-acoustic (PEA) method and the zeta potentials of different oil-paper combinations are also measured. The results show that the amount of interface charge changes with the type of oils and papers, and is much larger than the Maxwell-Wagner-Sillars (MWS) polarization charge. The difference in the amount of interface charges cannot be attributed to the difference in the conductivity and permittivity of the materials. It is suggested that the barrier for charge transport across the interface, which is formed due to the electric double layer, should be taken into consideration to explain the interface charge behavior in oil-paper insulation. [ABSTRACT FROM AUTHOR]

Breakdown strength is an important electrical property of insulating paper. Oil-impregnated paper of various aging states was prepared. Its breakdown voltage was then measured at pulsating direct current (DC) voltage with various ripple factors, and alternating current (AC) and DC voltage for comparison, respectively. The AC breakdown voltage is the smallest, and pulsating DC (r = 1/5) breakdown voltage is the greatest before the paper reaches its end of life. A dielectric model was adopted to investigate the difference in magnitude of breakdown voltage at different voltage waveforms. Meanwhile, it was found that breakdown voltage fluctuated and even increased occasionally during the thermal aging process, and a somewhat opposite changing tendency versus aging time was observed for breakdown voltage at DC voltage and pulsating DC voltage with small ripple factors (r = 1/5 and 1/3), compared with AC voltage. The degree of polymerization (DP) and moisture content of the paper were measured, and the characteristics of the pores and cracks of the paper were obtained to investigate the possible influencing factors of breakdown voltage at different aging states. The results showed that the moisture content, oil absorption ability associated with pores and cracks of paper, and the damage to paper structure all contributed to the variation of the breakdown voltage versus aging time, while the importance of their influence differed as the aging state of paper varied. [ABSTRACT FROM AUTHOR]

In accordance with environmental sustainability and in order to optimize the recycling process of prints from indirect electrophotography with liquid toner the results of investigating the effects of changes in printing conditions on the characteristics of recycled fibres is presented. Changing of printing machine conditions, respecting of voltage variations, comprises of the reverse rollers and intermediate cylinder. Based on the results it can be concluded that the change in the voltage of the reverse rollers more affect the recycling efficiency with respect to the voltage change of the intermediate cylinder. Brightness gain is higher when the print for recycling is made on uncoated paper compared to coated, and dependent on the voltage changes. Effective residual ink concentration decreases far more on handsheets obtained from recycled samples on uncoated paper in relation to both sides coated paper. Increasing the positive voltage of intermediate cylinder and increasing the negative charge of reverse rollers increases the 3 D gamut CIE L*a*b* color cubic units. Guidelines for the size of the voltage in order to obtain optimal print reproduction are provided. The further research will include the development in area of clean technologies, advanced materials, closed loop systems; therefore the significant terms in the area of environmental sustainability. [ABSTRACT FROM AUTHOR]

Oil-paper insulation of higher voltage winding and traction winding in on-board traction transformers frequently withstand large AC fluctuation voltages mainly combined with AC and inter-harmonic components. This paper presents the characteristics of partial discharge (PD) of oil-paper insulation under superimposed inter-harmonic AC voltages. The experimental results show that the addition of the inter-harmonic to the fundamental sinusoidal component results in variation of peak voltage and dv/dt along the phase. This superimposed inter-harmonic AC voltages has a significant impact on PD including partial discharge inception voltage (PDIV), breakdown voltage, PD repetition rate, and phase resolved partial discharge (PRPD). In addition, a dynamic characterization method of PD statistical parameters is proposed to determine the developing trend. The critical values and inflection points of PD are obtained. Besides, the theoretical mechanism is expounded to better interpret and understand the influence of inter-harmonic component on PD properties. These methods will provide the dynamic datasets and more information for insulation condition assessment of on-board traction transformer. [ABSTRACT FROM AUTHOR]

In this paper, the temporal space charge dynamics under both temperature and voltage polarity reversal of an epoxy resin impregnated crepe paper are characterized by pulsed electroacoustic method. It is found that the space charge injection and the interfacial traps located between the epoxy and paper plays an important role in determining the space charge dynamics. The results reveal that below 353 K, the calculated interfacial charge density is consistent with the Maxwell-Wagner (MW) model, while above 353 K, it is smaller than the measured value. The time constant during charging is much smaller than that predicted by the MW model and the space charge injection showed polarity effect, which leads to the interfacial charge densities under polarity poling voltage not being equal. It is proposed that the interfacial traps and space charge injection should be responsible for the observed space charge dynamics. [ABSTRACT FROM AUTHOR]

A piezoelectric based touch sensitive device has been successfully fabricated by screen printing silver (Ag) and polyvinylidene fluoride (PVDF) inks as conductive and piezoelectric materials, respectively, on paper substrate. X-ray diffraction (XRD) analysis was performed to verify the formation of β-phase crystals in the PVDF layer during the curing process. Voltages, as high as 0.22 V, were observed for human finger touch tests and a sensitivity of 0.3 V/N was obtained when varying forces ranging from 0.2 N to 1.4 N, in steps of 0.2 N, were applied on the printed device. The piezoelectric-voltage analysis demonstrated that the printed device can be used for both touch and force sensing applications. [ABSTRACT FROM AUTHOR]

