1. Activation-free preparation of porous carbon fiber derived from phenolic resin for CO2 absorption.
- Author
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Jiao, Fuli, Miao, Peng, Guo, Peng, Liu, Jie, and Wang, Xiaoxu
- Subjects
CARBON-based materials ,POROUS materials ,MELT spinning ,POLYVINYL butyral ,CARBON fibers - Abstract
• Porous carbon fibers with efficient CO 2 adsorption performance were produced through a method without activator. • The porous fibers not only had abundant pore structure but also were equipped with good mechanical strength. • The adsorption of CO 2 was mainly performed by nitrogen-containing groups and physical function through pores ranging from 0.3 nm to 0.8 nm. • The micropores between 0.3 nm and 0.6 nm were conducive to the selective adsorption of CO 2 /N 2. It is not uncommon to study the preparation of porous carbon materials for CO 2 adsorption, but it is still a challenge to simultaneously achieve the good mechanical strength, porous structure, and efficient adsorption performance of porous carbon fibers. Porous carbon fibers with desirable morphology and selective CO 2 adsorption were prepared using an activation-free method. The fibers were prepared through melt spinning of phenolic resin modified with polyvinyl butyral (PVB) and urea, followed by curing treatment, and then the pore structures were adjusted by controlling the carbonization temperature. The porous carbon fibers prepared by carbonization at 900 °C not only had excellent CO 2 adsorption (3.48 mmol/g) but also possessed desirable tensile strength (132 MPa). Those carbonized at 700 °C showcased CO 2 /N 2 selectivity of 57 (Ideal adsorption solution theory (IAST), CO 2 : N 2 =15:85), and tensile strength of 148 MPa, much higher than most fibers using other methods. The study revealed that the adsorption of CO 2 was mainly performed by nitrogen-containing groups and physical function through pores ranging from 0.3 nm to 0.8 nm, and the micropores between 0.3 nm and 0.6 nm were conducive to the selective adsorption of CO 2 /N 2. [Display omitted] [ABSTRACT FROM AUTHOR]
- Published
- 2024
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