1. Dual-plasma enhanced 2D/2D/2D g-C3N4/Pd/MoO3-x S-scheme heterojunction for high-selectivity photocatalytic CO2 reduction.
- Author
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Wang, Huijie, Liu, Qi, Xu, Mengyang, Yan, Chenlong, Song, Xianghai, Liu, Xin, Wang, Huiqin, Zhou, Weiqiang, and Huo, Pengwei
- Subjects
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PHOTOTHERMAL effect , *SURFACE plasmon resonance , *PHOTOREDUCTION , *COORDINATION polymers , *HETEROJUNCTIONS , *ELECTRON paramagnetic resonance , *PHOTOELECTRON spectroscopy - Abstract
[Display omitted] • The dual-plasma enhanced g-C 3 N 4 /Pd/MoO 3-x heterojunction was fabricated for high-selectivity photocatalytic CO 2 reduction. • The g-C 3 N 4 /Pd/MoO 3-x composites revealed excellent near-infrared absorption ability. • The carrier separation efficiency was effectively improved under the synergistic effect of MoO 3-x and Pd nanosheets. • The g-C 3 N 4 /Pd/MoO 3-x S-scheme heterojunction displayed high photocatalytic performance and CO selectivity. • The S-scheme charge transfer mechanism was proposed based on UPS and ESR results. The localized surface plasmon resonance (LSPR) effect has shown significant progress in enhancing the efficiency of light absorption and separating photogenerated carriers. Herein, the dual-plasma enhanced 2D/2D/2D g-C 3 N 4 /Pd/MoO 3-x (CPM) S-scheme heterojunction photocatalysts were synthesized using the method of hydrothermal and electrostatic self-assembly for high-selectivity photocatalytic reduction of CO 2 to produce CO. The dual LSPR effect of MoO 3-x and ultrathin Pd nanosheets synergistically broadened the optical response range of the CPM composites and successfully improved the photocatalytic activity and near-infrared (NIR) performance. The optimized CPM-30 photocatalysts exhibited CO yields of 18.55 μmol g−1 with a selectivity of 96.3%. In addition, the CO yield reached 3.92 μmol g−1 after 4 h of NIR light photoirradiation. The electron spin resonance (ESR) and ultraviolet photoelectron spectroscopy (UPS) tests showed that the S-scheme heterojunctions were constructed by coupling g-C 3 N 4 /Pd nanosheets and MoO 3-x. This work will provide a reference for improving product selectivity through the design of two-dimensional composites and the utilization of plasma materials. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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