Transformer oil, insulating paper, high voltage direct current (HVDC) bushings and on-load tap changer (OLTC) are essential parts of converter transformers. When the power flow of the HVDC system is reversed or a sudden outrage occurs, the charge field will deform the dielectric internal electric field, thus easily leading to the occurrence of discharge or insulation damage. In this case, it is necessary to carry out the characterization of the oil?paper interface to avoid these consequences. This paper analyses the interface charge accumulation and dissipation characteristics of an oil?paper insulation system under DC and polarity reversal voltages. In this paper, induced electrification was used to charge the composite oil?paper insulation. The amplitude of DC and polarity reversal voltages applied in this paper was 4 kV, and paper with thicknesses of 0.08 and 0.13 mm was used. This research offers a theoretical exploration to optimize the transformer oil? paper insulation structure and prevent damage to its insulation systems. From the research on different layers and thicknesses of paper, it can be concluded that the decay is fast in the initial period and then becomes slower with the lapse of time until finally the decay curve tends to become flat. With an increase in the number of the paper layers, the interface charge density decreases. So in real life multilayer paper is used to avoid failures owing to its structural weakness. Regarding the DC polarity reversal effect, increasing the thickness of the paper is equivalent to adding paper layers. The dissipation rate of the positive interface charge is quicker than that of the negative one. In the polarity reversal test, the dissipation rate becomes smaller as the reversal time gets longer. [ABSTRACT FROM AUTHOR]

The paper presents the application of the Cole-Cole model for determining the runs of the return voltage of the paper-oil insulation sample through a computer simulation. Different insulation conditions were simulated through an adequate selection of parameters a and T of the Cole-Cole model. For calculation purposes, a series - parallel substitute scheme, obtained through approximation of discrete characteristic operator impedance Za of the model applied, was used. The diagnostics of the simulated insulation condition was based on the analysis of a few selected parameters of the return voltage, obtained from time characteristics. [ABSTRACT FROM AUTHOR]

This paper presents an experimental work investigating the failure data of oil-impregnated paper under pulsating DC voltage. The failure data of the oil-impregnated paper specimens were obtained through constant voltage stress tests; the Weibull distribution was used to estimate the statistical distribution of failure data. The exponential function (EF) and the inverse power function (IPF) were used to modify the Weibull distribution of failure data, so as to obtain two dual-variable Weibull failure distributions (WFDs), which were used to analyze failure data of oil-paper specimens obtained under pulsating DC and individual DC and AC voltages. Their adequacies were evaluated by using failure data obtained through the constant stress tests under various voltages. Both EF-modified and IPF-modified WFDs show more adequacy for failure data of oil-paper insulation under DC and pulsating DC voltages than AC voltages. The EF-modified WFD was more adequate than IPF-modified WFD in estimating the statistical distribution of failure data. [ABSTRACT FROM PUBLISHER]

The oil-paper insulation of valve-side windings in a high voltage direct current (HVDC) converter transformer is subjected to both complicated voltage and severe thermal stresses. Partial discharge (PD) occurring in oil-paper bounded cavities is influenced by voltage stress type as well as temperature. This paper presents PD behaviors in an oil-paper bounded gas cavity under pulsating DC voltages. The voltage across the gas cavity and PD inception voltages at different test conditions are analyzed. Influences of temperature on statistical PD distributions and parameters are also presented. A numerical model is used to interpret PD behaviors under pulsating DC voltages and various temperatures. Experimental results and theoretical statements show that the temperature exhibits a great influence on the behaviors of cavity discharge under pulsating DC voltages. Volume resistivity, gas pressure, charge decay time constant, and electron generation rate are the primary parameters influencing PD behaviors at different temperatures. [ABSTRACT FROM PUBLISHER]

The oil-impregnated paper, as a vital part in the oil-paper insulation system, serves as the main insulation medium in converter transformer suffering various electric fields. However, the accumulated surface charge on the paper would accelerate the degradation of insulation system and may lead to surface flashover. Direct-fluorination is a method to change the chemical components of polymer matrix thus could affect the surface property of the dielectric material without the alternation of bulk property. This paper presents a method to modify the surface structure of the paper applied in transformers. The paper used in the experiment was treated using the F2/N2 mixture with a volume fraction of 10% for the F2 gas at a pressure of 0.05 MPa in a reaction vessel for 2, 5, 10 and 15 min, respectively. The chemical elements, functional group and physical morphology of the paper before and after modification were measured with energy dispersive X-ray spectroscopy (EDAX), attenuated total reflection infrared (ATR-IR) and scanning electron micrographs (SEM), respectively. Surface and volume resistivity of the fluorinated paper were measured. Furthermore, the surface charge property of the oil-impregnated paper was measured under various positive and negative voltages. Obtained results showed that the fluorination had an obvious influence on the chemical property and surface structure of the paper leading to the reduction of surface and volume resistivity. The treatment was shown to reduce the initial potential and cause acceleration in charge decay process. The trap distribution of the paper surface presented alternation as well. [ABSTRACT FROM PUBLISHER]

