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Anti-laser damage has become a major concern because of the rapid evolution of high power continuous-wave laser technology. While phenolic matrix composite coatings exhibit good anti-laser property, they show low reflectivity during laser irradiation, resulting in high energy absorption. A novel composite coating that consists of Al(OH)3 and nano-copper fillers with phenolic resin matrix has been designed to solve the low reflectivity problem. X-ray diffraction reveals that Al2O3 particles generate on the surface of the coating during laser irradiation because of the dehydration reaction of Al(OH)3. The endothermic effect of this dehydration reaction and the transpiration of nano-copper particles have a significant cooling effect on the coating. The reflectivity of coating is monitored in real time during laser irradiation. It is confirmed that the reflectivity gradually increases with the accumulation of Al2O3 particles. According to the temperature of back-surface substrates, the improved reflectivity does lead to a better anti-laser property of the coating. The laser ablation behavior of the composite coating was studied in detail through different laser parameters. The results show that both laser power density and irradiation time have effect on the micro-morphologies and reflectivity of the coating. [ABSTRACT FROM AUTHOR]

High-energy lasers can cause severe damage to conventional materials in an extremely short time. Highly reflective coatings are effective against damage, but they cannot withstand high laser power densities. In this study, a composite coating with two characteristics, namely, reflection and energy consumption, was designed and prepared. TiO 2 and BN powders, as light reflective media, were introduced into a boron-modified phenolic resin (BPF) to prepare an anti-laser composite coating. The results show that the initial reflectivity of the composite coating can reach 78.8% at a wavelength of 1064 nm. After damage-free protection for 0.4 s, ablation occurred in the irradiation region. Owing to the formation of residual char, which is the pyrolysis product of BPF, the coating maintained its protective performance. When the composite coating was irradiated at 1000 W/cm2 for 10 s, the back-surface temperature was 186 °C, which indicates decent anti-laser performance. We also studied the role of BN by setting a control experiment. The high conductivity and energy consumption caused by the evaporation of B 2 O 3 , which is the oxidation product of BN, helped in improving the anti-laser performance. The residual char with high porosity and degree of graphitization proved to be effective to isolate laser energy. This study provides a new design for protection of conventional materials against laser damage. [ABSTRACT FROM AUTHOR]

With the repaid development of laser manufacturing industry, laser protection for optical components, especially high power continuous laser, has been a major concern. Optical coatings should have a good anti-laser ablation property. However, the high-power laser ablation behavior of plasma-sprayed Ta 2 O 5 coatings is rarely investigated. In this paper, tantalum oxide coatings were prepared by plasma spraying technique and irradiated using continuous laser with 1070 nm wavelength. The phase structure, ablation surface morphology and reflectivity of the coating were characterized by XRD, SEM, and UV–Visible-near Infrared Spectroscopy. During laser irradiation, the tantalum oxide coatings experience three stages: coating oxidation, micro-cracks occurrence and mechanical failure. A finite-element simulation was also conducted to explore the change of temperature field during irradiation. The simulation results show that the change of reflectivity of tantalum oxide coating during laser irradiation is of great benefit in improving its laser protection ability. [ABSTRACT FROM AUTHOR]