To investigate the characteristics of micro bridges and their interactions with partial discharge (PD) in oil-paper insulation under DC voltage, an experimental platform with two-copper-electrode models is established. Generation and growth of micro bridge impurities are observed. PDs in experimental process are detected and analyzed. The result shows that the generation and growth of micro bridges have three stages based on their quantity and shape. At first stage PD accelerates the generation of micro bridges. At second stage the grown bridges trigger stronger discharges. At the last stage a so-called "hazardous bridge" that triggers highly intensive PDs emerges, through which breakdown happens. Therefore, bridges and PDs promote each other to cause insulation failure. In addition, impurities at the second stage are observed to transform into pile-like, bridge-like or particle-like shapes. The transformation process is considered to relate with the change of composition force on fiber bundles. Besides, a "cluster discharging" phenomenon is observed at the second stage, which is associated with the generation and disappearance of micro bridge impurities. [ABSTRACT FROM AUTHOR]

The article presents the results of comparative investigations of partial discharges in two insulation systems; aramid-enhanced cellulose paper-mineral oil, and pure cellulose paper-mineral oil. Partial discharges were investigated in a diagonal electric field with vertical and horizontal components. This field is treated as the most dangerous for insulation. The research was carried out on Nomex® 910 paper and cellulose paper samples, each paper being 0.25 mm thick. Samples of the two materials were tested at four levels of moisture. The inception voltage of partial discharges of all samples tested decreased as their moisture content increases. It was also proved that Nomex® 910 has a significantly higher partial discharge inception voltage than the cellulose paper, although this difference decreased with increasing moisture content. [ABSTRACT FROM AUTHOR]

Heretofore, unlike HVAC transformers, there is not much experience in both insulation design guides and test methods for ultra HV converter transformers. This special insulation phenomenon is very prominent due to the complication of voltage applied on valve-side windings of converter transformers. There is a severe lack of empirical research on partial discharge in oil-paper insulation under the combined ACDC voltage. The study in this paper provides a timely research into the issues. Nine possible configurations, which intent to simulate different defects in the transformer, have been investigated. The PD inception voltages varied ratios of combined AC-DC voltages were conducted. The discharge magnitude and its relation with the applied voltage for selected four common configurations were obtained during voltage increasing and decreasing respectively, which presented the PD initiating process and also reflected the insulation behavior of dielectrics. Besides, the Finite Element Analysis Soft was used to propose the effect of morphology of electrode surface (3 dimensional roughness is approximately 0.03 mm) on PD characteristics, which is very lacking in the previous references. The roles of DC and AC component in PD characteristics were discussed in the context of the relevant work in literatures. [ABSTRACT FROM AUTHOR]

To facilitate better interpretation of dielectric response measurements--thereby directing numerical evidence for condition assessments of oil-paper-insulated equipment in high-voltage alternating current (HVAC) transmission systems--a novel approach is presented to estimate the parameters in the extended Debye model (EDM) using wideband frequency domain spectroscopy (FDS). A syncretic algorithm that integrates a genetic algorithm (GA) and the Levenberg-Marquardt (L-M) algorithm is introduced in the present study to parameterize EDM using the FDS measurements of a real-life 126 kV oil-impregnated paper (OIP) bushing under different controlled temperatures. As for the uncertainty of the EDM structure due to variable branch quantity, Akaike's information criterion (AIC) is employed to determine the model orders. For verification, comparative analysis of FDS reconstruction and results of FDS transformation to polarization--depolarization current (PDC)/return voltage measurement (RVM) are presented. The comparison demonstrates good agreement between the measured and reconstructed spectroscopies of complex capacitance and tan δover the full tested frequency band (10-4 Hz-10³ Hz) with goodness of fit over 0.99. Deviations between the tested and modelled PDC/RVM from FDS are then discussed. Compared with the previous studies to parameterize the model using time domain dielectric responses, the proposed method solves the problematic matching between EDM and FDS especially in a wide frequency band, and therefore assures a basis for quantitative insulation condition assessment of OIP-insulated apparatus in energy systems. [ABSTRACT FROM AUTHOR]

In this paper, the rapid aging due to Partial Discharge (PD) activity was investigated in unaged and thermally aged oil-impregnated paper with a disk-shaped cavity between the sheets of paper. The PD inception voltage and the voltage for instantaneous breakdown were measured, and the time to breakdown was measured by applying voltages less than the instantaneous breakdown voltage. A comparison between time to breakdown of unaged and thermally aged paper shows no significant difference between thermally aged and unaged paper at sustaining PD activity. The time to breakdown as a function of applied electric field was plotted and compared for both cases showing points scattered around a line in log-log scale. Changes of the PD parameters, such as PD magnitude and PD repetition rate were analyzed from the beginning of PD activity up to the moment of breakdown. The results show that the number and magnitude of PD increase at the beginning of aging until they reach to a maximum value, then both quantities decrease slowly over time until the final puncture breakdown occurs. The results emphasize the importance of PD monitoring on real equipment with oil-impregnated paper as insulation system, such as power transformers, since a focus on the number and magnitude of PD at just the present time may mislead the interpretation. Dielectric spectroscopy measurements performed on unaged and thermally aged paper showed an increasing trend of ε" after the sheets of paper were exposed to thermal aging for longer time. Dielectric spectroscopy measurements performed on samples before and after exposure to PD activity showed a big change of ε", This change can be attributed to byproducts and ions produced by PD activity. [ABSTRACT FROM AUTHOR]

Water (H2O) microdroplets are sprayed onto a magnetic iron oxide (Fe3O4) and Nafion-coated graphite mesh using compressed N2 or air as the nebulizing gas. The resulting splash of microdroplets enters a mass spectrometer and is found to contain ammonia (NH3). This gas–liquid–solid heterogeneous catalytic system synthesizes ammonia in 0.2 ms. The conversion rate reaches 32.9 ± 1.38 nmol s−1 cm−2 at room temperature without application of an external electric potential and without irradiation. Water microdroplets are the hydrogen source for N2 in contact with Fe3O4. Hydrazine (H2NNH2) is also observed as a by-product and is suspected to be an intermediate in the formation of ammonia. This one-step nitrogen-fixation strategy to produce ammonia is eco-friendly and low cost, which converts widely available starting materials into a value-added product. [ABSTRACT FROM AUTHOR]

The effect of HV impulses on surface and cavity partial discharges (PD) of oil-impregnated paper (OIP) is investigated in this work, by subjecting specimens to impulse voltages superimposed on a continuous AC voltage. The superposition of transient and AC voltage is relevant to insulation systems in power-system equipment, which is exposed to transients such as lightning and switching impulses during its operation. For several different PD-generating defects in oil-impregnated paper, the PD behaviors before and after the impulse are compared. The influence of moisture content is studied by using OIP with moisture content <0.5%, 3.0% and 5.5%. The results show a distinctive behavior of PD due to the impulse for each defect and insulation condition, either by change in the PD rate and magnitude or by causing PD inception or extinction. Recordings of the voltage signals and associated PD measurements during and after the incidence of a high voltage transient are of potential use for condition assessment of the insulation of power transformers and their bushings, as a form of online diagnostics. [ABSTRACT FROM AUTHOR]

In comparison with the AC and DC working voltages, the effect of switching impulse voltage on insulation is very different because of its fast-rising rate and large amplitude. This paper mainly focuses on the characteristics of PD in oil-impregnated paper insulation under switching impulse voltage. First, a robust experimental platform was set up including the impulse power source, test samples with uniform gas and oil gap, and the signal acquisition and processing system. PD characteristics in the air and oil gap are analyzed and compared involving the time-domain waveforms, the variation tendency of the average amplitude and numbers of PD pulses, the occurrence time and the instantaneous value of impulse corresponding to the first PD. Based on the dielectric barrier discharge (filament) theory, a parallel microcircuit model was established to explain the similarities and dissimilarities, and to evaluate the gap discharge intensity. The occurrence and development of PD under switching impulse voltage of typical oil-impregnated paper defect were studied systematically with simulation, experiments, and modeling. [ABSTRACT FROM AUTHOR]

The oil-impregnated paper, which is the major section in converter transformer, plays a considerable role in the reliability and safety of power grid. However, the insulation degradation will be accelerated by the accumulation of charges that are on the surface of oil-impregnated paper. Therefore, the operating overvoltage occurs and irremediable damage will appear. Direct fluorination is an effective method of modifying the chemical components of polymer matrix so as to have effects on the surface characteristic of the insulating material without reforming the bulk properties. In this research, for studying effects of fluorination on charge behavior on the surface of oil-impregnated paper under the application of DC and impulse voltage, the F2/N2 compound, which the volume fraction for the F2 gas occupied 10 % and the pressure was 0.05 MPa in a reaction kettle for 5, 30 and 60 min respectively, was applied. Meanwhile, the chemical bond groups and the surface morphology of the fluorinated specimen were tested. Besides, the DC voltage amplitude was 4 kV and the applied time was 4 min. The impulse frequency was 500 Hz and the impulse voltage amplitude was 1, 2, 3 and 4 kV, respectively. The charge properties under various situations were investigated. From the research under the application of different fluorination time, impulse voltage amplitudes and polarities, conclusions can be drawn that, fluorination has significant effects on the chemical structure properties and surface characteristic of oil-impregnated paper. Furthermore, the initial potential can be reduced and the decay process of surface charge can be accelerated with different fluorination time increasing from 0 to 30 min. Nevertheless, the tendency is the opposite when the fluorination time continuously extends from 30 to 60 min. The trap distribution also exhibits alternation through the fluorination. [ABSTRACT FROM PUBLISHER]

Due to its excellent performance, oil-paper insulation has been widely used in many power apparatuses including converter transformer of high voltage direct current (HVDC) system. Space charge accumulation phenomena may significantly distort local electric field inside transformer and cause oil-paper insulation overstressing. As a result of long term operation, oil-paper gradually degrades. In most severe cases, the breakdown of insulation system may occur. In this work, the effect of space charge on breakdown characteristics of aged oil-paper insulation is investigated. Oil-paper samples with different aging states are obtained by thermally accelerated aging for various periods of time, categorized by the degree of polymerization (DP) of 1107 (new), 725, 504, 376 and 241, respectively. Experimental results show that the breakdown voltage of oil-paper samples without pre-stressing remains almost constant with thermal degradation. After the homo-polarity pre-stress, when the DP value is higher than ∼300 (from 1107 to 376), the breakdown voltage has an increasing tendency with an increase in thermal degradation. On the contrary, the breakdown voltage presents a decreasing tendency after the hetero-polarity pre-stress. When the DP is lower than ∼300 (DP241), the changes of breakdown voltage does not remain the same trend as previous samples after pre-stressing. Meanwhile, space charge distributions in different aged samples are measured by the pulsed electro-acoustic (PEA) method, and the trap parameters are correspondingly evaluated. It has been experimentally demonstrated that special attention should be paid to space charge accumulation and aging state of oil-paper insulation, which may lead to severe insulation accidents. [ABSTRACT FROM AUTHOR]

Oil-paper insulation system is an extraordinarily essential system of converter transformers as well as HVDC bushings. When the system changes its state, such as switching the thyristors, operating over-voltage appears, and the charge will deform the dielectric internal electric field, thus easily leading to the occurrence of discharge or insulation failure, so charge accumulation and dissipation on oil-paper insulation under pulse voltage need more investigation. This paper studies the surface charge behavior on double-layer oil-paper insulation under pulse voltage and inducing electrification was used to charge the oil-paper composite. Studies of various voltage amplitudes, pulse frequencies, numbers and polarities showed that the decay is fast initially, and then becomes slower with the time. Eventually the dissipation of charge behaviors tends to be flat. With the increase of voltage amplitudes, the surface potential rises, and less positive charges are accumulated on the surface than negative charges. The increase of the pulse frequency causes the initial values of surface potential a little smaller and the charge to dissipate more quickly. Also, with the increase of pulse numbers, the initial value gets bigger and the surface charge would be slowly dissipated. From the tdV/dt and decay time curves, the figures of positive voltage usually have two peaks, while there is only one peak in most of the curves under the negative one. With the increase of voltage amplitudes, the charge will dissipate more quickly. Additionally, the peak value and the characteristic time increase with the reduction of pulse frequency and the addition of numbers. [ABSTRACT FROM PUBLISHER]

Oil-paper insulation system is an extraordinarily essential system of converter transformer as well as HVDC bushing. This paper studies the interface charge accumulation and dissipation characteristics of oil-paper insulation system under DC voltage. In this paper, an induced electrification was used to charge the oil-paper samples. The amplitudes of the DC voltage varied from 1 to 4 kV and the paper was 0.13 mm in thickness. From the research of different voltage amplitudes and charging times of the paper, conclusions can be drawn that the decay is fast initially, and then becomes slower with the lapse of time. At last the dissipation trend tends to be flat. With the increase of the voltage amplitudes, the surface potential rises more rapidly, and higher voltage would also cause the charge to dissipate more quickly. Longer charging times would cause the charge to dissipate a bit more slowly. The decay rate of the negative voltage is a little smaller than that of the positive charge. Moreover, when it comes to the effect on the interface charge of the paper layers, the surface potential is more proportional to the increase of paper layers. When the amplitude of the voltage applied in the test is small or the charging time is short enough, the interface charge can be hardly accumulated on the bottom layer. In addition, the tdV/dt and the decay time curves under the positive voltage usually have two peak values, while there is only one peak value in most of the curves under the negative condition. [ABSTRACT FROM PUBLISHER]

A conductive carbon nanofiber (CNF) paper is described for the actuation of shape recovery of a shape-memory polymer (SMP) by electrically resistive Joule heating. The CNF paper was manufactured using a traditional physical vapor deposition process and the microscale morphology and structure of the CNF paper were observed using a scanning electron microscope. The CNF paper was found to be porous, with the pore size determined by the weight concentration of CNF. The excellent electrical properties of pure CNF papers and their SMP composites were characterized by the four-point probe method. Shape recovery actuation of this type of SMP composite induced by electrically resistive heating was achieved with a 12 V voltage. Additionally, the thermomechanical properties of the SMP composite were studied with respect to the volume fraction of CNF paper. [ABSTRACT FROM AUTHOR]

Space charge behavior is important in the oil-immersed-paper insulation in converter transformers for HVDC transmission. This paper reports an investigation of the space charge property in samples with two layers of oil-immersed-paper and oil. Based on pulsed electroacoustic (PEA) technique, a waveform recovery method was proposed to get rid of the effects of interface and anisotropy on PEA result, and the space charge distributions in the two-layer samples under different voltage and oil thicknesses were measured. It?s found that the charges with the same polarity as oil side electrode were accumulated at the interface and gradually increased with the increase of applied voltage. However, the positive charge charges always appeared in the oil under positive and negative voltages. Moreover, the charges in samples increased with the increase of applied voltage, while the amount of interface charges decreased with the increase of oil thickness. Due to the existence of interfacial charges, the electrical field in oil-immersed-paper was distorted with its maximum close to the interface. It is indicated that due to the different mobility properties of charges in paper and oil and the interface trap state, the interface between paper and oil plays an important role in charge formation and decay. [ABSTRACT FROM PUBLISHER]

An oil-paper insulation system which will withstand DC voltage under normal conditions is a key component of converter transformers as well as high voltage direct current (HVDC) bushings. When the system changes its state, operating overvoltage appears. This kind of overvoltage will consequently affect the application of oilimmersed facilities and the safety of entire grid. Therefore, this paper studies the charge coupling behavior of double-layer oil-paper insulation under DC and pulse voltages. From the research of different pulse voltage amplitudes, pulse numbers and polarity, conclusions can be drawn that, with the increase of the pulse voltage amplitudes, DC and pulse voltages in the same polarity cause the absolute value of the initial surface potential to decrease and then rise; while in different polarities, the charge with the same polarity as the pulse voltage increases. Furthermore, for the same pulse voltage, the absolute initial value of the DC voltage applied in the same polarity is higher than that in different polarities. Considering the pulse number effect, it is obvious that the initial value increases with the increase in the pulse number, and then reaches saturation. Also, with the increase in pulse number, the decay rate decreases and thus the charge is slowly dissipated. From the tdV/dt and the decay time curves, the peak value increases with the increase in the pulse number, while the characteristic time varies by the polarity of the DC and pulse voltages. [ABSTRACT FROM AUTHOR]

The paper presents new diagnostic method applied to assess aging degree for paper-oil insulation used in professional electrical power device, primarily including medium and high power transformers. The described method is based on modified diagnostics using the recovery voltage effect occurring in dielectrics (RVM ? Recovery Voltage Methods). Modification of the RVM method applied so far, which is now used only to assess moistening degree for paper-oil insulation in power transformers, consists in a new parametric analysis of recovery voltage time characteristics. Simulation and experimental tests carried out in laboratory conditions for adequately prepared insulation samples have proven that the time-constant of recovery voltage decay (?R_MIN) is the most susceptible parameter as regards quantitative change in the function of aging of the examined insulation. This conclusion is also confirmed by statistical studies, in which a multi-parameter variance analysis method has been applied. An original equivalent circuit diagram of the insulation has been used to simulate aging degree of paper-oil insulation samples in numerical tests. The diagram is based on the Cole-Cole type dielectric response model. [ABSTRACT FROM AUTHOR]

A method of predicting the residual breakdown electrical field strength of an epoxy-mica paper insulation system is described. This method was developed by using data on service?aged stator bars from generators as well as accelerated aging model bars. Thermal aging, mechanical aging, and combined thermal and mechanical aging were done individually as accelerated aging. The partial discharge characteristics, dissipation factor, and breakdown voltage were measured on the model bars and service?aged bars from generators. From these results, the residual breakdown electrical field strength was predicted based on the partial discharge characteristics and dissipation factor. First, the dominant type of deterioration (thermal or mechanical aging) on a bar?s insulation was determined by the pattern of voltage?partial discharge magnitude characteristics. Then the residual breakdown electrical field strength was predicted by using a predicting equation for both thermal and mechanical aging. Each predicting equation uses dissipation factor tip-up (i.e. difference in dissipation factor values between 2 kV and rated voltage) and partial discharge inception electrical field strength. The accuracy of this method was confirmed using data measured on 112 service-aged stator bars from generators and 10 accelerated aged model bars. The 95% confidence interval level included 94% of the measured residual breakdown electrical field strength values. This result shows that the method enables precise predictions of the residual breakdown electrical field strength of an epoxy-mica paper insulation system. [ABSTRACT FROM AUTHOR]

Paper-based microchip electrophoresis has the potential to bring laboratory electrophoresis tests to the point of need. However, high electric potential and current values induce pH and temperature shifts, which may affect biomolecule electrophoretic mobility thus decrease test reproducibility and accuracy of paper-based microfluidic electrophoresis. We have previously developed a microchip electrophoresis system, HemeChip, which has the capability of providing low-cost, rapid, reproducible, and accurate point-of-care (POC) electrophoresis tests for hemoglobin analysis. Here, we report the methodologies we implemented for characterizing HemeChip system pH and temperature during the development process, including utilizing commercially available universal pH indicator and digital camera pH shift characterization, and infrared camera characterizing temperature shift characterization. The characterization results demonstrated that pH shifts up to 1.1 units, a pH gradient up to 0.11 units/mm, temperature shifts up to 40 °C, and a temperature gradient up to 0.5 °C/mm existed in the system. Finally, we report an acid pre-treatment of the separation media, a cellulose acetate paper, mitigated both pH and temperature shifts and provided a stable environment for reproducible HemeChip hemoglobin electrophoresis separation. [ABSTRACT FROM AUTHOR]

Repeated impulses have long been considered to affect the insulation properties of electrical equipment. This interesting but rarely studied phenomenon may pose great risks to the reliable operation of power equipment. Therefore, in this work, we focus on the accumulative effect of repeated lightning impulses on the oil-impregnated paper (OIP) used in power transformers. Specifically, we study the effect of space charge on the accumulative characteristics of OIP. A repetitive impulse accumulating test platform was set up, and the tests were conducted to obtain the accumulative characteristics of OIP under repeated lightning impulses. The accumulative characteristics of OIP with various interval time were experimentally identified to study the influence of interval time on the accumulative effect. Then, space charge in OIP samples were investigated using the pulsed electro-acoustic technique. Charge behavior in OIP was analyzed under different conditions, i.e., changing the applied times, amplitude and interval time of the applied lightning impulses. Charge injection and transport occurred during lightning impulse accumulation. The increased application of lightning impulses, high applied voltage, and short interval time contributed to the accumulation and transport of space charges. At last, the possible mechanisms of the accumulative effect are discussed in this article based on the experimental results. [ABSTRACT FROM AUTHOR]

An experiment studying the physical principles of electrophoresis in liquids was developed for an undergraduate laboratory. We have improved upon the standard agarose gel electrophoresis experimental regime with a straightforward and cost-effective procedure, in which drops of widely available black food coloring were separated by electric field into their dye components on strips of chromatography paper soaked in a baking soda/water solution. Terminal velocities of seven student-safe dyes were measured as a function of the electric potential applied along the strips. The molecular mobility was introduced and calculated by analyzing data for a single dye. Sources of systematic and random errors were investigated. [ABSTRACT FROM AUTHOR]

Compared to conventional ac cables, the current rating of HVDC cable circuits is more complicated because the permissible current is not only limited by the operating temperature, but also by the electrical stress within the insulation. Therefore the IEC60287 current rating standard is considered insufficient for some HVDC applications because it fails to include the stress limitation. This paper presents an analytical methodology to calculate an electrical stress-limited rating for HVDC cables, which considers the maximum dielectric stress as the current limiting factor. This paper represents the first part of a project which has comprehensively reviewed cable rating calculations for mass impregnated HVDC cable systems. [ABSTRACT FROM PUBLISHER]

Voltage-controlled three-phase three-leg inverters are widely applied in various occasions. The inverters are generally switched to the current-controlled mode to limit the fault currents when short-circuit faults happen. Under symmetrical fault, the inverter can be controlled as a symmetrical, three-phase current source. However, the voltage limiting will happen under asymmetrical fault. As a result, the fault phase currents will be distorted and cannot be completely controlled. Considering that the voltage limiting is mainly caused by large load impedance of healthy phase under asymmetrical fault, the voltage limiting is avoided by paralleling the virtual impedance with the output filter capacitor in this paper. As a result, the current limiting loop is not broken and the fault phase currents can be effectively controlled. The implementation of virtual impedance in control system and the influence of virtual impedance on the stability of system are also analyzed in detail in this paper. The theoretical results are validated by experiments. [ABSTRACT FROM AUTHOR]

Paper Spray (PS) is an ambient ionisation technique that is conceptually simple, economical, direct and versatile. In its simplest form, the procedure for operation relies on the application of an electric potential to a triangular-shaped paper substrate with the addition of an extraction/spray solvent to generate charge droplets, without requiring any pneumatic assistance. Despite its promise and rapidly growing popularity, there are some practical challenges associated with PS implementation with scope to enhance its performance further. One such challenge relates to only a small fraction of the Taylor cone expansion being sampled at the MS inlet. In this work we propose a new arrangement for PS, which retains the inherent advantages of this popular technique without introducing additional variables, by using an ambient ion focusing lens that is held at the same potential as the paper substrate. A thorough investigation, consisting of visual spray inspection, electric field simulations and analytical evaluation, including analysis of paracetamol from saliva, shows that ambient ion focusing can provide up to a 50% improvement in spray stability, 60% increase in signal intensity and a 30% improvement in detection limits for routine paper spray mass spectrometry analysis. [Display omitted] • Ion lens arrangement provides a simple means to produce a stable and collimated beam profile. • Ambient ion focusing leads to improvements in spray stability, signal intensity, accuracy and detection limits. • Analysis of paracetamol in saliva is demonstrated using ambient ring lens paper spray mass spectrometry. [ABSTRACT FROM AUTHOR]

Microfluidic paper-based analytical devices (μPADs) are a promising solution for a wide range of point-of-care applications. The feasibility of inducing ion concentration polarization (ICP) on μPADs has thus far attracted little attention. Accordingly, this study commences by demonstrating the ICP phenomenon in a μPAD with a Nafion ion-selective membrane. We are the first to measure the current-voltage curve on a Nafion-coated μPAD in order to indicate that the ion depletion occurs and the ICP is triggered when the current reaches the limiting current. The ICP effect is then exploited to preconcentrate fluorescein on μPADs incorporating straight and convergent channels. By an optimal geometric design, it is shown that the convergent channel results in a greater preconcentration effect than the straight channel. Specifically, a 20-fold enhancement in the sample concentration is achieved after 130 s given an initial concentration of 10-5 M and an external potential of 50V. By contrast, the straight channel yields only a 10-fold improvement in the concentration after 180 s. Further, the practical feasibility of the proposed convergent-channel μPAD is demonstrated using fluorescein isothiocyanate labeled bovine serum albumin. The experimental results show that a 15-fold enhancement of the initial sample concentration (10-5 M) is obtained after 120 s given an external potential of 50V. [ABSTRACT FROM AUTHOR]

In last period many distribution system operators (DSO) invest significant amount of money in smart metering system. Those investments are in part due to regulatory obligations and in part due to needs of DSO (utilities) for knowledge about electric energy consumption. Term - electric energy consumption, refers not only on real consumption of electric energy but also on data about peak power, unbalance, voltage profiles, power losses etc. Data which DSO can obtain from smart meters depend on type of smart metering system. Further, smart meters as source of data can be implemented in transformer stations (TS) MV/LV and in LV grid at consumer level. Generally, smart meters can be placed in any node of distribution grid. As amount of smart meters is greater, the possibility of data analysis is greater. In this paper a smart metering system of J.P Elektroprivreda HZ HB d.d, Mostar, Bosnia and Herzegovina will be presented. One statistical approach for analyzing of advanced metering data of TS MV/LV will be presented. Statistical approach presented here is powerful tool for analyzing great amount of data from distribution grid in simple way. For example, transformer in TS MV/LV can be overloaded for 30%, but overload period can be for example single one-hour period in whole year. With smart meter data, false conclusions can be avoided. In concerned case, grid operation engineer will not make decision of transformer replacing. With knowledge of only max. power of transformer (without time series data), false conclusion can be adopted about transformer replacing. This can increase costs of grid operation for DSO. Smart metering can help in transformer monitoring. Voltage drop in LV buses of TS MV/LV can be 10% for example. It means that quick intervention in grid must be performed. But, period of increased voltage drop can be only single one-hour period in whole year (for example). On other side, TS MV/LV can have voltage drop of 7% for example in halfyear period. These data, obtained by smart meters, can help in issuing of priority grid investments. Main contribution of this paper is in performing of the statistical analysis of smart meter data in distribution grid and using the obtained results in maintenance/investment planning process. [ABSTRACT FROM AUTHOR]

On the development of flexible electronics, a highly flexible nonvolatile memory, which is an important circuit component for the portability, is necessary. However, the flexibility of existing nonvolatile memory has been limited, e.g. the smallest radius into which can be bent has been millimeters range, due to the difficulty in maintaining memory properties while bending. Here we propose the ultra flexible resistive nonvolatile memory using Ag-decorated cellulose nanofiber paper (CNP). The Ag-decorated CNP devices showed the stable nonvolatile memory effects with 6 orders of ON/OFF resistance ratio and the small standard deviation of switching voltage distribution. The memory performance of CNP devices can be maintained without any degradation when being bent down to the radius of 350 mm, which is the smallest value compared to those of existing any flexible nonvolatile memories. Thus the present device using abundant and mechanically flexible CNP offers a highly flexible nonvolatile memory for portable flexible electronics. [ABSTRACT FROM AUTHOR]

As a critical component of a high-voltage direct current (HVDC) transmission system, resin impregnated paper (RIP) wall bushing has become a weak point because of its surface charge accumulation. This paper studies a model RIP wall bushing core designed by the equal capacitance method. The stationary resistive field along the gas–solid interface of the RIP wall bushing core is investigated theoretically by a gas model, which considers the non-linearly field-dependent volume conductivity. The results show that the gas conductivity along the core surface tends to be an arched distribution from the high-voltage conductor to the end shielding screen. The surface charge mainly accumulates at the turning point of the radius, which may threaten the core's insulation. Then, the surface charge is obtained through a measurement system, where the experimental results are highly consistent with the simulation results. Considering the time constant of charge dissipation is nearly 15 min, it would be better to measure the surface charge on one axial direction of RIP wall bushing core after each voltage application. The simulation and experimental results of this paper can guide the design of a RIP wall bushing core. [ABSTRACT FROM AUTHOR]

Delivering high power quality in single‐phase distribution has witnessed more challenges especially with the increased penetration of single‐phase distributed generation (DG). This paper proposes a smart solid‐state‐based transformer, which aims to replace traditional ones, for single‐phase distribution laterals, and provide load balancing and protection to the three‐phase main feeders, that is based on connecting the single‐phase lateral to the three‐phase main feeder through a power electronics converter. This converter transfers balanced power from and to the three‐phase feeder while automatically regulating the lateral single‐phase voltage, hence, assuring high power quality without requiring any transformer on‐load tap changer. A 7‐level packed‐U‐cells (PUC) single‐phase inverter topology was used to deliver single‐phase regulated sinusoidal voltage to the AC loads, and at the same time, it is able to deliver DC power to DC loads. The simulation and hardware‐in‐the‐loop (HIL) results have shown that the proposed topology delivers high power quality for both AC and DC loads under different operating scenarios. Moreover, the converter can play the role of a solid‐state protection device coordinated with other up‐ and downstream protective devices. Finally, this system can be integrated within the smart grid allowing more flexibility for automation and efficient control of the grid. [ABSTRACT FROM AUTHOR]